Theoretical Study on the Structures and Electronic Spectra of the Derivatives of C_(60)-P-2,4,6-Triphenyl Borazinc

1 INTRODUCTION The electron-transfer reaction of C60 derivatives, especially light-induced electron-transfer reaction, has been an active research field for a long time. Many researches are focused on the long-live charge- separated state caused by electron-transfer[1]. And several electron-transfers between electron donor and C60 or intramolecular electron-transfer have been confirmed. As an example, TTF-C60 is proved to be a short-live charge-separated compound[2].Due to the excelle…     

Enantioselective synthesis of functionalized γ-butyrolactones

Sharpless asymmetric dihydroxylation and aminohydroxylation of (E)-dimethyl-2-alkylidene glutarates 2 were shown to afford enantio-enriched or enantiopure highly functionalized γ-butyrolactones 3 and 7.     

Oxazoline as a useful tool in organic synthesis: preparation of 4-aryl-1,2,3,4-tetrahydroisoquinoline alkaloid skeleton

New direct strategy for the synthesis of 4-aryl-1,2,3,4-tetrahydroisoquinolines. The key steps are based on oxazoline chemistry: nucleophilic substitution in an ortho-methoxyphenyloxazoline with a Grignard reagent and a 1,6-conjugate addition of a lithium amide to o-styrylphenyloxazoline.     

Microwave-assisted, solvent-free synthesis of 1-(α- or β-hydroxynaphthyl)-1,2,3,4-tetrahydroisoquinolines by the Mannich reaction

As a new extension of the Mannich reaction of naphthols, 1-(hydroxynaphthyl)-substituted 1,2,3,4-tetrahydroisoquinolines were synthesized by the nucleophilic addition of 1- or 2-naphthol to 3,4-dihydroisoquinolines under solvent-free conditions, using microwave irradiation. The additions to 3-methyl-6,7-dimethoxy-3,4-dihydroisoquinoline proved to be a highly diastereoselective processes, resulting in the cis isomers as the main or the only products.     

Spectrophotometric analysis of the sulphide-thiocyanate and cyanide-thiocyanate mixtures using the copper(II)-DPGH complex

Mixtures of sulphide-thiocyanate and cyanide-thiocyanate can be analyzed without separation using the Cu(II)-DPGH complex.Sulfide and cyanide cause a decrease in absorption that is a linear function of their concentration in the range 0.06–2 and 0.18–6 ppm, respectively. The Cu(II)-DPGH complex is extractable into chloroform in presence of thiocyanate and this is used for the Spectrophotometric determination of thiocyanate in the range 0.09–3 ppm.     

Rapid determination of protein in plant material by flow injection spectrophotometry with trinitrobenzenesulfonic acid

The rapid determination of protein in plant material based on spectrophotometric determination of amino acids in protein hydrolysates with trinitrobenzenesulfonic acid has been adapted to flow injection analysis. With the manifold described, a routine sampling rate of 120 samples/h is possible, though this, as well as sensitivity, can easily be varied. The method was calibrated against the Kjeldahl method and a good correlation was obtained between the two methods over a wide range of protein values for beans.     

The Kissinger law and isokinetic effect: Part II. Experimental analysis

On the basis of copper sulphate pentahydrate thermal dissociation, for analyzed reactions I to IV, 6 thermokinetic equations was discussed. Arrhenius law parameters were determined and the isokinetic effect (IE) and Kissinger law appearing was analyzed. It was found that only dependence resulting from isokinetic effect, in the form k _m=q/T _m, relates to the suitable thermokinetic Eq. (2) and Kissinger law in modified form (14). The confirmation was made that the possibility of determining the averaged activation energy from thermokinetic equations using suitable correction coefficients exists.This revised version was published online in November 2005 with corrections to the Cover Date.     

Interaction of (1-phenylethyl)indole-2-carbonitrile with C-nucleophiles

Methods of obtaining ketones and enamino esters have been developed on the basis of reactions of 1-(1-phenylethyl)indole-2-carbonitrile with organomagnesium and organozinc compounds. Removal of a benzyl group from the indole nitrogen atom by the Grignard reagent has been discovered. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1179–1183, August, 2006.     

K对Mn—Co—O的结构及氧化活性的影响

利用XRD,TPD,TFD-MS及催化氧化反应等实验技术,研究了K对Mn-Co-O的结构及氧化活性的影响。XRD结果表明,Mn-Co-O系已形成反尖晶石型的MnCo_2O_4结构;K-Mn-Co-O系中除MnCo_2O_4型结构外,还有新相KMnO_2存在。根据O_2的TPD-MS及吡啶的TPD结果,Mn-Co-O中添加适量的K能提高供氧活性和增加供氧数目,但酸中心数目减少,强度降低。K对Mn-Co—O催化剂氧化活性的影响随反应物分子结构的不同而异,对乙酸乙脂、苯甲酰氯等极性有机物的完全氧化反应,K能提高氧化活性,但对苯、正己烷等非极性有机物的完全氧化反应,K使其活性降低。     

压缩X因子导数光谱法测定痕量锗

本采用压缩Ｘ因子导数光谱技术实现了宽峰体系灵敏度的大幅度提高，提出了测定痕量锗的方法。在０．７２ｍｏｌ／ＬＨ２ＳＯ４和３．０ｍｏｌ／ＬＨ３ＰＯ４的混酸介质中，锗－水杨基荧光酮－ＯＰ三元显色体系的压缩Ｘ因子四阶导数光谱摩尔响应系数达１．８９×１０＾６Ｌ．ｍｏｌ＾－１．ｃｍ＾－１，灵敏度比常规光度法高１２．４倍；最低检测出限为０．０００３３ｍｇ／Ｌ，比常规光谱法低４倍；选择性也进一步提高，绝大多数离