全文获取类型
收费全文 | 29497篇 |
免费 | 2007篇 |
国内免费 | 3906篇 |
专业分类
化学 | 19544篇 |
晶体学 | 1058篇 |
力学 | 1186篇 |
综合类 | 323篇 |
数学 | 8251篇 |
物理学 | 5048篇 |
出版年
2024年 | 19篇 |
2023年 | 219篇 |
2022年 | 647篇 |
2021年 | 801篇 |
2020年 | 677篇 |
2019年 | 650篇 |
2018年 | 552篇 |
2017年 | 732篇 |
2016年 | 731篇 |
2015年 | 668篇 |
2014年 | 1087篇 |
2013年 | 2229篇 |
2012年 | 1517篇 |
2011年 | 1910篇 |
2010年 | 1782篇 |
2009年 | 2022篇 |
2008年 | 2023篇 |
2007年 | 2010篇 |
2006年 | 1902篇 |
2005年 | 1659篇 |
2004年 | 1569篇 |
2003年 | 1388篇 |
2002年 | 1195篇 |
2001年 | 905篇 |
2000年 | 878篇 |
1999年 | 714篇 |
1998年 | 712篇 |
1997年 | 585篇 |
1996年 | 471篇 |
1995年 | 460篇 |
1994年 | 413篇 |
1993年 | 362篇 |
1992年 | 334篇 |
1991年 | 246篇 |
1990年 | 160篇 |
1989年 | 174篇 |
1988年 | 160篇 |
1987年 | 114篇 |
1986年 | 83篇 |
1985年 | 88篇 |
1984年 | 117篇 |
1983年 | 34篇 |
1982年 | 68篇 |
1981年 | 81篇 |
1980年 | 65篇 |
1979年 | 45篇 |
1978年 | 39篇 |
1977年 | 29篇 |
1976年 | 17篇 |
1973年 | 15篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
141.
142.
We construct a multiplicative group structure in the class of integro-differential operators specific for a polydisk which was introduced by I. I. Bavrin. We indicate two applications of these operators to solution of functional equations. 相似文献
143.
《Magnetic resonance in chemistry : MRC》2003,41(9):731-734
An NMR study of one new and several known abietane diterpenes isolated from the roots of Aegiphila lhotzkyana is described. In addition to 1D NMR, several 2D shift‐correlated NMR pulse sequences (1H–1H‐COSY, NOESY, HMQC and HMBC) were used to establish all the structures, and unambiguously perform the 1H and 13C chemical shift assignments of the new natural diterpene and three derivatives, the NMR data for which have not been reported previously. Revision of current data assignment for teuvincenone H is also suggested. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
144.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
145.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
146.
王梦 《浙江大学学报(理学版)》2003,30(4):361-364
用旋转法结合Fourier估计以及Littlewood-Paley理论给出了乘积空间上带粗糙核的极大奇异积分算子的Lp有界性.证明了对于Ω∈Lq(Sn-1×Sm1),其中q>1,∫ sn-1Ω(x',y')dx'=0, y'∈Sm-1,∫ sm-1Ω(x',y')dy'=0, x'∈Sn-1,且b,h∈L∞(R1+),则积域上极大奇异积分算子T*(f)=supε1>0,ε2>0∫∫|u|>ε1|v|>ε2b(|u|)h (|v|)Ω(u',v')/|v|n|v|mf(x-u,y-v)dudv为Lp(Rn×Rm)有界,其中1<p<∞.从而改进了以往的结果. 相似文献
147.
On the basis of the hydrodynamic equations for nonlinear elastic-gravity waves beneath a solid ice cover and their Hamiltonian representation, a three-wave kinetic equation for the time evolution of the wave spectrum is formulated. The properties of the kernel of the kinetic integral describing the nonlinear interactions between wave triplets are investigated. An algorithm for numerically calculating the kinetic integral is developed. The rate of nonlinear energy transfer over the wave spectrum is estimated quantitatively and its most important characteristics are found. 相似文献
148.
中国股票市场风险的实证分析研究 总被引:6,自引:1,他引:5
本文从实证角度说明了上证指数和深证成份指数存在着GARCH现象 ,并建立了沪、深两市股指波动率的IGARCH(1,1) M模型与EGARCH(1,1) M模型。将估计的IGARCH(1,1) M模型与EGARCH(1,1) M模型比较得出 ,对上证指数的波动率 ,IGARCH(1,1) M模型与EGARCH(1,1) M模型的模拟效果基本相同 ,而对深证成份指数的波动率 ,IGARCH M模型要略优于EGARCH M模型。同时还对两市的股指收益的波动率进行了预测分析 相似文献
149.
Linear mixed 0–1 integer programming problems may be reformulated as equivalent continuous bilevel linear programming (BLP)
problems. We exploit these equivalences to transpose the concept of mixed 0–1 Gomory cuts to BLP. The first phase of our new
algorithm generates Gomory-like cuts. The second phase consists of a branch-and-bound procedure to ensure finite termination
with a global optimal solution. Different features of the algorithm, in particular, the cut selection and branching criteria
are studied in details. We propose also a set of algorithmic tests and procedures to improve the method. Finally, we illustrate
the performance through numerical experiments. Our algorithm outperforms pure branch-and-bound when tested on a series of
randomly generated problems.
Work of the authors was partially supported by FCAR, MITACS and NSERC grants. 相似文献
150.
Pedro lvarez‐Boo Jos Sergio Casas Alfonso Castieiras María Delfina Couce Eduardo Freijanes Eva Novoa Jos Sordo 《应用有机金属化学》2003,17(9):725-729
Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe2Cl2(PMP)] and [SnMe2Br2(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (1H, 13C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献