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121.
Xinfu Chen 《Journal of Differential Equations》2004,206(2):399-437
We study the full-time dynamics of the initial value problem, for uε=uε(x,t),
122.
123.
124.
The behavior of the symmetrical ethane-bridged bis(Zn porphyrin) (1) has been investigated at the air-water interface. The molecular organization of floating films of pure 1 and its mixture with amphiphilic substances, such as arachidic acid and n-octadecylamine, was inspected by means of surface pressure-area isotherms, Brewster angle microscopy and reflection spectroscopy in the UV-Vis region. The overall results suggest the presence in all cases of mainly the anti conformer of 1 even when the dimer was spread on pure water, through the ligation of water molecules to the zinc atoms in the axial positions. It was also demonstrated for the first time that the syn-to-anti conformational transition of the porphyrin dimer can be accelerated by the ligation of suitable amphiphiles even at the liquid-air interface. In particular, it is noted that n-octadecylamine, and arachidic acid (to a lesser extent), added to the system as amphiphiles, drive the syn ? anti equilibrium of 1 towards the anti form through the axial ligation of the amino or carboxylate group to the zinc atoms. 相似文献
125.
126.
Hopp B. Smausz T. Kresz N. Nagy P.M. Juhász A. Ignácz F. Márton Z. 《Applied Physics A: Materials Science & Processing》2003,76(5):731-735
Allergic-type diseases are current nowadays, and they are frequently caused by certain metals. We demonstrated that the metal
objects can be covered by Teflon protective thin layers using a pulsed laser deposition procedure. An ArF excimer laser beam
was focused onto the surface of pressed PTFE powder pellets; the applied fluences were 7.5–7.7 J/cm2. Teflon films were deposited on fourteen-carat gold, silver and titanium plates. The number of ablating pulses was 10000.
Post-annealing of the films was carried out in atmospheric air at oven temperatures between 320 and 500 °C. The thickness
of the thin layers was around 5 μm. The prepared films were granular without heat treatment or after annealing at a temperature
below 340 °C. At 360 °C a crystalline, contiguous, smooth, very compact and pinhole-free thin layer was produced; a melted
and re-solidified morphology was observed above 420 °C. The adhesion strength between the Teflon films and the metal substrates
was determined. This could exceed 1–4 MPa depending on the treatment temperature. It was proved that the prepared Teflon layers
can be suitable for prevention of contact between the human body and allergen metals and so for avoidance of metal allergy.
Received: 12 June 2002 / Accepted: 13 June 2002 / Published online: 4 November 2002
RID="*"
ID="*"Corresponding author. E-mail: bhopp@physx.u-szeged.hu 相似文献
127.
G. Held 《Applied Physics A: Materials Science & Processing》2003,76(5):689-700
The mutual influence of surface geometry (e.g. lattice parameters, morphology) and electronic structure is discussed for Cu-Ni
bimetallic (111) surfaces. It is found that on flat surfaces the electronic d-states of the adlayer experience very little
influence from the substrate electronic structure which is due to their large separation in binding energies and the close
match of Cu and Ni lattice constants. Using carbon monoxide and benzene as probe molecules, it is found that in most cases
the reactivity of Cu or Ni adlayers is very similar to the corresponding (111) single crystal surfaces. Exceptions are the
adsorption of CO on submonolayers of Cu on Ni(111) and the dissociation of benzene on Ni/Cu(111) which is very different from
Ni(111). These differences are related to geometric factors influencing the adsorption on these surfaces.
Received: 26 August 2002 / Accepted: 4 September 2002 / Published online: 5 February 2003
RID="*"
ID="*"Corresponding author. Fax: +44-1223/76-2829, E-mail: gh10009@cam.ac.uk [+1pt] Present address: University of Cambridge,
Lensfield Road, Department of Chemistry, Cambridge CB2 1EW, UK 相似文献
128.
G. B. Parravicini A. Stella M. C. Ungureanu P. G. Merli A. Migliori P. Cheyssac R. Kofman 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):219-222
Both theoretical and experimental works give evidence that
gallium exhibits solid phases labelled , , , besides the
stable phase strongly dependent both on the size and the
confinement conditions. An experimental technique was used based
on capacitance and conductance measurements
vs. temperature in the
audiofrequency range. This technique is particularly sensitive
to the conditions of the investigated particle surface that
plays a fundamental role in the melting and more generally in
the phase transition processes. In particular the strict
relation between the derivative of the capacitance with respect
to the temperature, dC/dT, and the entropy of the system is
considered. In gallium nanoparticles 20 nm in radius, only the
phase is shown to occur. Further the transition to liquid phase
was detected. The melting process was found to start about 65 K
below the full melting temperature value. In the case of
particles 10 nm in radius, where different metastable phases may
occur, the capacitance vs.
temperature curve was found to display abrupt changes of the
slope. The singularities are associated to a well defined
transition temperature. 相似文献
129.
H.-K. Zhao Q. Chen 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(4):419-427
We have investigated the spectral density of shot noise for the
system of a quantum dot (QD) coupled to two single-wall carbon
nanotube terminals irradiated with a microwave field on the QD. The
terminal features are involved in the shot noise through modifying
the self-energy of QD. The contributions of carbon nanotube
terminals to the shot noise exhibit obvious behaviors. The novel
side peaks are associated with the photon absorption and emission
procedure accompanying the suppression of shot noise. The shot noise
in balanced absorption belongs to sub-Poissonian, and it is
symmetric with respect to the gate voltage. The differential shot
noise displays intimate relation with the nature of carbon nanotubes
and the applied microwave field. It exhibits asymmetric behavior
for the unbalanced absorption case versus gate voltage. The Fano
factor of the system exhibits the deviation of shot noise from the
Schottky formula, and the structures of terminals obviously
contribute to it. The super-Poissonian and sub-Poissonian shot noise
can be achieved in the unbalanced absorption in different regime of
source-drain bias. 相似文献
130.
Molecular dynamics simulations are performed for water confined in carbon nanotubes with various diameters (11.0-13.8 A ). The simulations under an isobaric pressure (one atmosphere) by lowering temperatures from 300 K to 190K are carried out. Water molecules within variously sized tubes tend to transform from disorder to order with different configurations (four-water-molecule ring, six-water-molecule ring and seven-water-molecule ring) at phase transition temperatures, which may be lowered by the increasing tube radius. It is also found that the configurations of water in (10, 10) tube are not unique (seven-molecule ring and seven-molecule ring plus water chain). 相似文献