Localization theory of distributed fiber vibration sensor

Based on Sagnac interferometer, a simple distributed optical fiber sensing system with sub-loop is presented to monitor the vibration applied on the sensing fiber. By introducing a sub-loop, three output beams of interference with different delay time are gotten. Location of the vibration is analyzed through mathematical-physical equations. The vibration frequency, amplitude, and location are theoretically simulated. The results agree well with the previous experiments.     

Relativistic Mean Field Study of the Z=117 Isotopic Chain

The properties of the Z = 117 isotopic chain are studied within the framework of the axially deformed relativistic mean field theory （RMFT） in the blocked BCS approximation. The ground-state properties, such as hinging energies, deformations as well as the possible α decay energies and lifetimes are calculated with the parameter set of NL-Z2 and compared with results from the finite range droplet model. The analysis by RMFT shows that the isotopes in the range of mass number A =291 ~ 300 exhibit higher stability, which suggests that they may be promising nuclei to be hopefully synthesized in the lab among the nuclei Z = 117.     

AsH(X~3∑~-)及AsH_2(X~2B_1)自由基的分子结构与解析势能函数

运用Gaussian 03程序包中的单双迭代三重激发耦合簇理论和相关一致五重基优化了AsH_2的基态结构,并在优化结构的基础上计算了它的离解能和振动频率.结果表明:AsH_2基态的平衡构型具有C_(2v)对称性,键长R_(As-H)=0,1508 nm,键角∠HAsH=91.2231°,离解能D_e(Has-H)=2.8795 eV,振动频率ν_1(α_1)=1013.3361 cm~(-1),ν_2(α_1)=2225.1347 cm~(-1),ν_3(α_1)=2233.7565 cm~(-1).这些结果与实验值较为相符.对H_2的基态使用优选出的cc-pV6Z基组、对AsH的基态使用优选出的cc-pV5Z基组进行平衡几何与谐振频率的计算并进行单点能扫描,且将扫描结果拟合成了Murrell-Sorbie函数.与实验数据及其他理论结果的比较表明,本文关于AsH(X~3∑~-)自由基光谱常数(D_0,D_e,R_e,ω_e,B_e,α_e和ω_eX_e)的计算结果达到了很高的精度并最为完整.采用多体项展式理论导出了AsH_2(C_(2v),X~2B_1)自由基的解析势能函数,其等值势能图准确再现了它的离解能和平衡结构特征.首次报导了AsH_2(C_(2v),X~2B_1)自由基对称伸缩振动等值势能图中存在的两个对称鞍点,对应于反应AsH+H→ABH_2,势垒高度约0.1512×4.184 kJ/mol.

Abstract：

The CCSD(T) theory in combination with the cc-pV5Z basis set is used to determine the equilibrium geometry, dissociation energy and vibrational frequencies of AsH_2 (C_(2v), X~2B_1) radical. By comparison, excellent agreement can be found between the present results and the experiments. The values obtained at present are of 0.1508 ran for the equilibrium bond length R_(As-H), 91.2231° for the bond angle ∠ HASH, 2. 8795 eV for the dissociation energy D_e (HAs-H) and 1013.3361 cm~(-1), 2225.1347 cm~(-1) and 2233.7565 cm~(-1) for the vibrational frequencies ν_1(α_1), ν_2(α_1) and ν_3(α_1), respectively. The equilibrium geometry,harmonic frequency and potential energy curve of the AsH(X~3∑~-) radical are calculated at the CCSD(T)/cc-pV5Z level of theory. The ab initio results are fitted to the Murrell-Sorbie function with the least-square method. The spectroscopic parameters are in excellent agreement with the experiments. The analytic potential energy function of the AsH_2 (C_(2v), X~2 B_1) radical is derived by using the many-body expansion theory. This function correctly describes the configuration and dissociation energy of the AsH_2 (C_(2v), X~2B_1) radical. Two symmetrical saddle points have been found at (0.160 nm,0.296 nm) and (0.296 nm,0.160 nm) ,respectively. And the barrier height is equal to 0.1512×4.184 kJ/mol.     

信息技术与物理教学整合的理论与实践

信息技术与学科教学的整合，是我国面向21世纪基础教育教学改革的新视点．它的研究与实践改革了传统的教学观念，为学生主体性、创造性的发挥创设了良好的基础，使学校教育朝着自主的、有特色的课程教学方向发展．那么，如何突破传统的教学模式，充分利用计算机特别是互联网带来的巨大信息量，做好信息技术与物理学科的整合工作，构建新型的教学方式，进一步以现代信息技术为基础来实现教育和教学的创新，这有待于今后长期的努力．本文谈谈我们在学习与实践中的体会．     

Dilaton Black Hole Tunneling Radiation in de Sitter Universe

The Hawking radiation via tunneling from the dilaton black hole in de Sitter universe is investigated using Parikh Wilczek＇s method. We show that if the self-gravitational interaction and energy conservation are taken into account, the modified radiation spectrum deviates from exact thermal spectrum and satisfies the unitary theory.     

工科理论力学教学改革刍义

本文分析了工科理论力学教学改革的几种传统作法,阐述了当教学中存在的主要问题及相应的改革措施。     

共轭性对7-吡啶吲哚类衍生物的结构与电子光谱性质的影响

运用密度泛函理论(DFT)方法对7-吡啶吲哚衍生物的结构及电子光谱性质进行了理论研究.在B3LYP/6-31G(d)水平上得到了7-吡啶吲哚(M)以及5种共轭衍生物(a-e)的几何构型、电子布局以及前线分子轨道;应用含时密度泛函理论(TD-DFT)在B3LYP/6-31+G(d)水平上计算了5种衍生物的电子光谱性质.结果表明,共轭体系的π键成分增大,能级差减小,激发能降低,分子的最大激发波长向长波方向移动,即发生红移.但是,如果分子中的空间位阻增大,则共轭程度降低,发生蓝移.前线分子轨道分析表明该类化合物吸收光谱主要对应分子中的HOMO→LUMO电子跃迁,且为π-π*跃迁.为新型含吲哚基团的光电功能材料的设计合成提供了理论参考.     

杂双核(H)Rh-Cr配合物中乙烯插入RhI—H键反应的密度泛函研究

采用密度泛函理论B3LYP方法研究了配体和配位数对乙烯插入杂双核(CO)₄Cr(m-PH₂)₂RhH(L_n) (L＝CO或PH₃, n＝1或2)配合物中Rh—H键反应的影响. 计算结果表明, 六配位乙烯复合物中乙烯与铑之间轨道相互作用主要为乙烯到铑中心的s供体相互作用; 而五配位乙烯复合物中乙烯与铑中心间相互作用涉及乙烯到铑中心的s供体相互作用和铑到乙烯的p反馈作用. PH₃配体在热力学上不利于该反应. 处于氢配体对位的膦配体能加速乙烯插入反应. 乙烯插入的五配位反应途径占优势. Cr(CO)₄部分的引入降低了乙烯插入反应的活化能.     

光学玻璃挠曲刚度的光学测量方法研究

提出了一种基于光干涉法测量小样品光学平板玻璃挠曲刚度的方法。应用平板理论及牛顿环原理推导了光学平板玻璃挠曲刚度与牛顿环干涉图像之间的解析公式,通过自行设计的牛顿环应力测量装置测量了光学平板玻璃的应力及对应的牛顿环干涉图像,得到了光学平板玻璃的挠曲刚度。实验结果显示:测得的挠曲刚度数据与厂家标称值相比,在应力29.02~38.66N范围内,测量相对误差不超过±6.9%;在应力16.07~29.02N范围内,测量相对误差不超过±11%。     

基于限幅电压开关理论的nMOS四值解发器设计

本文应用限幅电压开关理论设计了两种订从型ｎＭＯＳ