六方相TbPO_4·nH_2O的控制合成及发光性能研究

通过控制PO3-4/Tb3+的量比,在低温水热条件下合成了不同形貌的TbPO4·nH2O纳米晶体。采用X射线衍射仪(XRD)、场发射扫描电镜(FE-SEM)及光致发光光谱(PL)等分析手段对所制备的样品进行了表征。研究了溶液中PO3-4/Tb3+比值变化对产物晶型结构、形貌、晶粒尺寸及发光性能的影响,给出了TbPO4·nH2O纳米粉体的生长机理。实验发现,当PO3-4/Tb3+比值达到60∶1时,产物在过量的磷酸根体系中生长成直径为100~200 nm的TbPO4·nH2O茧状微球,且产物的发光强度最大。PO3-4/Tb3+比值对TbPO4·nH2O形貌和发光性能有重要影响。     

Microstructure and optical properties of nitrogen-doped ZnO film

The nitrogen doping of ZnO film deposited by the magnetron sputtering method is subsequently realized by the hydrothermal synthesis method.The nitrogen-doped ZnO film is preferably(002) oriented.With the increase of hexamethylenetetramine(HMT) solution concentration,the average grain size of the film along the 002 direction almost immediately decreases and then monotonously increases,conversely,the lattice strain first increases and then decreases.The structural evolution of the film surface from compact and even to sparse and rough is attributed to the enhanced nitrogen doping content in the hydrothermal process.The transmission and photoluminescence properties of the film are closely related to grain size,lattice strain,and nitrogen-related defect arising from the enhanced nitrogen doping content with HMT concentration increasing.     

基于TRNSYS的太阳能集热系统能量转化分析与优化

建立了太阳能集热器非稳态数学模型。以工程实例为研究对象,借助于TRNSYS软件,分析不同集热器类型,集热面积,水箱容积,水箱流量对太阳能集热系统性能的影响。优化集热器和水箱设计参数,采用变流量水箱系统,对提高太阳能集热系统综合性能有指导意义。     

Ultra-high-speed single red–green–blue light-emitting diode-based visible light communication system utilizing advanced modulation formats

We report a 3.75-Gb/s visible light communication(VLC) system thatusessingle-carrier frequency-domain equalization(SC-FDE) based on a single red–green–blue(RGB) light-emitting diode(LED),with the measured bit error rates(BERs) under a pre-forward-error-correction threshold of 3.8×10-3.The fundamental characteristics of an RGB-LED-based VLC system are measured.We also compare SC-FDE with OFDM in terms of peak-to-average power ratio and BER performance,which shows that SC-FDE outperforms the OFDM modulation scheme.     

Phase transition and thermal expansion property of Cr_(2-x)Zr_(0.5x)Mg_(0.5x)Mo_3O_(12) solid solution

Compounds with the formula Cr2-xZr0.5xMg0.5xMo3O12（x = 0.0, 0.3, 0.5, 0.9, 1.3, 1.5, 1.7, 1.9） are synthesized, and the effects of Zr4＋ and Mg2＋ co-incorporation on the phase transition, thermal expansion, and Raman mode are investigated. It is found that Cr2-xZr0.5xMg0.5xMo3O12 crystallize into monoclinic structures for x 〈 1.3 and orthorhombic structures for x _〉 1.5 at room temperature. The phase transition temperature from a monoclinic to an orthorhombic structure of Cr2Mo3O12 can be reduced by the partial substitution of （ZrMg）6＋ for Cr3＋. The overall linear thermal expansion coefficient decreases with the increase of the （ZrMg）6＋ content in an orthorhombic structure sample. The co-incorporation of Zr4＋ and Mg2＋ in the lattice results in the occurrence of new Raman modes and the hardening of the symmetric vibrational modes, which are attributed to the MoO4 tetrahedra sharing comers with ZrO6/MgO6 octahedra and to the strengthening of Mo-O bonds due to less electronegativities of Zr4＋ and Mg2＋ than Cr3＋, respectively.     

Transport properties and anomalous fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures

The transport properties and fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures are described. By examining the I-V curves, an anomalous fatigue effect was found and its influences on resistive states were studied. I-V curves combined with C-f spectra were used to directly analyze the transport properties and fatigue effect. Compared to the first I-V cycle state, this structure shows more than one order increase of resistance after 100 cycles of ＂I-V curve training＂. The redistribution of oxygen vacancies in the depletion layer of Ag/Bi0.9La0.lFeO3 is believed to be responsible for the different resistance mechanisms and tenfold magnitude drop in resistance. The resistive switching is understood to be caused by electric field-induced carrier trapping and detrapping, which changes the depletion layer thickness at the Ag/Bi0.9La0.lFeO3 interface.     

环形线负载驱动变曲率反射镜技术

从薄板弹性理论出发,对可实现曲率变化的环形线负载驱动模型进行分析,给出了基于该模型的大镜厚比变曲率反射镜的形变方程.以较小的驱动力实现较大的中心形变为目标,利用MATLAB软件对不同反射镜厚度、驱动环半径下的反射镜形变情况进行模拟计算,结果表明,反射镜厚度范围在2~4 mm之间、驱动环半径数值在反射镜有效半径1/2处最佳.以此为依据,设计并研制了口径为100 mm、厚度为3 mm的铍青铜环形线负载驱动变曲率反射镜结构及原型样片,给出了变曲率反射镜整体结构前10阶的振动模态分析结果.完成装配后,反射镜原型样片的面形精度接近λ/30(λ为波长).对该结构进行极限曲率变化和面形精度保持的验证实验,通过对变曲率反射镜结构进行改进,环形线负载驱动能够实现超过30个波长(632.8 nm)的中心形变,且面形精度的变化与反射镜中心矢高的变化呈弱相关.     

基于LXI总线的压气机试验台测试系统设计及应用

本文介绍了基于LXI总线的压气机测试系统,阐述了该系统的主要特点和优势。试验中对电压、压力、温度、流量和频率等参数进行采集和记录,然后通过系统软件性能分析端提供专业的算法分析接口,接入压气机性能分析计算链以及其他用户自定义的算法进行实时性能分析,从而实现压力机性能的测试及判断。经过试验验证,该系统运行稳定,基于LXI总线的仪器和基于网络的数据发布方式既能满足试验数据实时采集、现场监视,多专业灵活分析等功能,提供灵活的接口形式满足不同专业的实时分析,实现了压气机性能的测试和试验风险的掌控。     

基于OPNET的星地光网络性能测试仿真平台研究

为了测试星地光网络的性能,设计了一种基于OPNET的星地光网络性能测试仿真平台。介绍了平台的总体技术架构,探讨了星间链路建立的条件。采用最大接入仰角与最长服务时间加权的方式,完成星地链路的卫星接入服务;按照切换呼叫优先的策略完成业务传输中的卫星切换服务,确保星地链路不间断的通信能力。根据最小链路代价和首次命中原则,实现星地光网络的路由与波长的动态分配。最后,利用平台的OPNET软件测试了三种星座下的星地光网络性能,测试结果表明：在LEO、MEO和GEO星座下,星地光网络的网络阻塞率分别为10%、40%和54%,平均网络时延分别为0.1s、0.07s和0.054s。测试结果对星地光网络的工程应用具有一定的指导意义。     

溶剂热法制备铜锌锡硫粉末及光学性能研究

以金属氯化物作为金属源,硫脲为硫源,乙二醇为溶剂,聚乙烯吡咯烷酮(PVP)为表面活性剂,采用溶剂热法在较低反应温度下合成了Cu2ZnSnS4(CZTS)粉末。利用X射线衍射仪(XRD)、拉曼光谱(Raman)、扫描电子显微镜(SEM)、高分辨透射电子显微镜(HRTEM)对样品的结构和形貌进行表征。利用紫外-可见光谱(UV-Vis)对样品的光学性能进行研究。结果表明,180℃反应25小时的样品均为锌黄锡矿CZTS颗粒,颗粒形貌为表面花状的微球。当体系中PVP含量为0.2g时,微球尺寸约为2.5μm。当体系中PVP含量为0.3g,0.4g,0.5g时,微球尺寸大约为1.1μm。其中,PVP含量为0.4g的样品分散性较好,在可见区有明显的吸收,用外延法得到其禁带宽度约为1.45eV,与太阳能电池所需的最佳禁带宽度接近。