利用平面σ-芳香性增强电子输运能力

芳香性是有机化学中的重要概念,传统芳香族化合物的芳香性通常源于π电子在环上下平面产生的高度离域,而σ-芳香性则主要源于分子内σ键和轨道重叠,两者均能影响分子的电子传输能力.采用密度泛函理论结合非平衡格林函数（DFT+NEGF）方法对苯、噻吩和呋喃及其衍生物进行了芳香性和电子输运性质的系统研究.计算结果表明,苯、噻吩和呋喃分子的电子输运性质受π-芳香性和σ-芳香性影响,其中σ-芳香性和电子传输正相关,而π-芳香性和电子传输能力成负相关.含有两个芳香环的联苯二巯基（DB）、联噻吩二巯基（DT）和联呋喃二巯基（DF）分子的电子传输能力受分子平面化影响较大,DF中呋喃环表现出比DT中噻吩环更大的NICS（1）_zz值.芳香性化合物具有更好的共平面趋势,通过F原子修饰DT和DF分子产生分子内F…S和F…O非共价相互作用的设计策略可以极大增加分子平面性和刚性.同时,含有分子内F…S和F…O相互作用的虚拟五元环具有平面σ-芳香性特征,有效促进电子沿F…S和F…O路径进行传输,从而提高电子传输能力.本研究有助于进一步理解分子芳香性与电子传输能力之间的内在关系,为未来设计更高效的电子器件提供策略.     

基于晶向优化和Sn合金化技术的一种2.45G弱能量微波无线输能用Ge基肖特基二极管

肖特基二极管是2.45 G弱能量密度无线能量收集系统的核心器件,其性能决定了系统整流效率的上限.从材料设计角度出发,利用晶向优化技术和Sn合金化技术,提出并设计了一种大有效质量、大亲和能和高电子迁移率的Ge基复合半导体.在此基础上,进一步利用器件仿真工具,设定合理的器件材料物理参数与几何结构参数,实现了一种2.45 G弱能量微波无线输能用Ge基肖特基二极管.基于该器件SPICE模型的ADS整流电路仿真表明:与传统Ge肖特基二极管相比,该新型Ge基肖特基二极管在输入能量为–10—–20 d Bm的弱能量工作区域,能量转换效率提升约10%.本文技术方案及相关结论,可为解决2.45 G弱能量密度无线能量收集系统整流效率低的问题提供有益的参考.     

Photochemically Catalyzed Diels-Alder Reaction of Azadienes with 2,3-Dihydrofuran by 2, 4, 6-Triphenylpyrylium Salt： Synthesis of Styrylfuroquinoline Derivatives

Photochemically promoted Diels-Alder reactions of 1, 4-diaryl-1-azabutadienes with 2,3-dihydrofuran were achieved by using 2, 4, 6-triphenylpyrylium tetrafluoroborate as catalyst to produce corresponding styrylfuroquinolines in high yield.     

光纤探针传输效率的研究

用实验方法测量了光纤探针的传输效率随光纤圆锥角的变化关系,给出了传输效率曲线。通过测定探针传输效率的实验可以看到,只要光纤探针的锥角在30°~55°范围内,就具有高透过率、高分辨率纳米微探针。测量了传输效率与光波波长的关系。     

Performance of a double sided silicon strip detector as a transmission detector for heavy ions

The performance of a double sided silicon strip detector （DSSSD）, which is used for the position and energy detection of heavy ions, is reported. The analysis shows that although the incomplete charge collection （ICC） and charge sharing （CS） effects of the DSSSD give rise to a loss of energy resolution, the position information is recorded without ambiguity. Representations of ICC/CS events in the energy spectra are shown and their origins are confirmed by correlation analysis of the spectra from both the junction side and ohmic side of the DSSSD.     

光量子开关

<正>经典信息网络中数据包通过路由器被准确地发送至收信地址。同样,在量子信息网络中,信息在网络节点间的准确传输也需要量子开关(量子路由器)。光子系统是量子通信和量子计算中常用的信息载体,因此光量子开关需要在不破坏光子所携带信息的情况下控制光子的传输路径。最近,以色列雷霍沃特的魏茨曼科学研究所Barak Dayan小组的一项研究有望解决这一问题。他们设计了一个光量子开关,实验原理如图1所示。通过控制耦合于微球光学谐振腔的铷原子量子     

带有三体相互作用的XXZ自旋链模型的隐形传态

本文对基于海森堡XXZ自旋链模型的隐形传态的平均保真度进行了详细计算和分析.通过比较不带三体相互作用、仅带一种三体相互作用和同时带两种三体相互作用的各种海森堡铁磁质和反铁磁质XXZ模型在外磁场正向和反向时的保真度与外磁场和温度的关系,找到了一些理想模型,用这些模型进行隐形传态时需要的外界磁场相对较弱、温度相对较高,这个结论为实验上用海森堡XXZ模型进行隐形传态提供了很好的理论依据.     

Spectral analysis of the UFBG-based acousto optical modulator in V–I transmission matrix formalism

In this study, the V-I transmission matrix formalism （V-I method） is proposed to analyze the spectrum characteristics of the uniform fiber Bragg grating （FBG）-based acousto--opfic modulators （UFBG-AOM）. The simulation results demon- strate that both the amplitude of the acoustically induced strain and the frequency of the acoustic wave （AW） have an effect on the spectrum. Additionally, the wavelength spacing between the primary reflectivity peak and the secondary reflectivity peak is proportional to the acoustic frequency with the ratio 0.1425 nm/MHz. Meanwhile, we compare the amount of calculation. For the FBG whose period is M, the calculation of the V-I method is 4 × （2M-l） in addition/subtraction, 8 × （2M - 1） in multiply/division and 2M in exponent arithmetic, which is almost a quarter of the multi-film method and transfer matrix （TM） method. The detailed analysis indicates that, compared with the conventional multi-film method and transfer matrix （TM） method, the V-I method is faster and less complex.     

Transport properties and anomalous fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures

The transport properties and fatigue effect of Ag/Bi0.9La0.lFeO3/La0.7Sr0.3MnO3 heterostructures are described. By examining the I-V curves, an anomalous fatigue effect was found and its influences on resistive states were studied. I-V curves combined with C-f spectra were used to directly analyze the transport properties and fatigue effect. Compared to the first I-V cycle state, this structure shows more than one order increase of resistance after 100 cycles of ＂I-V curve training＂. The redistribution of oxygen vacancies in the depletion layer of Ag/Bi0.9La0.lFeO3 is believed to be responsible for the different resistance mechanisms and tenfold magnitude drop in resistance. The resistive switching is understood to be caused by electric field-induced carrier trapping and detrapping, which changes the depletion layer thickness at the Ag/Bi0.9La0.lFeO3 interface.     

Phase imaging with rotating illumination

A modified extended-ptychographical-iterative-engine （ePIE） algorithm is proposed to overcome the dis- advantages of ePIE technique and reduce the influence of stage hysteresis or backlash error. The exit wave of a rotatable ＂screen＂ illuminated by plane wave is used as the illumination on the specimen, and the complex transmission functions of the rotatable object and specimen can be simultaneously reconstructed. Compared with the standard x - y scanning PIE algorithm, the proposed algorithm can completely avoid the influence of stage hysteresis （or backlash error）. The proposed algorithm also has higher convergence s!oeed and better accuracy than the standard PIE algorithm.