(1,2-μ2-L1)(1,2-μ2-L2)十羰基合三锇振动光谱的理论计算[L1, L2=H, Cl, Br, I]

用密度泛函理论和从头计算(abinitio)方法,在B3LYP CEP 4G ,B3LYP LanL2DZ和RHF CEP 4G ,RHF LanL2DZ水平上,全优化计算了(1,2 μ2 H) (1,2 μ2 L)Os3(CO) 1 0 (L :Cl,Br,I)的分子几何构型和电子结构;在RHF CEP 4G水平上,全优化计算了(1,2 μ2 L) 2 Os3(CO) 1 0 (L :H ,Cl,Br,I)的分子几何构型和电子结构。计算结果表明,在这些体系中,电子由Os(CO) 3向Os(CO) 4转移。用RHF CEP 4G对这七个簇合物进行了简正振动频率分析,在计算得到振动频率及吸收强度的基础上,模拟了稳定平衡结构的红外光谱图,并对计算结果进行了比较和讨论。     

干涉型光纤传感器相位生成载波解调方法改进与研究

提出了基于干涉型光纤传感器的相位生成载波解调方法（PGC）的改进方法,通过算法上的改进和增加抗混叠滤波器,有效地改善了解调结果,并大大降低了系统的采样频率,结论对设计干涉型光纤传感器解调系统有重要的参考意义     

激光诱导水体频率上转换的荧光发射

用Nd：YAG的二倍频532 nm激光对几种不同水体的激光诱导荧光(LIF)光谱进行了测量,利用特征光谱荧光标记(SFS)技术指认出水体中溶解有机物(DOM)、叶绿素a(Chl a)及类胡萝卜素等物质的特征光谱带。指出在455 nm波长处具有较大强度的荧光峰是附属色素中抗氧化作用的类胡萝卜素(PPC)的贡献。提出了激光诱导PPC荧光频率上转换发射的动力学模型。     

光学频率标准与光钟的实现

综述了时间频率标准的发展过程.对构成光学频率标准的四个要素,即激光冷却、激光稳频、离子捕陷和光学频率梳进行了系统的介绍.详细描述了光钟的原理与系统构成,并对光学频率标准与光钟的应用前景进行了展望.     

分数阶R Lα Cβ并联谐振电路的等效电路

R L C并联谐振电路是一种非常重要的谐振电路, 将其推广到分数阶, 并根据等效原理, 得到与分数阶 R Lα Cβ 并联电路等效的分数阶R ′ L ′ α C ′ β 并联电路及整数阶R ″ L ″ C ″并联电路     

扇形波导谐振宽边纵缝的归一化电导

扇形波导可作为高功率微波圆柱共形波导缝隙阵天线的基本单元。分析了扇形波导中主模场分量,根据实际情况对主模场进行了合理近似。采用互易定理推导由波导主模横向场分量和缝隙场分量表示的波导场分量的前向或后向散射系数。根据波导传输线理论,将波导宽边纵缝等效为并联导纳,再根据波导边界条件得到扇形波导宽边谐振纵缝的归一化电导与波导散射系数之间的关系式。根据缝隙天线与振子天线的互补关系得到扇形波导谐振缝隙的辐射阻抗,结合波导功率平衡关系得到由波导横向场散射系数表示的缝隙辐射功率表达式,得到归一化电导的与谐振宽边纵缝的偏移位置、缝隙宽度、波导波长以及扇形波导尺寸参数之间的解析表达式。给出了算例,在波导中间区域,通过商用软件计算得到的电导与理论公式结果基本吻合。     

基于平面超材料的Fano谐振可调谐研究

基于两段相同金属分裂环谐振器构成的单层结构, 从理论及实验方面研究了平面超材料的可调谐Fano谐振. 实验测量了平面超材料对TE和TM入射波的电磁响应, 利用电磁波的入射角度控制Fano谐振的强度, 实现了谐振的开关特性, 谐振频率红移可达到21%. 基于有限元法给出了平面超材料的场分布, 强的正常色散表明平面超材料的电磁响应可类比经典电磁诱导透明现象, 仿真与实验结果相符合. 对称结构超材料Fano谐振的开/关特性为超材料性能的可调谐控制提供了有效途径.     

Thermal Properties of Materials Characterized by Scanning Electron-Acoustic Microscopy

A modified technique of scanning electron-acoustic microscopy is employed to determine thermal diffusivity of materials. Using the dependence of the electron-acoustic signal on modulation frequency of the electron beam, the thermal diffusivity of materials is characterized based on a simplified thermoelastic theory. The thermal diffusivities of several metals characterized by the modified scanning electron-acoustic microscopy are in good agreement with the referential values of the corresponding materials, which proves that the scanning electronacoustic microscopy can be used to characterize the thermal diffusivity of materials effectively. In addition, for micro-inhomogeneous materials, such as biological tissues, the macro-effective （average） thermal diffusivities are characterized by the technique.     

Luminescence and ESR Studies of CaS：Dy Phosphor

CaS phosphor activated with Dy ions is prepared by the solid-state diffusion method. The phosphor is characterized by x-ray powder diffraction, thermogravimetric analysis and photoiuminescence. Defect centres formed in CaS：Dy are studied using the technique of electron spin resonance. The thermoluminescence glow curve shows peaks at around 117℃ and 345℃. Irradiated CaS：Dy exhibits ESR lines due to defect centres. The thermal annealing behaviour of one of the defect centres appears to correlate with the TL peaks at 117℃ and 345℃. This centre is characterized by an isotropic g-value of 2.0035 and is assigned to an F^＋ centre.     

The 1/f noise in multiwalled carbon nanotubes

The $1/f$ noise in multiwalled carbon nanotubes bundles has been investigated between the frequency range of 0.1 to 30 Hz. At room temperature the noise spectrum is standard 1/f, and its level is proportional to the square of the bias voltage. With decreasing temperature the noise level also decreases. At 4.2 K the noise level follows a non-monotonic dependence against the bias voltage, showing a peak at a certain bias voltage, meanwhile its frequency dependence also deviates from the 1/f trend. This anomalous behaviour is discussed within the picture of environmental quantum fluctuation of charge transport in the samples.