一个新的IEC61000-4-2标准ESD电流解析表达式

分析了两个ESD标准电流波形表达式,并提出一个新的基于脉冲函数来描述ESD标准电流的解析表达式,该表达式符合最新的标准IEC61000-4-2,在零时刻的电流及其微分部为0,且波形与实际测量波形基本吻合。     

FREE VIBRATION ANALYSIS OF LATTICE SANDWICH BEAMS UNDER SEVERAL TYPICAL BOUNDARY CONDITIONS

Free vibration problems of lattice sandwich beams under several typical boundary conditions are investigated in the present paper. The lattice sandwich beam is transformed to an equivalent homogeneous three-layered sandwich beam. Unlike the traditional analytical model in which the rotation angles of the face sheets and the core are assumed the same, different rotation angles are considered in this paper to characterize the real response of sandwich beams. The analytical solutions of the natural frequencies for several typical boundary conditions are obtained. The effects of material properties and geometric parameters on the natural frequencies are also investigated.     

二次解析-冷阱捕集-气相色谱法测定大气中总挥发性有机化合物

挥发性有机化合物(VOC′s)是指室温下易挥发的一类化合物,虽然目前还没有明确的定义,但多数定义都是基于化合物的物理化学性质。总挥发性有机污染物(TVOC′s)即空气中沸点在50℃～260℃之间的有机化合物的总称。挥发性有机化合物浓度虽低,但大多数有毒性、刺激性、致癌性,例如苯会导致白血病,三氯甲烷对肺、肾、血液造成较大的影响,可通过呼吸途径进入人体,对人体健康造成潜在威胁。同时,具有特殊气味的化合物又能导致人体各种不适反应[1-4]。     

读者·作者·编者

《化学分析计量》入选美国《化学文摘》(CA)千种表根据中国高等学校自然科学学报研究会资料,美国《化学文摘》数据库总计10000种以上期刊,中国期刊已超过1412种;引文频次最高的1000种期刊表中,收录中国(含港台)期刊236种,其中《化学分析计量》在千种表中排名第772。我们将一     

三次Gauss和及二项指数和的混合均值

我们用三角和的性质研究一类三次Gauss和与两项指数和混合均值的计算问题,并给出一个精确的计算公式.     

对称平板传输线分布电容的计算

介绍了共形映射法及其在静电场中的应用.求出了对称平板传输线的分布电容.     

数形结合求圆锥曲线的离心率取值范围问题

圆锥曲线的离心率取值范围是解析几何中的一个重点问题,也是高考难点.学生面对此类问题总是无法下手,即使是思路清晰,却由于运算量大而做不出结果.笔者认为此类问题如果借助于数形结合,将会迎刃而解,从而达到事半功倍的效果.     

Explanation of Theoretical Mechanism of Isomerization of L-Alanine Conformation for Experimental Results

B3LYP/6-31＋＋G＊＊ method was applied to investigate the mechanism of alanine isomerization.12 minima and 22 transition states were obtained after optimization and several paths of isomerization were found.It is found that intramolecular single-bond rotation and proton transfer might lead to isomerization.The energy barrier of C–N bond rotation was lower than 2.52 kcal·mol 1,while the energy barrier ranges of the rotation of C–C and C–O were separately 0.43~ 7.01 and 4.69~12.19 kcal·mol 1,and the minimum energy barrier of proton transfer was 30.76 kcal·mol 1.The most probable isomerization path and mechanism for the two most stable conformations was discussed to find that the highest energy barrier to be crossed in this path was 11.87 kcal·mol 1.In order to understand the microscopic nature why only 4 conformations were detected in the experiment,thermodynamic properties of all conformations at the experimental temperature of 391 K was calculated.It is found that conformations XII,XI,X and IX can only unidirectionally convert into conformations rapidly with low energy and vanish immediately.The other conformations were distributed according to Maxwell-Boltzman＇s law,and the distribution probabilities of conformations I,II,III,IV,V,VI,VII and VIII were respectively 27.2%,26.5%,25.8%,6.4%,5.2%,4.8%,2.5% and 1.6%.Conformations I,II and III with bigger probability and stronger absorption peak were easy to detect in the experiment.Conformation IV had a relatively smaller probability（6.4%） and weak absorption peak which,however,could also be identified.The other conformations had too small probability to identify in the spectrum.     

深入理解化学平衡常数及其应用——对2019年全国理综(Ⅰ卷)化学第28题的分析

在已有的化学平衡常数教学的基础上,提出认知化学平衡常数的新角度--化学平衡常数的多种表达式。依据教材中用浓度表示的化学平衡常数并结合理想气体状态方程,推导用物质的量分数及分压表示的化学平衡常数表达式,分析3者之间的区别和联系,进而应用化学平衡常数的多种表达形式解决2019年全国(Ⅰ卷)化学第28题中的相关问题,使学生深入理解解答这道高考试题的关键所在。同时,拓展了学生对平衡常数的认识,提升了学生灵活应用平衡常数解决问题的能力。