黑米花色苷酰化修饰红外光谱分析

黑米花色苷易受外部环境影响发生降解致使局部分子结构破坏而使营养价值和保健功能有所下降。利用有机酸提供酰基对黑米花色苷进行修饰来提高花色苷结构的稳定性。利用红外光谱分析经咖啡酸酰化修饰黑米花色苷的结构变化。结果表明：黑米花色苷酰化修饰前后于官能团区3 650~3 200和1 680~1 620 cm-1处均有吸收峰,且其于指纹区1 282.68和1 277.51 cm-1处出现酚羟基吸收峰,于1 056.07和1 054.03 cm-1处出现醇羟基吸收峰,719.90和719.71 cm-1处出现苯环上C-H面外弯曲振动吸收峰。由此可见,黑米花色苷酰化修饰后主要结构框架仍为花色苷的芳环结构。此外,黑米花色苷酰化修饰前后于1 900~1 650 cm-1间1 714.28和1 728.13 cm-1处均出现共轭羰基的特征吸收峰,对应于可直接连接在苯环上的α-羰基结构,由此说明黑米花色苷结构中存在着酰基基团。黑米花色苷经酰化修饰后红外图谱于1 517.20 cm-1处出现新吸收峰,其正好处于1 800~900 cm-1双键(不含氢)伸缩振动区,指纹区876.65 cm-1处亦出现了苯环上的C-H面外弯曲振动吸收峰。与之相呼应在经二阶导数处理后红外光谱图中在2 500～2 000 cm-1间出现了新的波动,此波段为累积双键伸缩振动区,而官能团区3 650~3 200 cm-1间3 370.20 cm-1处的吸收峰正好处于多分子缔合区。由此可见,在咖啡酸作为酰基供体,酰化修饰黑米花色苷时由于分子间的重新缔合于结构中引入了新的酰基基团而呈现出一种双酰化的空间结构。黑米花色苷酰化结构中有机酸与糖链相连,将有机酸置于2-苯基苯并吡喃骨架的表面,这种堆积作用模式可以较好地抵抗水的亲核攻击和其他降解反应进而提高黑米花色苷结构的稳定性。     

溶液密度法测定糖水溶液中糖分含量——推荐一个基础化学实验

介绍了一个基础化学实验——溶液密度法测定糖水溶液中糖分含量。该实验通过糖分含量-密度工作曲线测定糖水溶液中的蔗糖含量,并估算饮料中的糖含量。实验涉及多项化学实验基本操作以及作图法等实验技能,推荐作为大一学生的前期实验开设。     

A Fully Vectorial Effective Index Method for Accurate Dispersion Calculation of Photonic Crystal Fibres

A fully vectorial effective index method is developed for accurate dispersion calculation of photonic crystal fibres （PCFs）. In order to improve the accuracy of the model, different values for the effective core radius are used when PCFs have different fibre parameters. The accuracy of our approach is demonstrated by comparing our results with other numerical and experimental results reported in literature. It is found that the accuracy of the fully vectorial effective index method is improved and our results agree well with accurate numerical results obtained by other methods as well as the previously reported experimental data.     

Conditional Symmetries and Solutions to a Class of Nonlinear Diffusion-Convection Equations

The present paper discusses a class of nonlinear diffusion-convection equations with source. The method that we use is the conditional symmetry method. It is shown that the equation admits certain conditional symmetries for coefficient functions of the equations. As a consequence, solutions to the resulting equations are obtained.     

New exact solitary wave solutions to generalized mKdV equation and generalized Zakharov--Kuzentsov equation

In this paper, based on hyperbolic tanh-function method and homogeneous balance method, and auxiliary equation method, some new exact solitary solutions to the generalized mKdV equation and generalized Zakharov--Kuzentsov equation are constructed by the method of auxiliary equation with function transformation with aid of symbolic computation system Mathematica. The method is of important significance in seeking new exact solutions to the evolution equation with arbitrary nonlinear term.     

An exact solution of Fisher equation and its stability

In this paper, the Fisher equation is analysed. One of its travelling wave solution is obtained by comparing it with KdV--Burgers (KdVB) equation. Its amplitude, width and speed are investigated. The instability for the higher order disturbances to the solution of the Fisher equation is also studied.     

变系数广义KdV方程新的类孤波解和精确解

用普通KdV方程作变换，构造变系数广义KdV方程的解，获得了变系数广义KdV方程新的Jacobi椭圆函数精确解、类孤波解、三角函数解和Weierstrass椭圆函数解. 关键词： KdV方程 变系数广义KdV方程 类孤波解 精确解     

原子吸收光谱间接测定胱氨酸的研究

胱氨酸(Cystine,Cys)在碱性条件下与新生成的ZnS悬浮液反应,生成可溶性碱式胱氨酸锌配合物,再用塞曼原子吸收光谱测定溶液中的总锌浓度即可间接的得到胱氨酸的含量.优化了测定的条件,在pH 9.40的2%硼砂底液中于室温下,使胱氨酸试液与新生成的ZnS悬浮液反应20min,离心分离后测定上层清液锌的FAAS响应.在所选定的条件下胱氨酸测定的线性浓度范围为0-450μg·mL-1,特征浓度为4.40μg·mL-1,检出限为4.20μg·mL-1.该法用于样品中的胱氨酸测定,其相对标准偏差RSD为4.45%(n=7),方法的回收率在70.8%-105.8%之间.并对测定机理进行了探讨.     

非线性Schringer方程的Jacobi椭圆函数包络解

通过函数变换和扩展Jacobi椭圆函数展开法,利用吴消元法,借助符号运算软件Maple,得到非线性Schringer方程丰富的包络形式精确解,特别是由两个Jacobi椭圆函数表示的精确解.当模数m→1或m→0时,一部分解退化为双曲函数或三角函数表示的解,F-展开法和扩展的F-展开法得到的精确解是本文结果的特例.     

非线性Schr(o)inger方程的Jacobi椭圆函数包络解

通过函数变换和扩展Jacobi椭圆函数展开法,利用吴消元法,借助符号运算软件Maple,得到非线性Schr(o)inger方程丰富的包络形式精确解,特别是由两个Jacobi椭圆函数表示的精确解.当模数m→1或m→0时,一部分解退化为双曲函数或三角函数表示的解,F-展开法和扩展的F-展开法得到的精确解是本文结果的特例.