全文获取类型
收费全文 | 1800篇 |
免费 | 296篇 |
国内免费 | 308篇 |
专业分类
化学 | 904篇 |
晶体学 | 74篇 |
力学 | 115篇 |
综合类 | 37篇 |
数学 | 362篇 |
物理学 | 912篇 |
出版年
2024年 | 11篇 |
2023年 | 57篇 |
2022年 | 76篇 |
2021年 | 55篇 |
2020年 | 48篇 |
2019年 | 84篇 |
2018年 | 44篇 |
2017年 | 60篇 |
2016年 | 76篇 |
2015年 | 79篇 |
2014年 | 122篇 |
2013年 | 126篇 |
2012年 | 127篇 |
2011年 | 145篇 |
2010年 | 129篇 |
2009年 | 150篇 |
2008年 | 97篇 |
2007年 | 106篇 |
2006年 | 105篇 |
2005年 | 80篇 |
2004年 | 97篇 |
2003年 | 96篇 |
2002年 | 70篇 |
2001年 | 87篇 |
2000年 | 56篇 |
1999年 | 48篇 |
1998年 | 43篇 |
1997年 | 26篇 |
1996年 | 16篇 |
1995年 | 23篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 11篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1989年 | 11篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1983年 | 1篇 |
排序方式: 共有2404条查询结果,搜索用时 15 毫秒
32.
用C语言开发的教学软件,将“旋转磁场”的形成与旋转过程以动态,静态和分解的形式演示出来,能清楚地揭示了磁场的来源与旋转的成因,显示微机辅助教学的优势。 相似文献
33.
金属的电抛光应用越来越广泛.但电抛光机理至今仍不很清楚.我们曾用 XPS 和AES 研究了不同槽电压下电抛光铜表面的组成和物种,确认其表面均为纯铜,不存在含磷固体膜.本文用 XPS 研究电抛光液中1-羟基乙叉-1,1-膦酸(HEDP)浓度、抛光液的 pH 及其接受体(H_3PO_4,HEDP 和 HEDP H_3PO_4)变化时铜的表面组成,并进一步证明,电抛光时形成的粘液膜是水溶性膜,铜表面在不同抛光条件下并不形成难溶的含磷固体膜.通过电子能谱对固化后粘液膜组成和深度分布的研究确定,粘液膜可能是铜的多核聚合混合配体配合物,其组成可近似地表示为[Cu_4(PO_4)(HEDP)]_n. 相似文献
34.
35.
本文通过异氰酸酰化反应合成了含有脲基的苯乙炔新型配体及以它作为辅助配体的4′-(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物,初步研究了铂(II)络合物的光物理性质,发现由于脲基的存在,当浓度大于3.32×10-5mol/L时铂(II)络合物能够发生分子间簇集. 相似文献
36.
37.
The threat and global concern of energy crises have significantly increased over the last two decades. Because solar light and water are abundant on earth, photocatalytic hydrogen evolution through water splitting has been considered as a promising route to produce green energy. Therefore, semiconductor photocatalysts play a key role in transforming sunlight and water to hydrogen energy. To date, various photocatalysts have been studied. Among them, TiO2 has been extensively investigated because of its non-toxicity, high chemical stability, controllable morphology, and high photocatalytic activity. In particular, 1D TiO2 nanofibers (NFs) have attracted increasing attention as effective photocatalysts because of their unique 1D electron transfer pathway, high adsorption capacity, and high photoinduced electron–hole pair transfer capability. However, TiO2 NFs are considered as an inefficient photocatalyst for the hydrogen evolution reaction (HER) because of their disadvantages such as a large band gap (~3.2 eV) and fast recombination of photoinduced electron–hole pairs. Therefore, the development of a high-performance TiO2 NF photocatalyst is required for efficient solar light conversion. In recent years, several strategies have been explored to improve the photocatalytic activity of TiO2 NFs, including coupling with narrow-bandgap semiconductors (such as ZnIn2S4). Recently, microwave (MW)-assisted synthesis has been considered as an important strategy for the preparation of photocatalyst semiconductors because of its low cost, environment-friendliness, simplicity, and high reaction rate. Herein, to overcome the above-mentioned limiting properties of TiO2 NFs, we report a 2D/1D ZnIn2S4/TiO2 S-scheme heterojunction synthesized through a microwave (MW)-assisted process. Herein, the 2D/1D ZnIn2S4/TiO2 S-scheme heterojunction was constructed rapidly by using in situ 2D ZnIn2S4nanosheets decorated on 1D TiO2 NFs. The loading of ZnIn2S4 nanoplates on the TiO2 NFs could be easily controlled by adjusting the molar ratios of ZnIn2S4 precursors to TiO2 NFs. The photocatalytic activity of the as-prepared samples for water splitting under simulated solar light irradiation was assessed. The experimental results showed that the photocatalytic performance of the ZnIn2S4/TiO2 composites was significantly improved, and the obtained ZnIn2S4/TiO2 composites showed increased optical absorption. Under optimal conditions, the highest HER rate of the ZT-0.5 (molar ratio of ZnIn2S4/TiO2= 0.5) sample was 8774 μmol·g-1·h-1, which is considerably higher than those of pure TiO2 NFs (3312 μmol·g-1·h-1) and ZnIn2S4nanoplates (3114 μmol·g-1·h-1) by factors of 2.7 and 2.8, respectively. Based on the experimental data and Mott-Schottky analysis, a possible mechanism for the formation of the S-scheme heterojunction between ZnIn2S4 and TiO2 was proposed to interpret the enhanced HER activity of the ZnIn2S4/TiO2heterojunctionphotocatalysts.
相似文献
38.
39.
40.
建立了微波辅助萃取 (MAE) /气相 质谱联用法 (GC MS)测定蔬菜样品中二嗪磷、对硫磷、水胺硫磷的分析方法 ,研究了不同溶剂的萃取效率。选择二氯甲烷为萃取溶剂 ,采用二因素三水平的正交设计实验优化了萃取溶剂体积和萃取时间。方法的线性范围分别为二嗪磷和对硫磷 4ng/ g~ 40 0ng/ g、水胺硫磷 2 0ng/ g~ 40 0ng/ g,检出限分别为二嗪磷 0 2 9ng/g、对硫磷 1 70ng/g、水胺硫磷 2 30ng/g。测定 2 0 0 0ng/g和 50 0ng/g加标蔬菜样品 ,回收率为 72 2 %~ 1 0 2 0 % ,RSD为 1 5 %~ 1 1 0 %。。 相似文献