无电极电光电场传感器灵敏度提高的研究

从提高灵敏度角度出发,理论上分析了无电极电光电场传感器电极长度与灵敏度和带宽的关系.通过比较不同结构的传输函数,验证平衡检测方式的可行性,最后选取使用平衡检测的三端口结构作为实验器件结构,从而为器件制作的可行性方案从理论上作了验证.     

Effects of Dual-Electrode Biasing on Er in a Toroidal Plasma

Two externally biased electrodes were inserted into the plasma on the KT-5C tokamak to test the effects on modifying the radial electric field Er, other than single biasing. Using various combinations of biasing voltage,the influences of double biasing are compared with the single biasing. It turns out that the effect of dual-biasing is also effective as a single one, but the outer electrode seems to be shielded by the inner one and show less influence. The results clearly show that the radial electric field Er changed by external biasing is intrinsically an effect localized at the edge of the plasma, which is caused by the electrode induced radial current; and dualelectrode biasing using the method similar to the single biasing seems not to be able to increase more distinctly the peaking effect on Er than the single biasing.     

Enhancement of Overall Photovoltaic Efficiency by Changing the Position of the Attaching Group -RSO3- on the Hemicyanine Dye Molecules

A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%.     

新型的不锈钢镀Pt（Ir）电极

应用欠电位沉积与锚定效应，研制了一种新型的不锈钢镀Ｐｔ（Ｉｒ）电极，此电极具有优越的电化学特性，可望用于微传感器。     

钾离子选择电极及其在生物医学中的应用进展

钾离子选择电极的研究一直是一个非常活跃的题目,具有令人瞩目的发展。本文就其研制、测试法与应用方面的新进展进行评述。     

脂溶性酞菁钴(III)为载体的高选择性亚硝酸根PVC膜电极

以自制的4,4',4',4''-四特丁基酞菁钴(II)为原料合成二氯4,4',4',4''-四特丁基酞菁钴(III)。以此为载体制备PVC膜电极。该电极的电位选择性次序明显不同于Hofmeister次序, 其最佳 响应斜率为-52mV/pNO2^-, 线性范围为3×10^-^5～1×10^-^1mol.dm^-^3NaNO2。通过改变配合物轴向的配位阴离子, 用紫外-可见光谱法对电极的响应机理作了初步探讨。     

关于离子造反性电极分析中的等电位差—标准加入法的探讨

本文提出了一种离子选择性分析方法，即等电位差－标准加入法。本文法已用于氟的测定。本文法的影响因素少，准确度好，操作及计算简便。     

L-半胱氨酸自组装膜电极上锌离子的电化学行为及分析应用

锌是人体必需的微量元素 ,也是金属酶的组成部分和酶的激活剂 ,目前已知有 80多种酶的活性与锌的存在有关 ,因此研究锌在生物分子 (如Ｌ 半胱胺酸 )自组装膜结构中的电化学行为 ,对于研究和了解生物体内生命物质的电子转移及生命现象的本质具有重要意义。本文研究Ｚｎ2 +在Ｌ 半胱氨酸自组装修饰金电极[1～3] ,Ｃｙｓ/ＳＡＭ/Ａｕ上的电化学行为 ,建立了测定Ｚｎ2 +浓度的新方法 ,用于人体发样中痕量Ｚｎ2 +的测定 ,与目前所报道的锌的测定方法[4] 相比 ,具有快速、准确、灵敏度高等特点。1　实验部分1 1　仪器与试剂ＣＨＩ660型电化学工作…