14β-甲磺酰氧基对映-贝壳杉二萜重排反应

本文研究了一类具有15-C与16-C单键的14β-甲磺酰氧基对映-贝壳杉烷(烯)(6,7和8)在Zn-EtOH体系中的重排反应, 它们均能重排成6, 7, 5, 5并环系统的化合物3, 12, 13a和13b。8重排时生成一个8-OEt化合物, 为这类化合物重排时经过阳离子中间体提供了一个证据。     

拟线性常微分方程在半无限区间的边值问题

Existence of positive solution is established for boundary value problems of non-singular for a class quasi-linear ordinary differential equation on the semi-infinite interval. The results are obtained by using the nonlinear alternative of Leray-Schauder method.     

示波极谱法测定保健药品中的褪黑激素

褪黑激素与HNO3在室温下发生硝基化反应生成褪黑激素的硝基化合物,加NH3·H2O终止反应并用甲酸 甲酸钠缓冲液控制反应液pH3,在原点电位-0.20V(vs.SCE),测量-0.50V处的二阶导数峰高。方法检出限为1μg/L,线性范围为1μg/L～200μg/L,相对标准偏差为2.6%～8.0%,加标回收率为92 0%～110 0%,测定结果与高效液相色谱法进行比较,无显著性差异。     

水平中段模糊算子

本文提出“水平中段模糊算子”的概念,并且应用清晰域的观点研究了它们的性质,从而在实质上较文[1]更深刻地揭示了一般模糊算子的性质,为实际应用各种模糊算子提供了进一步的依据。     

Effects of Substrate Temperature on Helium Content and Microstructure of Nanocrystalline Titanium Films

Helium-charged nanocrystalline titanium films have been deposited by HeAr magnetron co-sputtering. The effects of substrate temperature on the helium content and microstructure of the nanocrystalline titanium films have been studied. The results indicate that helium atoms with a high concentration are evenly incorporated in the deposited titanium films. When the substrate temperature increases from 60℃ to 350℃ while the other deposition＇parameters are fixed, the helium content decreases gradually from 38.6 at.% to 9.2at.%, which proves that nanocrystalline Ti films have a great helium storage capacity. The 20 angle of the Bragg peak of （002） crystal planes of the He-charged Ti film shifts to a lower angle and that of （100） crystal plane is unchanged as compared with that of the pure Ti film, which indicates that the lattice parameter c increases and a keeps at the primitive value. The grain refining and helium damage result in the diffraction peak broadening.     

牛顿弦截法预估校正迭代格式的收敛阶

研究如下形式的牛顿弦截法的预估校正(P.C.)格式:P(预估):~xk+1=xk-(xk-xk-1)f(xk)f(xk)-f(xk-1)C(校正):xk+1=xk-(~xk+1-xk)f(xk)f~(xk+1)-f(xk)证明了它的收敛阶为2.618.     

光泽精化学发光体系的研究与应用

对光泽精化学发光体系的动力学性质、荧光光谱、化学发光光谱及化学发光机理进行研究和探讨。详细研究了光泽精 - H2 O2 - Co( )流动注射化学发光体系的最佳分析条件。结果表明 ,当光泽精 (L c)为 2 .5×10 - 5mol/L、H2 O2 为 0 .5 mol/L、Na OH为 0 .4 mol/L、CTMAB为 2 .0× 10 - 5mol/L时 ,测定 Co( )的校准曲线线性范围为 0 .0 5— 2 0 0μg/m L ,检出限为 0 .0 1μg/m L。对 10μg/m L Co( )连续测定 7次 ,相对标准偏差为 1.7%。     

~ Transform Demonstration of Dark Soliton Solutions Found by Inverse Scattering

One of the basic problems about the inverse scattering transform for solving a completely integrable nonlinear evolutions equation is to demonstrate that the Jost solutions obtained from the inverse scattering equations of Cauchy integral satisfy the Lax equations. Such a basic problem still exists in the procedure of deriving the dark soliton solutions of the NLS equation in normal dispersion with non-vanishing boundary conditions through the inverse scattering transform. In this paper, a pair of Jost solutions with same analytic properties are composed to be a 2 × 2 matrix and then another pair are introduced to be its right inverse confirmed by the Liouville theorem. As they are both 2 × 2 matrices, the right inverse should be the left inverse too, based upon which it is not difficult to show that these Jost solutions satisfy both the first and second Lax equations. As a result of compatibility condition, the dark soliton solutions definitely satisfy the NLS equation in normal dispersion with non-vanishing boundary conditions.