甲基丙烯酸N,N-二甲氨基乙酯与丙烯酰β-环糊精共聚水凝胶的合成及其性能研究

用不同的方法合成了两种结构不同的丙烯酰 β 环糊精酯 (β CD 3 A和 β CD 6 A) ,以此为单体与甲基丙烯酸N ,N 二甲氨基乙酯 (DMAEMA)通过氧化还原自由基引发聚合 ,合成出两类含 β 环糊精结构单元的新型水凝胶 .用核磁共振 ,红外光谱及元素分析对两种单体及共聚物的结构和组成进行了表征 .溶胀实验结果表明 ,两类水凝胶均具有较好的pH、温度及离子强度敏感性 ,且因其交联网络结构不同 ,其溶胀性能有所差异     

电沉积羟基磷灰石/TiO2复合涂层

结合强度;电沉积羟基磷灰石/TiO2复合涂层     

芳纶纤维/SMPU-SiO2复合材料的界面性能研究

选用形状记忆聚氨酯(SMPU)和正硅酸乙酯(TEOS)为前驱体,固体酸对甲基苯磺酸(PTSA)为催化剂,利用空气中的水分为水解水源,通过溶胶-凝胶法原位制备了形状记忆聚氨酯与二氧化硅( SMPU-SiO2)杂化材料,并将杂化材料应用于芳纶纤维增强的柔性复合材料中,以期改善芳纶纤维与基体的界面性能.同时,针对芳纶纤维表面...     

Solvent Effect on Characteristic Vibration of IR Spectrum of 4,4'-Dibromodiphenyl Ether

The optimal geometry, IR spectrum and vibration assignment of 4,4＇-dibromodiphenyl ether（BDE-15） in gas phase were calculated via the density functional theory（DFT） at the level of B3LYP/6-3 l＋G（d）. Based on the vi- bration assignment, the calculation of vibration frequencies and intensities of 5 main vibration types of BDE-15 in 25 kinds of solvents was carried out by means of a self-consistent reaction field（SCRF） theoretical model at the level of B3LYP/6-31＋G（d） to analyze the solvent effect on the vibration of IR spectrum of BDE-15. To study the solvent ef- fect further, C--O asymmetric stretching vibration fluctuating, which is relatively acute in both vibration frequency and intensity, was selected as the characteristic vibration to establish different linear solvation energy relation（LSER） models for solvent categoring. Solvent parameters（a, /3, ~r＊）, acceptable number（AN） and quantitative structure- activity relationship（QSAR） models were established via chemical quantum parameters of solvent moleculer, which were first been introduced to investigate different solvent-solute interaction mechanisms in alcoholic and non-alcoholic solvents on molecular level. At last, a single solvent molecule was embedded in the framework of po- larizable continuum model（PCM） to validate the effect of hydrogen bonding on solvent-solute interaction in alcohol solvents. The obtained results show that 5 main vibration types of BDE-15 in different solvents have small variation range in frequency and intensity and all the vibration frequencies in solvents are lower than those in gas phase, de- creasing along with the increasing of the dielectric Constant（e） of solvents exponentially. In contrast, all the vibration intensities in solvents are greater than those in gas phase and present positive exponential trend. Twenty-five solvents were divided into two categories（non-alcoholic solvents and alcoholic solvents） by LSER. The CmO asymmetric stretching vibration was mainly reg     

Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement

A novel water-soluble porphyrin[5,10,15,20-tetra（3-ethoxy-4-hydroxy-5-sulfonate）phenyl porphyrin, H2TEHPPS] was designed and synthesized, which could be used as a potential fluorescence sensor to detect temperature changes. The studies were performed in solution phase and the concentration of H2TEHPPS was 2.0×10^-5 mol/L. The optical properties of H2TEHPPS were investigated based on the UV and fluorescence spectra. The results show that the fluorescence intensity of H2TEHPPS is directly proportional to temperature in the range of 293-353 K So H,TEHPPS can be used as a molecular temoerature sensor in biomedical and other fields.     

原位固相接枝改性碳酸钙/聚丙烯复合材料的制备

用马来酸酐（MAH）在碳酸钙（CaCO3）表面引入双键,通过原位固相接枝法将聚丙烯蜡（PPW）化学键合在CaCO3表面,制得3种接枝率的CaCO3-MAH-PPW。 将这3种改性CaCO3填充聚丙烯（PP）制备复合材料,研究了PP/CaCO3界面作用对复合材料强度的影响。 结果表明,CaCO3表面经PPW接枝改性后在PP中的分散性提高,与PP相容性变好;随着改性CaCO3表面PPW接枝率的提高,CaCO3与PP之间界面作用逐渐增强。 当PPW接枝率为4.48 mg PPW/g CaCO3时,CaCO3与PP之间的界面作用最强,复合材料拉伸强度下降最小,杨氏模量提升最大,当m(PP)∶m(CaCO3)=100∶50时,杨氏模量达0.86 GPa,是纯PP的1.63倍;而PPW化学接枝率为2.49 mg PPW/g CaCO3时,CaCO3与PP之间的界面作用适中,复合材料缺口冲击强度提升最大,且当m(PP)∶m(CaCO3)=100∶10时,缺口冲击强度达3.91 kJ/m2,是纯PP的1.35倍。     

8,10-二炔廿五碳酸LB膜的周期结构

合成了8,10-二炔廿五碳酸,在玻璃片、石英片和镀金片上沉积了它的LB膜,X-射线衍射研究了LB膜的周期结构和聚合对它的影响。在2θ=1°—15°范围内观察到了多达7个布拉格衍射峰。由此计算了等同周期和分子在基片上的倾斜角。用分子模型计算了衍射峰强度,得到了与实验结果相符合的衍射峰强度奇偶起伏现象。     

meso-苯基四苯并卟啉锌的合成和光谱性能的研究

四苯并叶琳(TBP)及其金属配合物是一类新型的光敏性分子,其0-0跃迁出现在λ_max大于630nm的红光区,在光功能材料方面显示出良好的应用前景^[1-2].虽然有关meso-四取代四苯并叶琳金属配合物的合成及其光谱性能的研究已有多篇报道^[3-8],但报道方法的产率较低(最高达15%^[7],有关的光谱性能的报道也不一致^[3-5]。     

胶粘剂拉伸剪切强度测量结果的不确定度评定

依据GB/T 7124-2008《胶粘剂拉伸剪切强度的测定》,以环氧树脂结构胶为例,对胶粘剂拉伸剪切强度测量结果的不确定度分量进行了分析和量化,计算了合成标准不确定度和扩展不确定度。当环氧树脂结构胶的拉伸剪切强度为28.8 MPa时,扩展不确定度为1.0 MPa(k=2)。     

集中荷载下叠合梁抗剪强度

本文对低叠合面钢筋破简支在合梁二阶段受力的斜截面抗剪性能进行了试验研究，并运用非线性有限元分析和试验实测数据，得出了一个适合于集中荷载下高低叠合面叠合梁的抗剪强度计算公式．