C20三个异构体稳定性的从头计算研究

采用HF,B3LYP,MP2和QCISD等理论方法在6-31G和6-31G^*基组水平上,对C20的3个主要异构体碟型(Bowl)、笼型(Cage)和环型(Ring)的结构进行理论研究,得出这3个异构体的相对稳定性的次序为:Ring>Bowl>Cage.计算结果显示,分子轨道具有离域特性,电子的这种离域特征有利于原子间更好的成键,可避免出现大的张力,这是Cage型异构体虽然违反“五元环隔离规则”(Isolatedpentagonrule)却能稳定存在的原因.     

二元乙丙橡胶的环氧官能化及其增韧尼龙6的研究

在双螺杆挤出机中制备了环氧官能化的二元乙丙橡胶(gEPR) ,采用红外光谱工作曲线法测量了EPR的接枝率.将环氧官能化的EPR与尼龙6 (Nylon- 6 )熔融共混,并对共混体系的相形态、断裂形貌、增韧机理、力学性能进行了研究.结果表明,gEPR的环氧官能团与Nylon- 6的端羧基和(或)端氨基发生了化学反应生成Nylon -6 co EPR共聚物,该共聚物作为界面改性剂降低了Nylon -6与EPR之间的界面张力,使EPR在Nylon -6基体中均匀、稳定地分散,而且随着EPR接枝率的增加,EPR的粒径尺寸逐渐减小.断面形貌观察发现,与Nylon -6 EPR体系相比,Nyon -6 gEPR共混体系呈现明显的韧性断裂特征.通过对Nylon -6 gEPR共混体系缺口冲击形变区的研究得出EPR增韧Nylon -6的机理是橡胶粒子的空洞化和塑料基体的剪切屈服.力学性能测试表明gEPR的引入显著提高了Nylon -6的缺口冲击强度.     

载流圆环的张力、自感和线电流模型

分析讨论了一些献在计算载流圆环处于自身磁场受的张力和自感系数时使用线电流模型的不当所带来的发散问题。     

ANALYSIS OF THE LOCALIZATION OF DAMAGE AND THE COMPLETE STRESS-STRAIN RELATION FOR MESOSCOPIC HETEROGENEOUS ROCK UNDER UNIAXIAL TENSILE LOADING

The mechanical behavior of rock under uniaxial tensile loading is different from that of rock under compressive loads. A micromechanics-based model was proposed for mesoscopic heterogeneous brittle rock undergoing irreversible changes of their microscopic structures due to microcrack growth. The complete stress-strain relation including linear elasticity, nonlinear hardening, rapid stress drop and strain softening was obtained. The influence of all microcracks with different sizes and orientations were introduced into the constitutive relation by using the probability density function describing the distribution of orientations and the probability density function describing the distribution of sizes. The influence of Weibull distribution describing the distribution of orientations and Rayleigh function describing the distribution of sizes on the constitutive relation were researched. Theoretical predictions have shown to be consistent with the experimental results.     

基于动力松弛法的松弛索杆体系找形分析

索杆张力结构施工成形分析需要解决一个松弛态索杆系统的平衡形态求解问题,该问题可归结为一个给定构件原长的受荷索杆机构系统的找形问题。文中利用动力松弛法进行该类松弛索杆体系的找形分析。由于不建立刚度矩阵,避免了体系几何不稳定性所引起的刚度矩阵奇异问题。该方法采用悬链线索单元模型,可以考虑索大垂度效应。文中还推导了反映索原长和内力之间关系的悬链线索单元协调方程。通过一个正交松弛索网算例分析,考察了该找形方法的计算精度和收敛性。最后还模拟了一个索穹顶的施工成形过程,表明了该找形方法用于索杆张力结构施工成形分析的有效性。     

钢丝绳绳圈张力系数

本文把矿井提升机卷筒视为有限长且具有端部刚性支承的圆柱壳,根据本文所提计算原则,导出了不同支承方式的筒壳上所缠绕的钢丝绳绳圈张力系数的较精确的计算公式     

单链系泊浮体受外碰撞时的锚链动态张力

介绍系泊浮体受外碰撞时锚链动态张力计算方法,并对动态张力的若干问题进行了讨论．     

α，α‘—二氧代烯酮环二硫代缩酮类化合物的特征红外光谱（Ⅲ）

研究了5种α，α‘-二氧代烯酮环二硫代缩酮类化合物的碳基、碳碳双键、碳硫等一些特征红外光谱，尤其着重研究了共轭体系下的各种特征谱带随化学结构而变化的规律。     

Nonlinear traveling waves in a compressible Mooney-Rivlin rod I. Long finite-amplitude waves

In literature, nonlinear traveling waves in elastic circular rods have only been studied based on single partial differential equation (pde) models, and here we consider such a problem by using a more accurate coupled-pde model. We derive the Hamiltonian from the model equations for the long finite-amplitude wave approximation, analyze how the number of singular points of the system changes with the parameters, and study the features of these singular points qualitatively. Various physically acceptable nonlinear traveling waves are also discussed, and corresponding examples are given. In particular, we find that certain waves, which cannot be counted by the single-equation model, can arise. The project supported by the Research Grants Council of the HKSAR, China (City U 1107/99P) and the National Natural Science Foundation of China (10372054 and 10171061)     

基于LabWindows/CVI的矿井提升机钢丝绳张力监测仪设计实现

针对煤炭生产企业矿井多绳摩擦式提升机存在的钢丝绳张力不平衡问题,设计和开发了基于LabWindows/CVI的钢丝绳张力不平衡监测分析仪;该仪器装置能实时同步采集箕斗钢丝绳的张力和箕斗在井筒中的位移行程数据,箕斗的位移行程数据采用直接从在工控机端建立的OPC服务器内读取的方法,节省硬件成本;该监测仪装置能将箕斗的张力和位移监测数据自动存储于MySQL数据库,能自动绘制每根钢丝绳的张力-位移历史变化趋势曲线;当钢丝绳张力不平衡度超限时发出报警信息;该仪器装置可靠分析了箕斗在井筒中上下运动时的钢丝绳张力变化规律,对进一步提高提升系统的安全高效可靠运行性能具有十分重要的意义。 