油、水和混合表面活性剂"混相体系"的超低界面张力

本文考察了几种表面活性剂的复配体系,结果表明：油水两相极易混合（“混相”）的体系,界面张力必定超低。进而又了盐浓度及温度对体系界面张力的影响,油一水界面张力超低时,体系存在特殊的液晶结构,利用形成超低界面张力和混相体系的分散及稳定,从实验结果看,液晶更可能分散于体相中。含非离子的复配体系,存在相反转温度（ＰＩＴ）,且在相反转温度时界面张力出现最低值。     

Nonlinear effects of line tension in adhesion of small droplets

Three-phase line tensions may become crucial in the adhesion of miero-nano or small droplets on solid planes. In this paper we study for the first time the nonlinear effects in adhesion spanning the full range of physically possible parameters of surface tension, line tension, and droplet size. It is shown that the nonlinear adhesion solution spaces can be characterized into four regions. Within each region the adhesion behaves essentially the same. Especially, inside the characteristic regions with violent nonlinearities, the co-existence of multiple adhesion states for given materials is disclosed. Besides, two common fixed points in the solution space are revealed. These new results are consistent with numerical analysis and experimental observations reported in the literatures.     

由表面活性物质溶液的动界面张力外推求平衡界面张力的研究

表面活性物质溶液的界面张力往往随时间而变,难以测得平衡界面张力J。Kloubek^[1]曾应用经验式:1/(δ_H2O-δ_t)=b/(At^1/2)+1/A,以[1/(δ_H2O-δ_t)]对1/t^1/2作图外推求得溶液的平衡表面张力,但所得结果仅与文献值大致相符。本文从理论上分析该经验式的由来,以及产生偏离的原因,并寻求了解决的办法。     

液气界面张力垂直分量引起的基底弹性变形

Young方程是毛细理论和润湿的重要方程之一．但是,该方程只描述了3个界面张力的水平分量之间的平衡与接触角的关系,而对液气界面张力垂直分量未作任何描述．现在,随着软材料的广泛应用,该垂直分量将引起基底的表面变形,并在微流体系统的制造过程中起到重要作用,这已是该研究领域的共识．综述了关于表面变形这一问题在理论分析,实验研究和数值模拟等方面取得的进展．而且,还讨论了由垂直分量引起的表面变形对液滴润湿和铺展行为、微悬臂梁的弯曲、弹性毛细现象、电弹性毛细现象等的影响．不仅对该问题的历史发展和目前的研究进展进行了简单的综述,并且也针对后续的研究提出了几点建议．     

Substrate elastic deformation due to vertical component of liquid-vapor interfacial tension

Young’s equation is a fundamental equation in capillarity and wetting,which reflects the balance of the horizontal components of the three interfacial tensions with the contact angle(CA).However,it does not consider the vertical component of the liquid-vapor interfacial tension(VCLVIT).It is now well understood that the VCLVIT causes the elastic deformation of the solid substrate,which plays a significant role in the fabrication of the microfluidic devices because of the wide use of the soft materials.In this paper,the theoretical,experimental,and numerical aspects of the problem are reviewed.The effects of the VCLVIT-induced surface deformation on the wetting and spreading,the deflection of the microcantilever,and the elasto-capillarity and electroelasto-capillarity are discussed.Besides a brief review on the historical development and the recent advances,some suggestions on the future research are also provided.     

Stress concentration factor expression for tension strip with eccentric elliptical hole

Two explicit expressions of the stress concentration factor for a tension finite-width strip with a central elliptical hole and an eccentric elliptical hole, respectively, are formulated by using a semi-analytical and semi-empirical method. Accuracy of the results obtained from these expressions is better, and application scope is wider, than the results of Durelli’s photo-elastic experiment and Isida’s formula. When eccentricity of the elliptical hole is within a certain range, the error is less than 8%. Based on the relation between the stress concentration factor and the stress intensity factor, a stress intensity factor expression for tension strips with a center or an eccentric crack is derived with the obtained stress concentration factor expressions. Compared with the existing formulae and the finite element analysis, this stress intensity factor expression also has sufficient accuracy.     

优化张力参数与边界条件的平面三次Cardinal样条

当数据点给定时,三次Cardinal样条的张力参数和边界条件均为自由变量,因此可对这些自由变量进行优化,以得到满足某种特定要求的最佳三次Cardinal样条。讨论了如何通过优化张力参数与边界条件使得构造的平面三次Cardinal样条尽可能光顺。首先,分析了三次Cardinal参数样条曲线形状的影响因素;然后,利用曲率变化能极小对三次Cardinal参数样条曲线的张力参数与边界条件进行优化,获得张力参数与边界条件的唯一解; 最后,给出了对应三次Cardinal样条函数的张力参数与边界条件的优化方法。实例表明,经曲率变化极小优化张力参数与边界条件后的三次Cardinal样条比三次Catmull-Rom样条更为光顺,插值效果更好。     

餐厨废油制备的生物基两性表面活性剂的油水界面性能

以餐厨废油制备了生物基两性表面活性剂,应用界面张力和动态光散射方法,研究了该生物基两性表面活性剂体系的油水界面性能及在溶液中的聚集行为。 在无外加碱条件下,由餐厨废油制备的表面活性剂表现出良好的界面性能,在50~70 ℃以及pH值为7~12的条件下,均可以将油水界面张力降至超低值(<10^-3 mN/m),在不同的油藏模拟地层水中均保持较好的界面活性;分别在50、-20和4 ℃下保存,其界面活性均未受到明显影响。 在水溶液中形成的聚集体的平均流体力学半径为10~30 nm,无机盐离子的加入可使聚集体的粒径上升。 基于其优良的界面性质和可再生来源,由餐厨废油制备的生物基两性表面活性剂在三次采油方面具有重要的应用价值。     

光散射法同时测量气液二元体系的黏度、界面张力和热、质扩散系数的研究

当气液二元体系处于宏观热力学平衡状态时,表面与体相的波动弛豫时间具有不同量级,通过调节散射体积和改变采样时间,利用表面光散射实验系统可以同时探测到来自界面处表面波及体相中温度和浓度的波动信息。本文在已有的表面光散射实验系统上,以正庚烷与二氧化碳二元系统为例,同时实现了该体系黏度、界面张力和热、质扩散系数的测量,其扩展不确定度分布为3.0%,3.7%,20%,4.3%(k=2)。实验所得到的数据与文献进行了对比,其偏差在不确定度范围内,证明了本文提出的测量方法可以实现气液二元体系四种性质的同时测量,且测量精度可以满足一般工程应用。