乙基苯胺的转动光谱及分子结构

本文使用傅里叶变换微波谱仪研究了乙基苯胺类物质(邻乙基苯胺,间乙基苯胺,对乙基苯胺)的分子结构. 由于此类分子含氮原子(I¹⁴N=1),因此跃迁谱线中都呈现出核四级裂分. 通过比较实验测定得到的分子结构,可总结苯胺环上不同位置乙基的取代对氨基及分子整体结构的影响.     

氢离子与里德堡态锂原子碰撞中的电荷转移过程

利用双中心原子轨道强耦合方法研究了H+离子与里德堡态的Li(5d)原子碰撞的电荷转移过程,计算了5d电子转移到氢原子各个次壳层的态选择截面及总截面.研究了态选择截面随俘获电子主量子数及角量子数变化的规律,并尝试给出了解析的标度关系;探讨了标度规律随入射粒子能量的变化,分析了高激发态电子电荷转移过程的动力学机制.     

The rotational anisotropies in the ferromagnetism/antiferromagnetism 1/ antiferromagnetism 2 exchange bias structures

The rotational anisotropies in the exchange bias structures of ferromagnetism/antiferromagnetism 1/antiferromagnetism 2 are studied in this paper. Based on the model, in which the antiferromagnetism is treated with an Ising mean field theory and the rotational anisotropy is assumed to be related to the field created by the moment induced on the antiferromagnetic layer next to the ferromagnetic layer, we can explain why in experiments for ferromagnetism (FM)/antiferromagntism 1 (AFM1)/antiferromagnetism 2 (AFM2) systems the thickness-dependent rotational anisotropy value is non-monotonic, i.e. it reaches a minimum for this system at a specific thickness of the first antiferromagnetic layer and exhibits oscillatory behaviour. In addition, we find that the temperature-dependent rotational anisotropy value is in good agreement with the experimental result.     

高斯型耦合Tavis-Cummings模型中原子的熵压缩

利用全量子理论研究了高斯型耦合Tavis-Cummings模型中一个原子的熵压缩,运用数值计算方法讨论了原子垂直于腔轴的运动速度、光场强度以及两原子的初态对单个原子熵压缩的影响.结果表明,原子的熵压缩时间由原子的运动速度决定,压缩程度由光场强度决定,压缩时间和压缩程度还决定于原子的初始状态.     

厄尔尼诺和南方涛动海气耦合模型中参数估计的变分方法

提出一种基于变分原理估计厄尔尼诺和南方涛动海气耦合模型中未知参数的方法. 首先将所研究的非线性海气耦合动力方程引入到目标泛函中; 接着利用变分方法导出伴随方程和待辨识参数泛函梯度的公式; 然后设计了估计未知参数的算法.数值试验结果表明变分方法是一 种能有效估计海气耦合非线性系统未知参数的方法.     

有横向耦合的束流系统的匹配问题

分析了不同起始情况的束流通过有横向耦合的束流系统后发射度的变化，给出了束流有效发射度的边界方程式及匹配条件．     

弯曲波导之间的耦合分析

采用极坐标下的光束传播法分析了两条平行变曲波导的中心间距、曲率半径等因素对模式耦合的影响,得到了耦合长度、耦合强度随中心间距、曲率半径的变化规律,并将直波导作为变曲波导的一种特殊情况进行了分析.     

光锥导光装置耦合效率分析与测试

介绍了光锥导光装置的优势,分析了影响光锥导光装置耦合效率的主要因素,得出了影响光锥导光装置耦合效率的理论模型误差曲线。以光锥端面反射损耗及光纤辐射损耗为主要误差源,测试了光锥导光装置的耦合效率及误差对耦合效率的影响;采用分光比标定的方法测量导光装置的耦合效率,消除了由于激光器输出能量变化给试验中脉冲能量测量环节带来的影响;根据试验测量数据,拟合出误差对耦合效率的影响曲线,通过与理论误差曲线进行对比,验证了理论模型的正确性,同时测得该耦合装置的耦合效率为70．26％。在激光束的入射角度误差〈5°,且在光纤耐受弯折允许范围内甩动光纤的情况下,总误差对耦合效率的影响〈10％,满足实际工程误差的允许范围。该耦合装置已经应用到实际工程中。     

Derivation of baroclinic Ertel–Rossby invariant-based thermally-coupled vorticity equation in moist flow

For the potential vorticity （PV） invariant, there is a PV-based complete-form vorticity equation, which we use heuris- tically in the present paper to answer the following question： for the Ertel-Rossby invariant （ERI）, is there a corresponding vorticity tendency equation？ Such an ERI-based thermally-coupled vorticity equation is derived and discussed in detail in this study. From the obtained new vorticity equation, the vertical vorticity change is constrained by the vertical velocity term, the term associated with the slope of the generalized momentum surface, the term related to the horizontal vorticity change, and the baroclinic or solenoid term. It explicitly includes both the dynamical and thermodynamic factors＇ influence on the vorticity change. For the ERI itself, besides the traditional PV term, the ERI also includes the moisture factor, which is excluded in dry ERI, and the term related to the gradients of pressure, kinetic energy, and potential energy that reflects the fast-manifold property. Therefore, it is more complete to describe the fast motions off the slow manifold for severe weather than the PV term. These advantages are naturally handed on and inherited by the ERI-based thermally-coupled vorticity equation. Then the ERI-based thermally-coupled vorticity equation is further transformed and compared with the traditional vorticity equation. The main difference between the two equations is the term which describes the contribution of the solenoid term to the vertical vorticity development. In a barotropic flow, the solenoid term disappears, then the ERI-based thermally-coupled vorticity equation can regress to the traditional vorticity equation.     

百瓦级高亮度光纤耦合半导体激光模块的研制

用3只976 nm半导体激光短列阵作为子模块,研制出连续工作的百瓦级高亮度光纤耦合模块。首先,利用光束转换器将每个半导体激光短列阵进行光束整形;然后采用空间复用技术将3个半导体激光短列阵在光参数积小的方向上叠加,并利用倒置伽利略望远镜作为扩束器进一步压缩发散角;最后利用优化结构的透镜组将激光聚焦到芯径200 μm,数值孔径为0.22的光纤中。测量结果显示:聚焦后激光的发散角为24.8°,焦平面的光斑尺寸为175.2 μm;耦合后测量光纤出光功率可达107 W,对应亮度为2.23 MW/(cm²·sr),达到了国内利用列阵进行光纤耦合的领先水平;在工作电流为52.5 A时,电光转换效率为43.1%,远高于全固态等激光器;最后测量本模块在不同驱动电流时的光谱,并以此计算出模块的热阻为1.29 K/W,说明它的散热性能良好。结果表明,本光纤耦合模块适合应用于泵浦光纤激光器、医疗和激光加工等领域。