薄膜物理及其应用讲座：第三讲 非晶半导体薄膜最新进展

介绍了非晶半导体薄膜的结构特点和在光电器件上的独特性能，给出了薄膜器件的发展水平和制膜技术、制膜设备的研究现状。     

Hermitian阵的 Hadamard积的Schur补的一些不等式（英文）

本文得到了正定Hermitian阵的Hadamard积的Schur补的一些不等式，进而，给出了他们的一些应用，这些改进了近期的一些结束．     

用正四棱锥形阵对声目标定位研究

文章结合声阵列在智能雷系统中的应用，提出了用立体五元声阵列对声目标进行定位，将智能雷中用于预警的传感器也参与到定位阵列中来，这样就在不增加传感器的条件下实现了市体阵列对声目标的定位。文章推导了定位公式和误差公式，并对结果进行仿真分析，与平面阵相比取得了较好的效果。不但提高了精度还降低了声阵列的盲区。     

卟啉类光敏剂在染料敏化太阳能电池中的应用

染料敏化太阳能电池结合了染料光敏剂和无机半导体的优势，具有较宽的光谱响应范围，制造工艺简单、成本较低，对环境友好，应用前景广阔，因而备受人们的关注。本文以卟啉配合物为主线，介绍光敏太阳能电池的基本构造和光电原理，从改善电池性能的角度，综述了各种卟啉类光敏剂在染料太阳能电池中的应用，讨论了卟啉配合物及其超分子结构对光电转化率的影响机理。     

方酸染料在远红光区／近红外区对纳米晶二氧化钛电极的高效敏化作用

Four para-dialkylaminophenyl （PDAAP1-PDAAP4） bearing carboxyl groups were studied for application to the dye-sensitized solar cells （DSC）. It was found the short spacer CH2 between carboxyl and dialkylaminophenyl chromophore in PDAAP3 and PDAAP4 led to highly efficient monochromatic incident photon-to-current conversion efficiencies （IPCE）, however the long alkyl group C4H9 attached on aniline moieties in PDAAP2 and PDAAP4 favored improvement of open-circuit photovoltage. Thus, the solar cell sensitized by PDAAP4, having both short carboxyl groups CH2COOH and long alkyl groups C4H9, exhibited the IPCE maximum of 73% at 670 nm and overall energy conversion efficiency η of 3.06%, representing the highest IPCE and η values so far in dialkylaminophenyl-based organic dye-sensitized semiconductor solar cells. Taking advantage of the highly efficient sensitizing ability of PDAAP4 in far-red region, the data of IPCE above 630 nm of the solar cells were improved greatly by cosensitization with both N3 and PDAAP4. The influences of the TiO2 film thickness and the concentration of 4-tert-butylpyridine （TBP） in electrolyte were also investigated.     

Composite Electrode SnO2／TiO2 for Dye-Sensitized Solar Cells

Composite nanoporous electrode SnO2/TiO2 was fabricated for the dye sensitized solar cell (DSSC) with N3 (Cis-Ru). After introducing of TiO2, the open-circuit photovoltage (Voc) was higher than that of the pure SnO2 electrode, while short-circuit photocurrent (Isc) was varied with the ratio of the TiO2. Appropriate content of the TiO2 can be beneficial to the efficiency of the solar cell, and it gives negative impact on the composite electrode when the content of TiO2 is higher.     

四氟苯基宽带隙聚合物给体光伏材料的研究

设计并通过Stille缩聚方法合成了一种基于四氟苯和4,8-双(5-(2-乙基己基)噻吩-2-基)-苯并[1,2-b:4,5-b’]二噻吩单元的推拉电子型宽带隙聚合物(PBDT4F)作为聚合物太阳能电池的给体材料。用核磁共振氢谱(1H-NMR)、凝胶渗透色谱(GPC)、热重分析、紫外-可见吸收光谱和循环伏安法等对其进行了表征。结果表明:PBDT4F对400～600 nm短波长光具有强吸收能力,并且具有低的最高占有轨道(HOMO)能级和适合的最低未占有轨道(LUMO)能级。基于PBDT4F为给体、有机小分子(5Z,5’Z)-5,5’-((7,7’-(4,4,9,9-四辛基-4,9-二氢-s-茚并[1,2-b:5,6-b’]二噻吩-2,7-二基)双(苯并[c][1,2,5]噻二唑-7,4-二基)双(亚甲叉))双(3-乙基-2-硫代-4-噻唑烷二酮)(O-IDTBR)为受体的共混活性层的光伏器件取得了0.986 V的开路电压和2.58%的光电转化效率。     

新型无机太阳能电池

UC Berkeley化学教授A.Paul Alivisato的小组使得一度仅局限于理论范畴的一种完全由无机纳晶组成的新型太阳能电池成为现实。虽然这种无机电池目前的效率只有2.9%,而市售太阳能电池的效率已达到15%左右,但是这一进展可能致使一类较传统硅基太阳能电池价廉而且稳定的能量转化器件的问世。Alivisato等的做法是将两层柱状无机纳晶分别旋涂在覆有铝的氧化锡铟玻璃上,第一层为CeTe,第二层为CdSe。当这种电池放置在日光下时,CeTe和CdSe层间将发生电荷转移。这种无机器件还有超越由有机材料制成的太阳能电池之处,即吸收光的频区较宽。(Scien…     

New Type High Efficient Quasi-Solid-State Ionic Liquid Electrolyte for Dye-Sensitized Solar Cells

For the fist time the preparation of a mostly solid-state high efficiem electro-conductive material comprising 1-methyl-3-propylimidazolium iodide （MPII）, benzimidazole （BI）, iodine and lithium iodide was reported. In this electrolyte, BI acts as not only additives but also gelators. With its significant electrochemical properties, an overall efficiency of 3.07% was achieved under AM 1.5 （100 mW/cm^2）.