线性啁啾光脉冲在具有纵向增益光纤中的自相似传播研究

非线性薛定谔方程是光脉冲在光纤中传播时所遵循的基本方程.本文利用分步傅里叶方法从数值结算的角度研究了具有线性啁啾的光脉冲在具有横向增益光纤中的自相似传播特性.研究表明:当群速度色散系数和光脉冲的啁啾系数符号相同时,由于在传播过程中自相位调制和群速度色散分别起主要作用,不论何种形式的光脉冲在传输过程中均会受到压缩,但随着传播距离的增加压缩的光脉冲会展宽;埃尔米特高斯输入和正弦输入在传播过程中的光强分布是对称的,拉盖尔高斯输入在传播过程中会发生能量交换而表现出明显的偏转;当群速度色散系数和光脉冲的啁啾系数符号不相同时,在传播过程中群速度色散始终起主要作用,脉冲一直展宽.这些研究结论可能为未来光纤压缩器、光纤放大器以及新型THz调制波源的制备提供新的理论基础和方法.     

动生电动势的几何意义

根据动生电动势中包含的矢量混合积,分析动生电动势的几何意义.在此基础上,对导体在磁场中运动产生的动生电动势用动生电动势的定义和求体积的方法进行求解,并从几何意义上对导体在磁场中运动时不产生动生电动势的情况进行说明.     

Pressure-induced phase transition in silicon nitride material

The equilibrium crystal structures,lattice parameters,elastic constants,and elastic moduli of the polymorphs α-,β-,and γ-Si3N4,have been calculated by first-principles method.β-Si3N4 is ductile in nature and has an ionic bonding.γSi3N4 is found to be a brittle material and has covalent chemical bonds,especially at high pressures.The phase boundary of the β→γ transition is obtained and a positive slope is found.This indicates that at higher temperatures it requires higher pressures to synthesize γ-Si3N4.On the other hand,the α→γ phase boundary can be described as P = 14.37198+ 3.27 × 10?3T-7.83911 × 10?7T2-3.13552 × 10?10T3.The phase transition from α-to γ-Si3N4 occurs at 16.1 GPa and 1700 K.Then,the dependencies of bulk modulus,heat capacity,and thermal expansion on the pressure P are obtained in the ranges of 0 GPa-30 GPa and 0 K-2000 K.Significant features in these properties are observed at high temperatures.It turns out that the thermal expansion of γ-Si3N4 is larger than that of α-Si3N4 over wide pressure and temperature ranges.The evolutions of the heat capacity with temperature for the Si3N4 polymorphs are close to each other,which are important for possible applications of Si3N4.     

Photonic multi-shape UWB pulse generation using a semiconductor optical amplifier-based nonlinear optical loop mirror

We propose and demonstrate a scheme to implement photonic multi-shape ultra-wideband(UWB) signal generation using a semiconductor optical amplifier(SOA) based nonlinear optical loop mirror(NOLM).By employing the cross phase modulation(XPM) effect,cross gain modulation(XGM),or both,multi-shape UWB waveforms are generated including monocycle,doublet,triplet,and quadruplet pulses.Both the shapes and polarities of the generated pulses are flexible to adjust,which may be very useful in UWB pulse shape modulation and pulse polarity modulation.     

程序升温大体积进样和解卷积气相色谱-质谱法测定蔬菜水果中32种农药残留量

建立了蔬菜、水果中有机磷、有机氯、拟除虫菊酯和氨基甲酸酯等32种农药的气相色谱-质谱(GC-MS)检测方法。样品经乙腈提取,石墨碳黑串联丙氨基固相萃取柱净化,采用程序升温大体积进样,GC-MS全扫描模式采集,结合解卷积技术定性分析,内标法定量。分别对程序升温和大体积进样等条件进行了研究,并考察了方法选择性和耐用性。在最优条件下,32种农药的响应值与浓度呈良好的线性关系(r>0.995),各农药的方法检出限为2.0~5.0 μg/kg,以菠菜、四季豆和黄瓜为代表基质,进行3个水平(0.010~0.50 mg/kg)的加标回收试验(n=6),回收率为65.2%~120.3%,相对标准偏差(RSD)为4.1%~22.3%。该方法快速、灵敏、可靠、耐用,能满足蔬菜、水果中多类多残留痕量分析的要求。     

Concentration-dependent crystal structure,elastic constants and electronic structure of Zr x Ti1−x alloys under high pressure

The physical properties of ZrxTi1-x（x=0.0, 0.33, 0.5, 0.67, 0.75 and 1.00） alloys were sinmlated by virtual crystal approximation （VCA） methods which is generally used for disordered solid solutions modeling. The elastic constant, electronic structure and thermal Equation of state （EOS） of disor- dered ZrxTi1-x alloys under pressure are investigated by plane-wave pseudo-potentia1 method. Our simulations reveal increasement of variations of the calculated equilibrium volumes and decrease- ment of Bulk modulus as a function of the alloy compositions. Lattice parameters a and c of alloys with differentZr concentrations decrease linearly with pressure increasing, but the c/avalues are increasing as pressure increases, indicating no phase transitions under pressure from 0 GPa to 100 GPa. The elastic constants and the Bulk modulus to the Shear modulus ratios （B/G） indicate good ductility of Zr, Zr0.33 Ti0.67 Zr0.5Ti0.5, Zr0.75Ti0.25 and Ti, but the Zr0.67Ti0.33 alloy is brittle under 0 K and 0 GPa. The metallic behavior of these alloys was also proved by analyzing partial and total DOS.     

体积排阻色谱法测定低分子量肝素抗凝血因子Xa的活性

发展了一种基于体积排阻色谱测定低分子量肝素(LMWH)抗凝血活性的方法。利用肝素与抗凝血酶Ⅲ(ATⅢ)结合后可增强ATⅢ对凝血因子Xa(FXa)抑制作用的原理,通过测定加入LMWH后FXa水解其生色底物产生对硝基苯胺(pNA)这一反应的抑制程度确定LMWH的活性。首先将含有一定浓度LMWH的缓冲溶液与ATⅢ溶液混合,然后依次加入FXa和生色底物,分别孵育一段时间。底物被FXa水解,产生游离的pNA。体积排阻色谱可将小分子产物pNA与其他大分子分离开,因而可以在pNA的最大吸收波长下得到高灵敏度的测定,并且不再受其他成分的干扰。该方法重复性好,灵敏度高,极大地减少了样品的消耗量,降低了成本,并且还可进行各种复杂样品(如血浆)中LMWH抗FXa活性的监测。     

大体积混凝土温度应力耦合直观化仿真计算系统

温度应力耦合问题是大体积混凝土工程施工期的核心关注点,大量相关的计算软件对用户能力要求较高,难以实现普遍性应用.本文以Excel软件为基础,配合VBA编程,实现了前处理的直观化,并通过C语言编制后台程序,利用Marc为核心求解器,完成了大体积混凝土温度应力耦合仿真计算系统的开发.该系统的用户友好性较强,直观易懂,能够实现前处理、计算、后处理全套过程的自动化,进一步提高了大体积混凝土工程仿真计算分析的通用性.通过国内某大型混凝土拱坝的实际算例,证明了该套系统的正确性和可行性.     

基于不同时间步长时域非结构有限体积法模拟声-弹性耦合问题

介绍一种改进的时域非结构有限体积法(FVM),并将其应用于声-弹性耦合问题。在流体与固体介质中分别求解声波动方程与弹性波方程,根据交界面上的力平衡与质点振速连续条件考虑二者的相互作用。同时考虑双线性四边形单元的线性变化项及常数项,并结合常应变三角形单元处理混合网格问题。分别对三角形单元和四边形单元进行色散分析,给出声波动方程的稳定性条件。在不同介质中采用不同时间步长,提高计算效率。求解弹性波问题、声-弹性耦合问题,结果表明,改进后的方法求解声-弹性耦合问题是有效和准确的,并且具有良好的数值稳定性。