依赖系统大小的能量损失对强子谱压低的影响

基于微扰量子色动力学(pQCD)的部分子模型, 在领头阶(LO)近似下分别计算了质子－质子(p+p)碰撞, Au+Au和Cu+Cu不同对心度碰撞产生π⁰的强子谱和相应的核修正因子R_AA. 在考虑部分子喷注能量损失(即喷注淬火)效应后的理论计算表明, 与相同质心系能量s=200GeV的p+p碰撞相比, Au+Au或Cu+Cu不同对心度碰撞产生的强子谱被压低, 被压低的程度与依赖系统大小的能量损失有强烈的关系. 系统越大, 部分子喷注的能量损失越大, 导致强子谱被压低得越多, R_AA越小. 理论计算的数值结果和实验数据相符合, 说明能量损失机制的可靠性和真实性.     

超声场对低碳钢性质的优化作用

本文论述了超声场在低碳钢激冷淬火过程中对其性质优化所产生的重要影响。在实验中选用了两类低碳钢——A_3钢和20钢,共做了140多个试件。从它们在超声场中激冷淬火后的效果来看,其强度指标比淬火前和纯水淬都有一定的提高,硬度也提高了不少,金相组织均为细化的板条马氏体,而且在电子断口形貌中观察到大面积的韧窝,这些都证明了超声场对钢(特别是廉价的低碳钢)的优质化方面起了重要的作用。最后初步探讨了在热处理过程中起积极作用的超声场效应的实质。     

静高压下Al-Mn准晶形成及其结构稳定性的研究

 静高压（4.5 GPa）下Al₆Mn合金熔态淬火（冷却速度约为10² ℃/s），得到Al₆Mn合金的高压淬火样品。X射线分析表明：Al₆Mn合金的高压淬火样品中含有准晶二十面体相、Al₆Mn相及Al的面心立方相；与常压结果相比，高压淬火方法的冷却速率可比常压的低约3个数量级的条件下产生准晶二十面体相。其晶化温度与急冷甩带的相近。对静高压（2.5 GPa）下Al₆Mn准晶条带样品的晶化过程进行了研究。X射线分析表明：静高压下Al₆Mn准晶条带样品的晶化过程中，出现了一种新的未知亚稳相——准晶向晶体转化中的一种中间过渡态，具有类T相形式；与常压结果比较，高压下准晶相晶化温度提高。     

Pure LiFePO4 with high energy density prepared by water quenching treatment

A compound"vacuum firing and water quenching"technique was presented in the synthesis of LiFePO_4 cathode powder.The sample was prepared by heating the pre-decomposed precursor mixtures sealed in vacuum quartz-tube,followed by water quenching at the sintering temperature.The results indicate that using the"fast quenching"treatment can succeed in controlling overgrowth of the grain size of final product and improving its utilization ratio of active material.The sample synthesized by this technique has the high reversible discharge specific capacity and good cyclic electrochemical performance.     

感应淬火综合监控系统设计

感应淬火综合监控系统集成了感应淬火能量监控与环境监控功能,其硬件基础为工控机与Y5000+多功能板,工控机通过并行口与Y5000+多功能板实现数据交换。Y5000+多功能板以CPLD芯片为核心,扩展了DI/DO、PI/PO以及AI/AO功能。感应淬火综合监控系统的应用程序分为上层管理程序与底层实时测控程序。在RTX支持下,系统完全能满足实时性与可靠性要求。     

Dynamic Assemblies and Photophysical Changes of Zinc Porphyrin Dimer Regulated by N-Containing Ligands

Zinc porphyrin dimer （1） has been designed and synthesized as a novel host of N-containing ligands. The assembly behavior and photophysical changes of its host-guest complexes were evaluated by IH NMR, fluorescence, and UV-visible titrations, and the processes reveal that the host-guest assembly first creates a stable sandwich complex, then an axial coordination equilibrium appears between the sandwich complex and free ligand. The changes of absorption spectra of the assembly processes rely on the stabilities of the complexes, and fluorescence quenching depends on the axial coordination equilibrium, which indicates that the axial ligation/de-ligation dynamics is indeed a pathway from the excited state to the ground state for metalloporphyrin complexes.     

Fluorescence Quenching Study of Zinc Bisporphyrins by Fulleropyrrolidines and Their N-Oxides

Novel phenylene-bridged zinc bisporphyrins （1-4）, fulleropyrrolidines （C60-m, C60-h） and their N-oxides （C60-mo, C60-ho） were synthesized. The fluorescence quenching processes of bisporphyrins in toluene solution by fulleropyrrolidines and their N-oxides were investigated by steady-state fluorescence spectra. The fluorescence quenching constants proved that the fluorescence quenching ability was decreased as reduction of the pyrrolidine functional groups of fullerene surface： C60-h〉C60-m〉C60, and the fluorescence quenching ability was increased about 1.3-7.4 times by utilizing fulleropyrrolidine N-oxides （C60-mo, C60-ho） compared to fulleropyrrolidine compounds （C60-m, C60-h）. The results revealed photoinduced electron transfer （PET） efficiency between bispor-phyrin and fullerene derivatives could be tunable by change of functional groups on fullerene surface.     

4-(4-羟基丁基－2－炔氧基)－3-（苯磺酰基）－1，2，5－噁二唑－2－氧化物与牛血清白蛋白结合作用的光谱法研究

The interaction between 4-(4-hydroxybut-2-ynyloxy)-3-(phenylsulfonyl)-1,2,5-oxadiazole-2-oxide(FB)andbovine serum albumin(BSA)was studied by spectroscopic methods including fluorescence and UV-Vis absorptionspectroscopy.The quenching mechanism of fluorescence of BSA by FB was considered to be a dynamic quenchingprocedure.The number of binding sites n and apparent binding constant K were measured by fluorescence quench-ing method.The results indicate that there is FB molecular binding with BSA,and forming 1∶1 complex.Thethermodynamic parameters such as ΔH,ΔG and ΔS,etc.,were calculated.The results indicate that the binding reac-tion is mainly entropy-driven and hydrophobic forces play major role in the binding reaction.The distance r be-tween donor(BSA)and acceptor(FB)was obtained according to Frster theory of non-radioactive energy transfer.     

T10钢金属模具中裂纹电磁热止裂的实验研究

自主设计了改进型ZL-2超强脉冲电流发生装置，采用它对T10金属模具钢中裂纹进行脉冲放电止裂。放电时裂纹尖端熔化形成堆焊和高压应力区，使裂纹尖端钝化，达到了止裂的目的。由于脉冲放电超快速加热和冷却，在裂纹尖端处实现了冲击淬火，得到了超细化的隐晶马氏体和细粒碳化物等微观组织，同时围绕裂纹尖端形成了白亮层组织，提高了裂纹尖端处的硬度、强韧性和耐磨性，实验结果验证了理论研究和数值模拟的结果，为将电磁热裂纹止裂技术应用到金属模具裂纹止裂中，进行了基础实验工艺的研究工作。     

Viscosity and Jet Quenching from a Holographic Model

We consider the backreaction of the fundamental flavor degrees of freedom on the A dSs-Schwarz background, and calculate their contributions to the shear viscosity and jet-quenching parameter of the thermal quark-gluon plasma.