标准芳烃及其混合溶液的同步荧光光谱分析

为了提供区分标准芳烃的实验依据,并为环境中芳烃污染检测提供参考.对10个标准芳烃样品(萘、芴、蒽、菲、荧蒽、苊、芘、1,2-苯并[A]蒽、苯并[k]荧蒽、苯并菲)及其混合溶液(蒽、萘、芴混合溶液,苊、荧蒽、菲混合溶液和芘、1,2-苯并[A]蒽、苯并[k]荧蒽、苯并菲混合溶液)的同步荧光特性进行了分析,获得10种标准芳烃标志峰最好时对应的Δλ值及其标志峰位.在此基础上,通过同步荧光光谱分析区分了三种标准芳烃混合溶液的组分,实验发现对蒽、萘、芴混合溶液,Δλ=3nm时最易区分三种组分;对苊、荧蒽、菲混合溶液,Δλ=3nm或Δλ=10nm均可区分三种组分,相对而言,Δλ=10nm更简便些;对芘、1,2-苯并[A]蒽、苯并[k]荧蒽、苯并菲混合溶液,Δλ=5nm时是最好的,但也仅能区分芘、1,2-苯并[A]蒽、苯并[k]荧蒽三种组分,苯并菲不确定.     

Laser Damage Mechanisms of Amorphous Ta2O5 Films at 1064, 532 and 355nm in One-on-One Regime

Ta2O5 films are deposited on fused silica substrates by conventional e-beam evaporation. Surface topography and chemical composition are examined by atomic force microscopy （AFM） and x-ray photoelectron spectroscopy （XPS）. The calculation of electron structures of Ta2O5 and Ta2O5-x is attempted using a first-principle pseudopotential method within the local density approximation. The laser-induced damage threshold （LIDT） is performed at 1064, 532 and 355 nm in 1-on-1 regime, respectively. The results show that the LIDT increases with the wavelength increasing, which is in agreement with the wavelength effect. However, the LIDT results are not consistent with the empirical equation （I（λ）=aλm）, which may be attributed to the intrinsic absorption of Ta2O5 at the wavelengths of 532 or/and 355 nm. Moreover, different damage morphologies are observed when the films are irradiated at different wavelengths. It is concluded that the laser damage at 1064 nm is the defect dominant mechanism and at 355 nm it is the intrinsic absorption dominant mechanism, whereas at 532 nm it is the combined defect and intrinsic absorption dominant mechanism.     

一类大气浅水波方程的近似解

研究了一类非线性浅水波方程，利用同论映射理论和方法，得到了相应系统的近似解. 关键词： 浅水波 非线性 同伦映射 近似解     

Optimization on Synchrotron Radiation Lattice of BEPCII

The Beijing Electron and Positron Collider II （BEPCII） is a double ring electron positron collider, which can also be used as a synchrotron radiation （SR） light source. Since the BEPCII will start commissioning with SR mode in November 2006, it is essential to have a satisfying SR lattice. Here we first perform frequency map analysis on the original BEPCII SR lattice. The result shows that the resonance is really severe in the lattice and the transverse motion of particles is unstable. Then a new SR lattice is designed to obtain a large dynamic aperture and much more stable transverse motion. The dynamic aperture of the new lattice including nonlinear wiggler effect is calculated to be very good. This new SR lattice can be used in the commissioning stage of the BEPCII.     

基于LSTM的激光混沌同步通信

针对激光混沌保密通信系统中混沌信号接收双方硬件参数难以完全匹配的问题,用长短期记忆神经网络对发射端产生的大量混沌加密信号和部分载波信号进行充分训练,最终得到一个与发射端激光器系统高度相似的神经网络模型,并用此非线性模型代替接收端进行解密,实现了2 Gbit/s的混沌同步通信。该方法明显降低了混沌同步的复杂性。探讨了不同节点数量、耦合系数以及信噪比对于同步通信的影响,结果表明同步系数可以高达0.999 966,均方根误差达到10^-3量级,误码率低至10^-10量级。最后通过图像传输系统验证了方案的可行性。     

恒能量同步荧光光谱法测定食用油中多环芳烃

用12%（w/V）的氢氧化钾-乙醇溶液皂化食用油的脂肪酸,以环己烷萃取皂化液中的多环芳烃,经浓缩,柱层析纯化并浓缩,取微量试样液稀释后,通过选择合适能量差,建立了同步荧光法测定食用油中多环芳烃含量的新方法,其线性范围为5—1000ng.mL-1,检出限在0.04—15.21ng.mL-1之间,平均加标回收率在81.94%—90.06%之间。该方法具有快速、简便、准确等特点。     

单模激光Lorenz系统与Duffing系统缩阶反同步

 对于2阶Duffing系统与3阶单模激光Lorenz系统,用主动控制方法设计了一种同步控制器,实现二者之间的缩阶反同步。依据罗斯 霍维兹判据,给出误差系统在原点处渐进稳定的条件。数值试验证实：在控制器作用下,2阶Duffing系统的状态变量与3阶单模激光Lorenz投影子系统的状态变量振动的幅值相同但方向相反,且在随机噪声干扰下反同步仍能很好地实现。这表明所设计的控制器对于不同阶的Duffing系统与Lorenz系统的缩阶反同步的实现是可行的、有效的,而且具有很好的鲁棒性。     

同步加速器无损检验艺术品和化石

梵高曾向他的兄弟抱怨自己的向日葵油画很快就褪色了,而现在看起来他的向日葵不是褪色了,而是由黄色变成棕色了。这种变化是由于染料中的六价铬缓慢还原为三价铬,使绿色化合物转变为棕色化合物造成的。这是意大利佩鲁贾大学(University of Perugia)的莫尼科(Letizia Monico)与比利时安特卫普大学(University of Antwerp)的同行在法国格勒诺布尔(Grenoble)利用欧洲同步辐射装置(European Synchrotron Radiation Facility,ESRF)的密集X 射线通过实验进行无损光谱学检测得出的结论。
这里的X 射线同样被法国国家自然历史博物馆( National Museum of Natural History ) 的何赛(Alexandra Houssaye)用于制作9500 万年前有足蛇化石的3D 影像。目前全世界仅发现3 件有足蛇化石,它们表明蛇最初像蜥蜴一样是有腿的,后来才渐渐失去。何赛研究的这件蛇化石看起来只有一条腿,其实还有一条腿埋在岩石之中,借助欧洲同步辐射装置后才看清了化石的细节。     

Adaptive lag synchronization and parameter identification of fractional order chaotic systems

This paper proposes a simple scheme for the lag synchronization and the parameter identification of fractional order chaotic systems based on the new stability theory. The lag synchronization is achieved and the unknown parameters are identified by using the adaptive lag laws. Moreover, the scheme is analytical and is simple to implement in practice. The well-known fractional order chaotic Lü system is used to illustrate the validity of this theoretic method.     

线结构光自同步扫描三维形貌测量系统

针对空间目标操控任务中非合作目标近距离三维形貌测量的需求,设计了基于激光三角法原理的线结构光自同步扫描三维形貌测量系统.分析了经典的点扫描测量系统模型,扩展建立了线结构光扫描系统模型.构建了测量系统桌面样机,利用二维平面棋盘靶标构建虚拟立体靶标完成了系统参量的标定.分别对已知结构的工件及天宫一号缩比模型进行了测量实验,结果表明:测量距离为1m时,系统三坐标测量误差均优于1mm,Z向距离误差为0.18mm,测量点到拟合平面的距离误差均值为0.31mm.该系统简化了扫描系统结构,能降低空间载荷的重量和功耗,满足空间任务中快速三维形貌测量的需求.