光学系统黑斑法杂光系数和PST间的联系

PST(点源传递函数)是杂光分析程序常用的输出结果形式,杂光系数则是杂光实验测量最常用的结果表示方式。本文根据辐射传热理论,建立了杂光分析计算程序的输出结果PST和用黑斑法进行杂光测量所得的杂光系数V之间的联系,并给出了相应的解析表达式。     

粒子强度源模型粒子历程的计算和释热量分布

本文利用粒子强度源法来计算煤粉粒子的运动，燃烧过程，并假定煤粉粒子群围绕其中心位置逞正态分布来估算煤粉燃烧热的分布。     

Fine splits of photon emission spectrum of hydrogen atom caused by transitions between different dressed states in intense high frequency laser field

The photon emission spectrum of the hydrogen atoms in an intense high-frequency laser pulse is simulated by using one-dimensional soft Coulomb potential. Regular fine structures appear on the two sides of both the odd and even multiples of photon energy of the laser field besides the ordinary odd harmonic peaks. It is proved that the splits of the fine structures are responsible for hyper-Raman lines and the energy spacing between the odd harmonic lines is equal to the difference in energy between the eigenstates with the same parity of the time averaged Krameters Henneberger （KH） potential. By analysing the features of the fine structures, we also verify that the so-called even order harmonics under the stabilization condition are indeed hyper-Raman lines caused by the transitions between the dressed atomic states with different values of parity.     

采用组合脉冲驱动生成单一的X射线阿秒脉冲

采用组合激光脉冲(800 nm/9.4 fs 24 nm/1 fs)辐照联合两原子体系产生高次谐波,获得了单一的X-射线阿秒脉冲.我们发现,当固定钛宝石激光的峰值强度并改变高频谐波脉冲的峰值强度Ih时,存在一个优选的Ih范围,在该范围内相应的阿秒脉冲最优化,即强度达到最强,对此,本文从受激复合的角度给出了合理解释.     

Influences of Temperature on Proton Conductivity in the Hydrogen-Bond Molecular Systems with Damping

Influences of temperature of medium on proton conductivity in hydrogen-bonded systems exposed in an electricfield are numerically studied by the fourth-order Runge-Kutta method with our model. The results obtained show that the proton soliton is very robust against thermal perturbation and damping of medium, and is thermally stable in the temperature range T ≤ 273 K. From the simulation we find out that the mobility （or velocity） of proton conduction in ice crystal is a nonmonotonic function of temperature in the temperature range 170-273 K： i.e., it increases initially, reaches a maximum at about 191 K, subsequently decreases to a minimum at about 211 K, and then increases again. This changed rule of mobility is qualitatively consistent with its experimental data in ice in the same temperature range. This result provides an evidence for existence of solitons in the hydrogen-bonded systems.     

由相干制备原子系统构成的理想光学介质

电磁感应透明(electromagnetically induced transparency,EIT)发生时所伴随的效应(如可控的线性吸收和色散,可控的非线性增强)是理想光学介质所必需的重要特性。通过理解这种相干制备的多能级原子系统的线性和非线性特征,人们能够更好地设计和利用这种新颖的光学介质,并将其应用到光通信和量子信息处理中。文章简单介绍了与EIT有关的原子介质的基本(线性和非线性)光学特性,并简单评价了几个令人感兴趣的应用。     

错误系统结构的分解变换研究

对于错误系统的结构分解,需要先弄清楚错误系统的结构,再把该错误系统以某种基本结构分解成若干子系统,然后对子系统又以某种基本结构分解成下一层次的若干子系统,如此下去,直到所有子系统都为基本结构子系统为止.在此基础上,研究以串联、并联、扩缩、蕴含、反馈和其它型等六种基本型为基础的分解变换的分解方式,分解类型.同时采用图说明相应变换,采用系统结构与错误函数定量描述变换的逻辑规律,利用结构与功能的关系定量描述系统结构与错误的关系,最后给出了变换体系.     

2014《分析科学学报》征订启事

欢迎订阅欢迎投稿《分析科学学报》是经国家科技部(原国家科委)批准,国家教育部主管的分析科学领域的综合性学术刊物,1985年创刊,全国公开发行(刊号ISSN1006-6144CN42-1338/O),由武汉大学、北京大学、南京大学共同主办。《分析科学学报》主要报道我国在分析科学领域中的新理论、新方法、新试剂、新仪器和新技术,介绍分析科学前沿领域的最新进展和动向。栏目有:研究报告、研究简报、仪器研制与实验技术、综述与评论、技术交流、动态与信息之窗,可供大专院校、科研院所、环保、化工、冶金、药物、医学、商检以及工矿企业单位中的分析科技人员和管理人员阅读。     

商用氧化铟锡玻璃:室温高效还原氮气的催化剂电极

NH₃作为一种必需的活化氮源,在化肥、染料、爆炸物和药物等的制造中起到了关键作用;同时,它也是一种在交通运输领域具有吸引力的无碳能源载体.工业上生产氨气使用典型的哈伯-博世工艺,但是此工艺涉及大量的能源消耗和碳排放,给环境带来巨大的压力.电化学氮还原反应(NRR)能够在温和环境下实现环境友好、节能的氨合成,但此过程需要高效的电催化剂.高效的NRR催化剂(Au、Ag、Pd和Ru)储量少、成本高,阻碍了它的实际应用.因此,设计和开发由地球上丰富的元素制成的具有成本效益的催化剂来代替NRR催化剂意义重大.本课题组最近的研究(Chem.Commun.,2018,54,12966-12969)表明,SnO2在环境条件下具有电催化氧化活性,但其低电导率限制了其性能,可通过氟掺杂或石墨烯杂化予以解决.氧化铟锡(ITO)作为一种含SnO2的材料,导电性好,可望用于NRR的高效电催化剂中.因此,本文采用商用氧化铟锡玻璃(ITO/G)作为催化剂电极,在温和环境条件下进行N₂-NH₃的电化学转化,并呈现出对生成氨气有较高的选择性.XRD和XPS结果表示,商用ITO/G中存在In,Sn和O元素;SEM显示ITO/G具有清晰的纳米薄膜结构和267 nm的截面厚度;相应的EDX谱图显示In,Sn和O元素分布均匀,且原子比为32.11:3.16:64.74.采用紫外-可见光谱及线性扫描伏安和恒电位极化等电化学测试研究了商用ITO/G的NRR活性.在0.5 M LiClO4电解液中测试时,于-0.40 V vs.RHE条件下,ITO/G的NH₃产率为1.06×10^-10 mol s^-1 cm^-2,其法拉第效率为6.17%.15N同位素标记实验证实了所测到的NH₃是由ITO/G催化的N₂电还原反应生成的.利用第一性原理计算探讨了在ITO催化剂上可能的NRR反应机理,确定了ITO催化剂的NRR活性位点、N₂化学吸附活性位点以及NRR的反应途径.此外,24 h恒电位(-0.40 V vs.RHE)极化测试和2 h恒电位极化(-0.40 V vs.RHE)测试后的XRD和SEM结果表明,该催化剂具有较高的电化学稳定性.综上所述,商用ITO/G用作在环境条件下将N₂转化为NH₃的有效催化剂电极,将为开发人工固定氮气的ITO基纳米结构提供一种研究途径.     

Thermally induced dephasing of high power second harmonic generation in MgO:LiNbO3 waveguides

High power second harmonic generation(SHG) in MgO-doped LiNbO3 waveguides is investigated using a three-dimensional(3D) coupled thermo-optical model.Simulations performed for a 1111.6-nm fundamental laser show the in?uence of the absorptions and the thermally induced dephasing on the conversion efficiencies of the different waveguides.The onset of the thermally induced dephasing effect for each waveguide is also indicated.As a result of high light intensity in the waveguide,nonlinear absorptions are identified as the possible main factors in efficiency losses in specific cases.