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51.
以己二酸酐和邻羟基苯甲酸为原料,制备了己二酸单(2-羧苯酚)酯,并以它为单体聚合得到了相应的聚酯酸酐.研究了温度、真空度对聚合物分子量的影响,得到了最佳的聚合条件:真空度66.66Pa,聚合温度200℃.在此条件下聚合2.5h,得到的聚己二酸单(2-羧苯酚)酯重均分子量达6498.另外,还对聚合物在不同pH值条件下的体外降解行为进行了研究. 相似文献
52.
The single-longitudinal-mode Nd:GdVO4/RTiOPO4 (RTP) solid-state Green laser operation of a laser-diode (LD) end-pumped laser is realized by multi-cavities and a Brewster plate. The LD-pumped single-frequency green laser has been demonstrated by optimizing several parameters and a cavity length, with precise temperature controlling of Nd:GdV04, RTP and laser diode. When the incident pump power is 2 W at 808.4 nm, a single-frequency cw green laser at 532nm with output 210 m W is obtained, the optical-to-optical conversion efficiency is up to 10.5%. 相似文献
53.
Single Qubit and Its Universal Logic Gate Made of a Heisenberg Spin Cluster with Five Particles 下载免费PDF全文
We investigate an anisotropic Heisenberg spin cluster with five particles controlled by a time-dependent magnetic field. With the algebraic dynamical method, we obtain the exact analytical solution to the time dependent Schr6dinger equation. Based on the analytical solution, it is shown that the system can be used as a universal single qubit logic gate controlled by the strength and frequency of the magnetic field, and the six special single qubit logic gates can be realized physically. We also discuss the anti-decoherence property of the qubit and its logic gates resulted from particle coupling effect and collectivity of the cluster. 相似文献
54.
设计、合成了含核酸碱基的双亲化合物N6-十四酰基-9-辛基腺嘌呤三甲基溴化铵;用目标化合物和卵磷脂制备混合脂质体受体。分别研究了受体与巴比妥酸、核黄素药物在混合脂质体亲脂区通过互补氢键进行的分子识别。紫外可见光谱研究表明,底物巴比妥酸在258nm的吸收峰,核黄素在222nm,264nm的吸收峰随时间的延长而逐渐降低,这种减色作用归因于脂质体内的巴比妥酸和核黄素在亲脂区分别与双亲化合物上的腺嘌呤形成了氢键。 相似文献
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ZDRAVKOVICS SATARICM.V 《中国物理快报》2005,22(4):850-852
We compare optical and acoustical frequencies in the Peyrard-Bishop-Dauxois model, i.e. an extended Peyrard-Bishop model, of DNA molecules. We discuss how ratio of those frequencies depends on a value of the harmonic constant of the helicoidal spring K. Also, we suggest that the most favourable mode could be a resonance mode. 相似文献
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分子聚集体在非线性光学和集成光学等领域有潜在的应用前景。纳米结构一维染料分子J—聚集体有许多既不同于单个分子又不同于体材料的奇异性质,即超辐射和巨光学非线性。这种超辐射是由于在几个本征态内振于强度结合在一起,得到一巨跃迁偶极于,因而是超辐射的。跃迁速率与耦合分子个数N成正比。分子聚集体的J—吸收和超辐射发射是共振的。利用Z—扫描技术测量PIC在不同配比下的非线性折射率、非线性吸收系数和非线性极化率。观测到随着链长变短,样品的三阶非线性极化率增大。对这种非线性增强的机制进行了分析和讨论。 相似文献
60.
Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering 下载免费PDF全文
The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents. 相似文献