Two-Step Growth of MgO Films on Sapphire （0001） Substrates by Radio Frequency Plasma-Assisted Molecular Beam Epitaxy

We report on the growth of rock salt MgO films on sapphire (0001) substrates by rf plasma-assisted molecular beam epitaxy.A two-step method,i.e.high temperature epilayer growth after low-temperature buffer layer growth,was adopted to obtain the single crystal MgO film.The epitaxial orientation between the MgO epilayer and the sapphire (0001) substrate was studied by using in situ reflection high energy electron diffraction and ex situ x-ray diffraction,and it is found that the MgO film grows with [111] orientation.The role of the low temperature buffer layer in the improvement of crystal quality of the MgO epilayer is discussed based on the cross-sectional scanning electron microscopy.     

Spin Dynamics of Supramolecular Dimer [Mn4]2 Interacting With a Spin-polarized Electron

A new family of the supramolecular antiferromagnetically exchange-coupled dimer of single-molecules magnets, [Mn4]2, really behave as a quantum mechanical coupled system and can be used for quantum computation [Tiron et al (2003) Phys. Rev. Lett. 91 227203]. We study the time evolution of [Mn4]2 dimer interacting     

Intermolecular Interaction Potentials of CH4-Ne Complex Calculated with Local Density Approximation Methods

The intermolecular interactions potentials for two configurations of CH4-Ne complex are calculated with localdensity approximation methods in the frame of density functional theory. It is found that the calculated potentialshave two minima when the distance between the carbon atom of CH4 and the Ne atom takes R = 5.80a.u.and 6.20a.u. for both the two configurations. For the edge configuration, the corresponding depth of thepotential is 0.0669536eV and 0.0671416eV. For the face configuration, the corresponding depth of the potentialis 0,0737956 eV and 0.0645506 eV. The global minimum occurs at R = 5.80 a.u. for the face configuration with adepth of the potential 0.0737956eV. The depths of our calculation are in better agreement with the experimentaldata than the quantum chemical calculation approach~ while the position of minimum potential for our calculationis underestimated.     

Universal Scaling Law for Atomic Diffusion and Viscosity in Liquid Metals

The recently proposed scaling law relating the diffusion coefficient and the excess entropy of liquid [Samanta A et al. 2004 Phys. Reu. Lett. 92 145901; Dzugutov M 1996 Nature 381 137], and a quasi-universal relationship between the transport coefficients and excess entropy of dense fluids [Rosenfeld Y 1977 Phys. Rev. A 15 2545],are tested for diverse liquid metals using molecular dynamics simulations. Interatomic potentials derived from the glue potential and second-moment approximation of tight-binding scheme are used to study liquid metals.Our simulation results give sound support to the above-mentioned universal scaling laws. Following Dzugutov,we have also reached a new universal scaling relationship between the viscosity coefficient and excess entropy.The simulation results suggest that the reduced transport coefficients can be expressed approximately in terms of the corresponding packing density.     

Ultrafast Energy Transfer and Enhanced Two-Photon Absorption in a Novel Porphyrin Side-Chain Polymer

Ultrafast relaxation processes and transient two-photon absorption are studied in a novel porphyrin side-chain polymer, 5-hydroxy-10,15,20-triphenyl-porphyrin-poly(glycidyl methacrylate) (HTPP-PGMA), by using picosecond luminescence spectroscopy and femtosecond pump--probe techniques. HTPP-PGMA exhibits the ultrafast initial luminescence decay (～300ps), which is absent in the conventional porphyrin monomer such as TPP. Enhanced two-photon absorption was observed in HTPP-PGMA; the corresponding Im x⁽³⁾ is about 2.8× 10¹¹esu, which is almost one order of magnitude larger than that of the conventional porphyrin monomer (TPP) (～1.3×10¹²esu). The ultrafast energy transfer plays an important role in the excited-state relaxation dynamics observed in HTPP-PGMA. The potential application of HTPP-PGMA in optical switching is discussed.     

新课改下物理学习价值取向的再识识

本结合新课改，提出了教师应该注重去引导学生理解学习物理的原因，即物理学习的价值取向的问题，既而着重分析了在物理学习本身、物理学习评价，以及面对择业与选科的物理学科三个方面，学生应该持有的价值取向。     

Intermolecular interaction potentials of methane－argon complex calculated using LDA approaches

The intermolecular interaction potential for methane－argon complex is calculated by local density approximation (LDA) approaches. The calculated potential has a minimum when the intermolecular distance of methane－argon complex is 6.75 a.u.; the corresponding depth of the potential is 0.0163eV which has good agreement with experimental data. We also have made a nonlinear fitting of our results for the Lennard-Jones (12-6) potential function and obtain that V(R)=143794365.332/R^{12}-3032.093 / R^6 (R in a.u. and V(R) in eV).     

热学中易混概念辨析

按照分子动理论的观点，热现象是与大量微观粒子的无规则运动(即热运动)密切相关的．为了描述热现象和分子热运动的规律和本质，物理学中引入了温度、内能、分子动能、分子平均动能、分子势能、热量等物理量．很多同学在学习过程中容易弄混这些概念，为了帮助同学们理解这些概念的内涵及相互区别，下面通过几道辨析题对相近概念进行逐一比较，希望对同学们有所启发．     

用于产生瞬态物种的脉冲放电及其光谱探测的分子束装置

建立了一套用于产生瞬变物种的脉冲高压放电分子束装置，以N2气为例，对高压脉冲放电过程和整个荧光采集系统的工作效率进行了研究，从N2气的振动光谱中得到其激发态的振动温度为2257K。     

电子散射的受激原子态取向的趋向性规则

原子碰撞中的取向参数的研究为原子碰撞动力学、受激原子态结构提供了丰富的信息。本介绍近年来电子与原子碰撞受激原子态取向的特征，其中包括电子与轻原子低能小角度散射下取向的趋向性规则；自旋依赖的取向特点；重原子散射下的取向特点，就重原子散射下取向的趋向性规则的破坏做了简要的分析和讨论。