国际第一台超高能量分辨率真空紫外激光角分辨光电子能谱仪研制成功

在中科院综合计划局大型仪器研制项目《真空紫外激光角分辨光电子能谱仪的研制》资助下，中科院物理研究所周兴江研究组、理化技术研究所陈创天院士研究组和物理研究所许祖彦院士研究组合作，成功研制了国际首台超高能量分辨率真空紫外激光角分辨光电子能谱仪。2006年12月28日，该成果通过了中国科学院主持的鉴定。出席鉴定会的有国家科技部、中国科学院基础局、中国科学院综合计划局和物理研究所等单位的领导。由龚昌德院士担任组长的鉴定专家委员会对该国际首创的高尖端科学仪器给予了高度评价。     

Influence of Length of Opposing bi-Au Cone-Tips and Different Environment on Field Enhancement in Feed Gap

Electric field enhancement distributions encountered in feed gap of opposing bi-Au cone-tips is studied using a frequency-domain three-dimensional finite element method to solve Maxwell＇s equations of electric field distributions. Both the influences of cone-tip length and surrounding medium on electric field enhancement are investigated. The maximal enhancement value is discussed in terms of a simple physical model based on a standing wave on the tip surface associated with the antenna effect and surface plasmon. Simulated results demonstrate the enhancement is sensitive to the tip length. By selecting a suitably matched scale according to the incident wavelength, a large enhancement value can be observed within a small focused spot between the opposing tips permitting a high spatial resolution. The relative position of the opposing tips is also found for the optimum enhancement. All of the results suggest that our configuration is suitable for the site-specific Raman spectroscopic analysis at nanoscale.     

电极用纳米Ag~2O的电化学性能研究1: 纳米Ag~2O 的制备及表征

用化学方法首次成功地制备出了用于电极活性材料的纳米Ag~2O微粒，并通过TEM，XRD和XPS等测试技术进行了分析表征。同时，对每种方法纳米Ag~2O的生成机理进行了初步的探讨，表明这些方法具有一定的普适意义。     

6Li费米原子气中的配对能隙

在超导体中，为了拆散一个库珀对，必须提供某种激发能，这一能量的下限即所谓能隙．超导能隙可以通过光电子能谱实验进行测量．^6Li原子其质子、中子和电子的总数是奇数q，因此属于费米原子．除非^6Li原子两两结成库珀对，它们不可能共同占据量子力学的基态，实现玻色一爱因斯坦凝聚(BEC)．     

舰艇对抗微分对策建模研究

编队舰艇对抗攻击瞬时运动状态过程的完整描述是一个尚未很好解决的技术难点，本就驱逐舰对多艘导弹快挺对抗攻击建模问题进行了研究，建立了攻击时间尽可能短的定量微分对策模型，并给出了具体实现方法，中模型和方法可为实时舰艇作战指挥系统的研制、开发提供技术支持及理论依据。     

含金双硫螯合配体簇合物的研究 II: [Mo2Fe2(μ3-S)4(S2CNEt2)5]·CH3CN的合成, 结构和性质

在无氧非水介质中, 以(NH4)2MoS4, FeCl3和NaS2CNEt2为原料合成了簇合物[Mo2Fe2S4(S2CNEt2)5]·CH3CN。X射线单晶结构测定表明, 它具有[Mo2Fe2S4]^5^+类立方烷核心骨架。每个金属原子有一螯合基团S2CNEt2配位。第五个S2CNEt2基团在两个Mo原子间跨桥配位。XPS和Mossbauer谱的测定及M-S(M=Fe或Mo)键长比较表明, 簇合物中Fe原子的氧化态是不同的, 而两个Mo原子则具有相同的氧化态, 该簇合物为顺磁性物质, μm=4.27μs。此外, 还测定了它的红外光谱, 紫外-可见光谱和催化乙炔还原活性。     

Physical and Electrochemical Characterization of Hydrothermal Prepared α'-NaV_2O_5 Crystals

α'-NaV2O5 was prepared by a simple hydrothermal process.X-ray diffraction confirmed the orthorhombic structure of α'-NaV2O5,with preferential growth along the (001) direction.Scanning electron microscopy showed α'-NaV2O5 was composed of flake-shaped crystals.X-ray photoelectron spectroscopy confirmed the co-existence of V4+ and V5+ in α'-NaV2O5,which results in an average V4.5+ oxidation state of α'-NaV2O5.The observed Raman bands are ascribed to different V―O vibrations.α'-NaV2O5 shows a reversible specific capacity of about 100 mA·h·g-1 between 3.5 and 1.0 V,with a good capacity retention.The good electrochemical stability of the material is attributed to its structural stability during Li+ intercalation.