高折光指数光学树脂的合成——相转移法合成不饱和硫醇酯单体的条件控制

采用正常的低温相转移催化（ＰＴＣ）和反滴碱溶液ＰＴＣ法分别合成了含硫双烯ＭＥＳＤＭＡ和单烯ＭＥＰＳＭＡ．１Ｈ ＮＭＲ分析证明ＭＥＳ中的杂质主要是由原料ＴＤＧ引入的．对含单个巯基的ＭＥＰＳ的正常ＰＴＣ酯化接枝双键，因存在巯基和不饱和双键的加成反应而导致失败．作者最终得到了折光指数在１６２５以上的ＭＥＳＤＭＡ／ＭＥＰＳＭＡ共聚物．     

用热聚法固定指示剂的光纤氧气传感器研究

采用热聚法将甲叉双丙烯酰胺（MBBA）聚合并共价交联在硅烷化的玻璃微珠上 ，同时将指示剂Ru（Ⅱ）-邻啡咯啉配合物物理包埋于聚合物中，研制了一种基于 荧光猝灭原理的光纤氧气传感器，采用NaHSO_3-O_2-MnSO_4体系引发MBBA水溶液热 聚合后应，通过确定NaHSO_3,MnSO_4,MBBA和Ru(phen)_3Cl_2的最佳反应浓度以及 玻璃微珠的尺寸，优化了聚合反应条件，改善了指示剂的固定效果，制备了性能较 好的传感器探头，该传感器的检测下限为5×10~(-6)(V/V)，响应时间为10s该传感 器连续工作50min,重复性标准偏差为±1%。     

《功能高分子材料》

全书共分17章，结合功能高分子材料的结构与性能、制备方法及应用领域，对离子交换树脂，吸附树脂，离子交换纤维和活性碳纤维，高分子膜分离材料，高分子色谱固定相，高分子试剂，高分子负载催化剂，导电高分子材料，电效发光聚合物材料，非线性光学高分子材料，液晶高分子材料，感光高分子材料，医用高分子材料，环境敏感高分子材料，高分子电解质，高分子染料，淀粉，纤维素衍生物高分子等进行了详细论述。[第一段]     

Catalytic Preparation of Optically Active 1,1′—Binaphthalene—2,2′—Diol by Chiral Benzoimidazole—Cu（Ⅱ）Complex

Inthepastseveraldecades ,muchattentionhasbeenpaidtoopticallyactive ,C2 asymmetric1,1′ bi naphthalene 2 ,2′ diolanditsderivativesbecauseoftheirapplicationininducingchiralityinasymmetricsynthesis[1,2 ] .Enantiomericallypure1,1′ binaphtha lene 2 ,2′ diolhasbeen preparedbymanymethodsrangingfromtheclassicalresolutionviacrystalliza tionofthediastereoisomericsalts[3] toasymmetricox idativecoupling[4～ 6 ] .However ,theuseofexpensivechiralreagentsandthetediousnessoftheprocessessetalimitontheuseof…     

Cu2(μ-dppb)2(μ-Cl)2的合成、晶体结构及非线性光学性质

The complex Cu₂(μ-dppb)₂(μ-Cl)₂ has been synthesized from the reaction of CuCl， dppb and (n-Bu)₄NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a=9.939(4)?， b=10.083(6)?， c=14.104(5)?， α=76.46(3)°， β=71.02(2)°， γ=70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb， and the inner ring is a 4-membered ring composed of two Cl^- and two Cu(Ⅰ). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α₂=1.75×10^-13m·W^-1 and n₂=3.19×10^-18m²·W^-1. CCDC: 193113.     

Nonlinear Optical Properties of Tri—nuclear Transition Metal Clusters M—（μ—S）s—M′（M=Mo,W;M′=Cu,Ag,Au）

The static polarizabilities and the second-order hyperpolarizabilities of a series of tri-nuclear metal cluster models MS4(M′PPh3)2(M′PPh3)(M=Mo,W;M′=Cu,Ag,Au)have been calculated within the first-principle theoretical framework. The model clusters have two fragments of rhombic units and it is the charge ransfer from one of these moieties to the other that is responsible for nonlinear optical property. This kind of electronic delocaization, differentiated from that of planar π-system, is very interesting and is worthy for further investigation.     

Determination of Enantiomeric Excess of Glutamic Acids by Lab-made Capillary Array Electrophoresis

The techniques of combinatorial chemistry have recently been applied to the discovery of new asymmetric catalyst for a variety of organic transformations1-3. Using combina- torial methods, it is straightforward to generate thousands of potential asymmetri…     

甲基丙烯酸三苯墓甲酯和甲基丙烯酸酯类的共聚物在溶液中的螺旋诱导和解旋作用

甲基丙烯酸三苯墓甲酯和甲基丙烯酸酯类的共聚物在溶液中的螺旋诱导和解旋作用陈传福，刘卫宏，陈永明，任长玉，习复（中国科学院化学研究所北京１０００８０）关键词甲基丙烯酸三苯基甲酯，甲基丙烯酸甲酯，光学活性，螺旋诱导，解旋在手性阴离子复合引发剂存在下，甲基...     

利用AFM和SNOM对淋巴细胞膜表面超微结构及其光学性质的初步研究

利用原子力显微镜(Atomic Force Microscopy，AFM)对淋巴细胞表面形貌进行了形态学的初步研究，观察到了其膜表面其他显微技术所不能发现的超微结构．同时也运用扫描近场光学显微镜(Scanning Near field Optical Microscopy，SNOM)对淋巴细胞进行成像，观察了其对光的透射、吸收等光学性质，并对两种成像方法进行了比较．研究发现：淋巴细胞膜表面凹凸不平，分布着大量直径几十到几百纳米不等的小颗粒；淋巴细胞中央部位有自发荧光现象．结果表明，AFM和SNOM可作为进一步探讨淋巴细胞的结构与功能关系的有力工具．     

双折射光纤中克尔效应及光纤－光学逻辑门

本文详细地研究了单模双折射光纤中的克尔效应．讨论了其应用于光纤－光学逻辑门的优点,给出了有关的理论分析和计算结果以实验装置,确定了强度型逻辑门的“１／０”状态,测出了输出光脉冲宽度．理论分析和实验结果符合良好．