Photopromoted carbonylation of 1-bromo-6-chlorohexane under ambient conditions

Photopromoted carbonylation of 1-bromo-6-chlorohexane with CO catalyzed by CuBr2 and CdI2 has been carried out under ambient conditions. The results indicate that the carbonylation proceeds with the major product of chloroester ClCH2（CH2）5COOCH3 under catalysis of CuBr2. Furthermore, the activity of the carbonylation can be improved by addition of basic additives （NaOAc, Na3PO4 or （n-C4H9）3N）. Among these additives, （n-C4H9）3N is the most efficient in terms of the yield of ClCH2（CH2）5COOCH3. However, the methoxycarbonyl substituting chlorine product of BrCH2（CH2）5COOCH3 is not obtained in the presence of CdI2. This is quite different from the carbonylation of monochloroalkane.     

激光器机理及激光功率表达式的实验验证

运用光反馈的原理和技术演示并验证激光功率表达式，说明激光介质和光学谐振腔的性质和作用。     

SYNTHESIS OF NEW POLY （p—PHENYLENEVINYLENE） DERIVATIVES WITH IMPROVED SOLUBILITY

PPV－based copolymers with cyano group in the main chain have been synthesized by Wittig-type polycondensation of alkoxy-substituted dialdehydes and 4,4‘-bis(cyanomethyl)-substituted diphenyl ether:[-C6H4-O-C6H4-C(CN)=CH-C6H2(OR)2-C=C(CN)-]n(POPPV),The copolymers are highly soluble in common solvents and their super highly transparent homogeneous thin films can be formed by spin coating directly without heat treatment.The chemical structures are determined by NMR and IR spectroscopys and evaluated using photoluminescence,gel-permeation chromatography(GPC)and DSC(or TGA) methods.The incorporation of ether group into the PPV backbone has an interruption of the main-chain conjugation,that results in the blue-shift of electroluminescence spectra and enhancemnt the solubility.     

脉冲时间分辨光声量热法用于光厚溶液

近年来,用光声量热法(photoacoustic calorimetry,缩写PAC)测量液相体系中的光物理或光化学过程有了较快发展.这对于观测无辐射的瞬态粒子有重要意义。Peters及其同事曾分析过这种光声技术的原理.简言之,脉冲激光被体系吸收后将     

Exact Solutions and Coherence Structures of Generalized Breor-Kaup Equations

Using the mapping method based on q-deformed hyperbolic functions, the exact solutions of generalized Breor-Kaup equations are obtained. Based on the solutions, two coherent structures, periodic-branch kink and nonpropagating kink, have been obtained. Moreover, one solitonal interaction form, two line solitons interaction on the kink background, has been found.     

光干涉中光程差及半波损失

对光的干涉中光程差及半波损失问题作了分析 ,提供一种解答问题的方法和技巧     

硅衬底阳极氧化铝膜的荧光发射研究

报道了用电子束蒸发技术在硅守底上沉积，并于１５ｗｔ％Ｈ２ＳＯ４，温度２５℃和４０Ｖ直流电压条件下阳极氧化铝薄的制备（膜厚约４００ｎｍ）。研究了该阳极氧化铝膜的红外吸收光谱（ＦＴＩＲ）、光致荧光光谱（ＰＬ）和荧光激发光谱（ＰＬＥ）。发现其荧光光谱在２８０￣５００ｎｍ范围内由三个主发射带组成，其峰值分别位于３１２ｎｍ，３６７ｎｍ和４４９ｎｍ。所有这三个ＰＬ带，经分析都与阳极氧化铝膜中的氧化铝膜中的氧空