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111.
JiangMinCHEN LuLingWU XianHUANG 《中国化学快报》2004,15(2):143-144
2,5-Disubstituted oxazoles were prepared conveniently by treatment of aromatic α-methyl ketones and nitriles with poly[styrene(iodosodiacetate)] in one-pot process. 相似文献
112.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
113.
Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes 总被引:3,自引:0,他引:3
Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryaldehydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields. 相似文献
114.
XiangBaoMENG HuiLI QingLI ZhongJunLI 《中国化学快报》2004,15(7):777-778
An unusual reductive ring-opening reaction of phthalimide with sodium hydride in anhydrous DMF was observed for the first time. The presumed mechanism was described in detail. 相似文献
115.
本文通过研究匹配问题的实例空间,匈牙利算法和解空间三者之间的关系,指出S实例空间的数目与问题复杂度之间的关系既不是充分也不是必要的,而如何对问题的解空间进行合理的分解才能是问题的关键。 相似文献
116.
A layer of 40nm-thick Ag-SiN film with Ag nano-particles embedded and distributed randomly in the SiN thin film were deposited by the method of radiant-frequency magnetron sputtering. Specimens orderly comprising a random Ag-SiN film and an optical phase change recording layer were exposed to a focused laser beam with wavelength of 69Ohm. It is shown that, with a random Ag-SiN layer deposited above the recording layer. Calculation by the finite difference time domain method of a 4Ohm-thick SiN film under a Gaussian beam irradiation has been carried out to simulate the near-field distribution in the film, which showed a huge local near-field intensity enhancement of about 200 times if small Ag particles with diameter of 6 nm were modelled inthe SiN film in the central region of the in cident laser spot. 相似文献
117.
Nanoporous Structure in Low-Dielectric Films with Positronium Annihilation Lifetime Spectroscopy
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We investigate nano-porous structures in thin low-dielectric films, i.e. the pore sizes, distributions, and interconnectivity, by using depth profiled positronium annihilation lifetime spectroscopy (PALS). It is found that PALS has good sensitivity to probe both interconnected and closed pores in the range from 0.3nm to 3Onto, even in the film buried beneath a diffusion barrier. A series of low dielectric constant films of organosilicon-silsequioxane with different weight percentages of porogen have been comparatively investigated. The PALS technique can be used to distinguish the open porosity from the closed one, to determine the pore size, and to detect the percolation threshold with the increasing porosity that represents the transition from closed pores to interconnected pores.Furthermore, the pore percolation length can be derived. 相似文献
118.
119.
Structure and Photoluminescence of Nano-ZnO Films Grown on a Si (100) Substrate by Oxygen- and Argon-Plasma-Assisted Thermal Evaporation of Metallic Zn
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Nano-ZnO thin films were prepared by oxygen- and argon-plasma-assisted thermal evaporation of metallic Zn at low temperature, followed by low-temperature annealing at 300℃ to 500℃ in oxygen ambient. X-ray diffraction patterns indicate that the nano-ZnO films have a polycrystalline hexagonal wurtzite structure. Raman scattering spectra demonstrate the existence of interface layers between Zn and ZnO. Upon annealing at 400℃ for i h, the interface mode disappears, and photoluminescence spectra show a very strong ultraviolet emission peak around 381 nm. The temperature-dependent PL spectra indicate that the UV band is due to free-exciton emission. 相似文献
120.
二次谐波系统在浑沌态下的光子统计 总被引:3,自引:2,他引:1
数值分析了调制泵浦作用下的二次谐波产生系统的浑沌动力学行为.考虑到混沌运动的遍历性,提出一种研究浑沌态光场光子统计的数值方法,即通过数值积分求解系统动力学方程估计光子数的系统平均.运用这一方法于二次谐波系统,计算了其在浑沌态下的光子统计分布,结果表明是一种超Poisson分布. 相似文献