全文获取类型
收费全文 | 1869篇 |
免费 | 86篇 |
国内免费 | 198篇 |
专业分类
化学 | 1102篇 |
晶体学 | 15篇 |
力学 | 8篇 |
综合类 | 7篇 |
数学 | 701篇 |
物理学 | 320篇 |
出版年
2023年 | 19篇 |
2022年 | 18篇 |
2021年 | 20篇 |
2020年 | 34篇 |
2019年 | 42篇 |
2018年 | 33篇 |
2017年 | 33篇 |
2016年 | 22篇 |
2015年 | 27篇 |
2014年 | 52篇 |
2013年 | 144篇 |
2012年 | 95篇 |
2011年 | 67篇 |
2010年 | 84篇 |
2009年 | 87篇 |
2008年 | 127篇 |
2007年 | 145篇 |
2006年 | 106篇 |
2005年 | 98篇 |
2004年 | 70篇 |
2003年 | 73篇 |
2002年 | 81篇 |
2001年 | 61篇 |
2000年 | 63篇 |
1999年 | 64篇 |
1998年 | 61篇 |
1997年 | 45篇 |
1996年 | 64篇 |
1995年 | 49篇 |
1994年 | 67篇 |
1993年 | 49篇 |
1992年 | 36篇 |
1991年 | 19篇 |
1990年 | 17篇 |
1989年 | 9篇 |
1988年 | 11篇 |
1987年 | 8篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1972年 | 2篇 |
排序方式: 共有2153条查询结果,搜索用时 31 毫秒
41.
Jacqueline Ferrand 《Geometriae Dedicata》1996,61(1):103-120
This paper develops the theory of conformal invariants initiated inJ. Differential Geom
8 (1973), 487–510 for a Riemannian manifoldM with dimensionn2. We construct and study four conformally invariant functions M, M, M, M resp. depending on 4, 3 or 2 points onM, defined as extremal capacities for condensers associated with those points. These functions have similarities with the classical invariants onS
n
,R
n
orH
n
. Their properties, and especially their continuity, are efficient tools for solving some problems of conformal geometry in the large. 相似文献
42.
Let u(x, y) be defined in B
1×B
2 where B
1
m
and B
2
n
, and assume that u(x, ·) harmonic for every fixed x and u(·, y) is subharmonic for every fixed y. We show that if u(·, y) is, in addition, C
2 for each y then u is subharmonic in B
1×B
2 in both variables jointly. 相似文献
43.
Zhen-Qing Chen 《Potential Analysis》1996,5(4):383-401
Let D be an open set in d and E be a relatively closed subset of D having zero Lebesgue measure. A necessary and sufficient integral condition is given for the Sobolev spaces W
1,2 (D) and W
1,2(D\E) to be the same. The latter is equivalent to (normally) reflecting Brownian motion (RBM) on
being indistinguishable (in distribution) from RBM on
. This integral condition is satisfied, for example, when E has zero (d–1)-dimensional Hausdorff measure. Therefore it is possible to delete from D a relatively closed subset E having positive capacity but nevertheless the RBM on
is indistinguishable from the RBM on
, or equivalently, W
1,2(D\E)=W1,2(D). An example of such kind is: D=2 and E is the Cantor set. In the proof of above mentioned results, a detailed study of RBMs on general open sets is given. In particular, a semimartingale decomposition and approximation result previously proved in [3] for RBMs on bounded open sets is extended to the case of unbounded open sets.Research supported in part by NSF Grant DMS 86-57483. 相似文献
44.
R. Ficarra M. L. Calabrò S. Tommasini D. Costantino M. Carulli S. Melardi M. R. Di Bella F. Casuscelli R. Romeo P. Ficarra 《Chromatographia》1996,43(7-8):365-368
Summary A high-performance liquid chromatographic method is reported for the resolution of the enantiomers of a series of fused -lactams (2,7-diaza-3-oxo[3.3.0]octan-6-ones) with probable anti-HIV and anticancer activity. Resolution was achieved on a Chiralcel® OD column, cellulose tris-(3,5-dimethylphenyl carbamate) adsorbed on macroporous silica gel; mixtures ofn-hexane and isopropyl alcohol in different proportions were used as the mobile phase. The analysis was studied at different temperatures. 相似文献
45.
Summary In a simply connected planar domainD the expected lifetime of conditioned Brownian motion may be viewed as a function on the set of hyperbolic geodesics for the domain. We show that each hyperbolic geodesic induces a decomposition ofD into disjoint subregions
and that the subregions are obtained in a natural way using Euclidean geometric quantities relating toD. The lifetime associated with on each
j
is then shown to be bounded by the product of the diameter of the smallest ball containing
j
and the diameter of the largest ball in
j
. Because this quantity is never larger than, and in general is much smaller than, the area of the largest ball in
j
it leads to finite lifetime estimates in a variety of domains of infinite area.Research of the first author was supported in part by NSF Grant DMS-9100811Research of the second author was supported in part by NSF Grant DMS-9105407 相似文献
46.
Compounds of general formulatrans-ArNi(PR3)2OAr' (R = Et, cyclohexyl; Ar = 2-MeC6H4, 2-FC6H4; Ar' = 4-FC6H4, 4-NO2C6H4) were synthesized by the reaction of Ar'OK with cationic nickel complexes generated by treatment of ArNi(PR3)2Cl with TlBF4. Syntheses of 4-fluorophenoxide complexes, ArNi(PR3)2OC6H4F-4, additionally give some quantities oftrans-[ArNi(PR3)2OC6H4F-4][HOC6H4F-4] adducts. Exchange reactions MeC6H4Ni(PEt3)2OC6H4F-4 + XC6H4OH 2-MeC6H4Ni(PEt3)2OC6H4X + 4-FC6H4OH were studied in THF. The equilibrium is shifted to the right as the acidity of ArOH increases. A linear relationship between lgK
eq and pK
a of XC6H4OH in DMSO was found. A conclusion concerning the strong polarization of the Ni-O bond was made on the basis of an analysis of the chemical shifts of fluorine atoms in 2-MeC6H4Ni(PEt3)2OC6H4F-4.Translated fromIvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2266–2271, November, 1995. 相似文献
47.
48.
A computational study is made of the effect of basis set upon the energy, properties and inversion barrier of the phosphine molecule. The calculations are performed at both the SCF and CI level. The flexibility of the double zeta basis is discussed in the light of the results. 相似文献
49.
The effect of geometry modifications of13C chemical shifts has been investigated in a small subset of molecules using both LO-INDO and Gaussian 70 (4–31) calculations. The Gaussian calculations, while known to give poor absolute shifts, compare well to the reparameterized semi-empirical INDO determinations in calculated shift changes. In virtually all cases the signs of the shift changes were found to be opposite to that of the changes in the calculated electronic energy. 相似文献
50.
19F and 1H NMR spectra of halocarbons 总被引:1,自引:0,他引:1
Foris A 《Magnetic resonance in chemistry : MRC》2004,42(6):534-555
19F NMR chemical shifts and coupling constants are reported for 215 compounds. For 77 of these compounds, 1H NMR spectral data are also given. Long-range couplings, including 8J(F,F) and 5J(F,H), are reported. The complexity of halocarbon spectra owing to the presence of rotational isomers, asymmetric centers, long-range couplings, and chlorine isotope effects are illustrated, and the methods used for analyzing such complex spectra are briefly discussed. 相似文献