全文获取类型
收费全文 | 727篇 |
免费 | 65篇 |
国内免费 | 22篇 |
专业分类
化学 | 501篇 |
晶体学 | 6篇 |
力学 | 33篇 |
综合类 | 6篇 |
数学 | 46篇 |
物理学 | 222篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 8篇 |
2018年 | 14篇 |
2017年 | 12篇 |
2016年 | 12篇 |
2015年 | 18篇 |
2014年 | 16篇 |
2013年 | 14篇 |
2012年 | 9篇 |
2011年 | 12篇 |
2010年 | 17篇 |
2009年 | 8篇 |
2008年 | 15篇 |
2007年 | 16篇 |
2006年 | 11篇 |
2005年 | 11篇 |
2004年 | 9篇 |
2003年 | 13篇 |
2002年 | 13篇 |
2001年 | 9篇 |
2000年 | 9篇 |
1999年 | 10篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 66篇 |
1984年 | 32篇 |
1983年 | 49篇 |
1982年 | 54篇 |
1981年 | 56篇 |
1980年 | 30篇 |
1979年 | 29篇 |
1978年 | 22篇 |
1977年 | 29篇 |
1976年 | 31篇 |
1975年 | 35篇 |
1974年 | 36篇 |
1973年 | 34篇 |
排序方式: 共有814条查询结果,搜索用时 7 毫秒
1.
采用DIS数字信息化系统,对不同浓度的蓝墨水溶液在激光光源照射下的透射平均照度及照度分布图像进行实验研究,得到了平均照度值随溶液浓度变化的规律。对不同颜色塑料膜片对白炽灯光源透过照度值及照度分布图像进行实验研究得到及其相关之规律。 相似文献
2.
YANG Yuanhong 《Chinese Journal of Lasers》1997,6(6):518-522
NovelAlDigitalSchemeforOpenLoopFiberOpticGyroscopesYANGYuanhong(The5thResearchDivisionofBeijingUniversityofAeronauts&Astronau... 相似文献
3.
B. Brocklehurst R.S. Dixon E.M. Gardy V.J. Lopata M.J. Quinn A. Singh F.P. Sargent 《Chemical physics letters》1974,28(3):361-363
Excited state formation by ion recombination in solutions of fluorene in squalene has been studied by pulse radiolysis at the center of a large electromagnet. The products of the slower part of the ion recombination are affected by an applied magnetic field. The fluorescence yield increases by a factor of about 1.5 whereas the triplet yield decreases. 相似文献
4.
Two methods for the determination of polyethylene glycols (PEGs) in aqueous solution by precipitation with iodine have been developed. For PEGs with molecular weight 4 x 10(3)-2 x 10(4) the excess of iodine is titrated with thiosulphate, and for PEGs with average m.w. > 2 x 10(4) turbidimetric measurement is used. Both methods are relatively simple and give accurate and reproducible results. 相似文献
5.
Two new intermetallic compounds have been synthetized and structurally studied by single crystal diffractometric data: Ca7Au3 (oP80, space groupPbca,a = 20.742(8), b = 18.036(8), c = 6.665(2) A?,Z = 8, R = 0.051) and Ca5Au4 (mP18, space groupP21/c, a = 8.028(3), b = 8.019(6), c = 7.727(3) A?, β = 109.16(6)°,Z = 2, R = 0.104). Both atomic arrangements, which represent new structural types, are based on Au-centered Ca trigonal prisms and are geometrically related to the Th7Fe3 and Pu5Rh4 structures. 相似文献
6.
Horst P. Beck 《Journal of solid state chemistry》1983,47(3):328-332
A high pressure phase BaI2-II, which can be quenched and retained as a metastable form at ambient conditions, is reported. The structure has been determined by X-ray investigations using single crystals. BaI2-II crystallizes in an anti-Fe2P-type arrangement, space group Å, c = 5.173(3)Å, which is slightly denser than the PbCl2-type structure found at normal pressure. Structural features of the two phases are discussed in comparison. 相似文献
7.
The shift of the uncoupled OH stretching frequency of water (from its free state position) in crystal hydrates has been plotted against a parameter r0 obtained by subtracting the H-bond (OH...Y) length from the sum of the free state ionic radii of O and Y. From an analysis of this curve it is inferred that MOw coordination in hydrates reduces the ionic size of water oxygen and its effect on the OH stretching frequency is opposite to that of H-bonding. 相似文献
8.
A systematic study of the adsorption and interfacial behaviour of the adenine mono-nucleotides (5′-AMP, 3′-AMP, cyclic 3′,5′-AMP, 5′-ADP and 5′-ATP) and adenosine for comparison at the HMDE has been carried out at pH 3.4 to 3.5. Thus, the N(1) of the adenine moiety is protonated to a major extent.The adsorption was followed by single sweep voltammetry (measurement of the time integral of the reduction peak of the adsorbed adenine moiety) and by a.c. voltammetry (out-of-phase component of the a.c. response being proportional to the differential double layer capacity). In this paper the situation corresponding to a “dilute” adsorption layer existing at low bulk concentrations is studied for various degrees of coverage. The potential dependence of the coverage is of bell shaped type with an extended maximum region around the potential of electrocapillary maximum (Eecm) of the blank. For the same bulk concentration the coverage decreases in the series AMP, ADP, ATP, i.e. with increasing negative charge of the nucleotide, and at the same time the potential range of adsorption narrows. Among the monophosphates the coverage decreases in the series 3′-AMP, 5′-AMP, cyclic 3′,5′-AMP. The variations are connected with the varying charge of the mononucleotides and with the possibilities for interactions with adjacent molecules in the adsorption layer.At elevated bulk concentrations above a threshold value a substantial increase in coverage occurs around Eecm as due to strong interactions between the adsorbed base moieties a rather compact film is formed. 相似文献
9.
C.N.R. Rao Om Parkash D. Bahadur P. Ganguly S. Nagabhushana 《Journal of solid state chemistry》1977,22(3):353-360
Electronic and magnetic properties of Ln1?xSrxCoO3 (Ln = Pr, Nd, Sm, Eu, and Gd) systems show that above a critical value of x, the d electrons become itinerant while the materials become ferromagnetic at low temperatures. The ferromagnetic component increases with increase in x and decrease in temperature. The Curie temperature increases with x and decreases with decrease in the size of the rare-earth ion. Incorporation of Ba2+ in LaCoO3 favors itinerant electron ferromagnetism relative to Sr2+ while Ca2+ is less favorable than Sr2+. 相似文献
10.
Kinetics of Bz2O2-initiated polymerization of VAC in pyridine at 60° were investigated. The polymerization was significantly retarded by pyridine. The monomer exponent decreased from 2.5 at a relatively low [Bz2O2] (1.0 × 10?2 M) to 2.0 at [Bz2O2] ? 4.0 × 10?2 M. The observed kinetic features were explained on the basis of degradative chain transfer and copolymerization with pyridine. 相似文献