Molecular Rectangle Formed by Head-to-tail Self-Assembly of 1-(Dipyrrin-2-yl)-1-(dipyrrin-3-yl)methane

Summary. 1-(Dipyrrin-2-yl)-1-(dipyrrin-3-yl)methane, the N-confused analog of biladiene-ac, is prepared by condensation of 2,3-dipyrromethane with two molecules of 2-formylpyrrole in dichloromethane in the presence of hydrogen bromide. Self-assembly of the ligand with Zn(II) in dichloromethane and methanol offers a dinuclear dimeric complex with a ligand:metal ratio of 2:2. X-Ray crystal structure analysis reveals two ligands bound through a head-to-tail pattern to two zinc centers to form a severely distorted helical conformation, which has the shape of a rectangle.     

输电铁塔四地脚螺栓塔脚板抗拉承载力试验与计算方法研究

针对架空输电线路铁塔中常用的四地脚螺栓塔脚板进行了抗拉承载力试验和理论计算方法研究。首先,选取8个试件进行塔脚板抗拉承载力试验研究,分析塔脚底板板厚及有无加劲板对塔脚板抗拉承载力的影响;其次,通过有限元模拟塔脚板的应力分布情况,并结合“塑性分析,弹性设计”的思想,提出了一种基于屈服线理论的四地脚螺栓塔脚板抗拉承载力计算公式;最后,与试验结果、有限元仿真结果、已有技术规定中的计算结果进行了对比。结果表明:建议公式与试验结果和仿真结果较为吻合,相关技术规定中的计算结果偏于保守,验证了本文建议公式的精确性;底板厚度和加劲板的作用对塔脚板承载力影响较大。研究结果可为输电铁塔四地脚螺栓塔脚板结构设计提供参考。     

Hardness and phase analysis of IN 718 deformed at high strain rate

Specimens of the nickel base alloy IN 718 deformed at high strain rate (~10 s^–1), as realized in a screw press, have higher strength than parts forged conventionally in a hydraulic press. Microstructure analyses in light and transmission electron microscopes reveal the precipitation of very small Ni₃Nb particles (-phase) to be the reason for the increased hardness. Several processing routes are discussed and analyzed in relation to the TTT-diagram of IN 718.     

散裂靶中质子束窗的散射效应

 质子束窗是在高功率靶区中的一个分界窗,它将质子输运线上高真空区域和氦容器中的氦环境分开。在其他散裂中子源中质子束窗的热效应以及机械问题都已经被研究过了,但质子束在该窗中散射效应的研究却很少被报导,然而在靶设计中如果没有处理好质子束窗的散射效应会有很大的问题。报导了质子束窗散射效应的模拟计算结果,包括不同质子束窗的材料和结构选择,并以中国散裂中子源（CSNS）为例,介绍了在CSNS一期和二期中质子束窗采用周边水冷的铝合金单层结构,CSNS三期采用中间水冷的铝合金夹层结构。文中给出了不同结构的质子束窗和不同的与靶距离散射效应对靶上经非线性磁铁均匀化的束流分布的影响的模拟计算结果。模拟结果显示质子窗的散射效应对束流损失和靶上的束流分布有重要的影响。     

Discusión sobre el artículo «Evaluación numérica del efecto del espesor de la placa de contacto en la acción de palanca en conexión de acero tipo T» de L.M. Bezerra,C.S. de Freitas,W.T. Matias y J.E. Carmona

A discussion is proposed on the paper “Evaluación numérica del efecto del espesor de la placa de contacto en la acción de palanca en conexión de acero tipo T” by L.M. Bezerra, C.S. de Freitas, W.T. Matias and J.E. Carmona. The topics to be discussed are the definition of the T-stub model, the bibliographic references used in the work and the finite element analysis assumptions adopted in the modeling of the components.     

Shear Failure of Inconel 718 under Dynamic Loads

Kinetics of deformation and fracture of nickel–iron alloy Inconel 718 under dynamic shear loading was measured using a split torsional Hopkinson bar facility and high-speed photography. Tubular specimens with a reduced gage length and a starter notch were sheared at strain rates up to 6 × 10³ s⁻¹. High-speed photographs of fiducial lines scribed on the specimen surface showed the development of local strains and cracking. This paper describes the experimental and analytical procedures, illustrates average and local plastic strain evolution, and presents shear crack initiation times and propagation speeds.     

Synthesis and rheological properties of star-shaped polydimethylsiloxanes based on carbosilane dendrimers

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通过化学成分检测、金相组织分析、氢含量的测定、断口的宏微观观察、大直径高强螺栓的原型件拉伸试验以及有限元分析等手段从材料、结构、制造工艺三个方面上探究了ITER磁体支撑718螺栓低强度断裂的原因。材料分析结果表明,国产718螺栓材料的性能满足要求。工艺分析结果表明,螺栓低强度断裂的主要原因为滚压螺纹后的热处理导致螺纹根部脆性。结构分析结果表明,由于应力集中的影响,718螺栓的强度低于原材料强度,而且随着螺栓直径的增大而降低。基于以上分析结论,提出了能显著提高718螺栓强度的新工艺。通过原型件的拉伸试验,新工艺螺栓可以有效地提高螺栓的强度160MPa,达到1230MPa。     

The mathematics of the grand unified theory

This paper surveys the mathematics of GUT and highlights the author’s new real number system which is a continuum, non-Archimedean and non-Hausdorff, but its subspace of decimals is countably infinite, discrete, Archimedean and Hausdorff. The paper also proves Goldbach’s conjecture in and provides an overview of GUT and qualitative and computational models of many of the presently ill-defined physical concepts, e.g., gravity.     

Laser controlled melting of pre-prepared inconel 718 alloy surface

Laser treatment of Inconel 718 alloy surface is carried out. The alloy surface is coated with a carbon layer containing 7% TiC particles prior to the laser treatment. The carbon coating provides increased absorption of the incident laser beam and holds TiC particles. The microstrutural and morphological changes in the laser treated region are examined using optical and scanning electron microscopes, energy dispersive spectroscopy, and X-ray diffraction. The microhardness of the surface is measured and the residual stress formed at the surface vicinity is determined from the XRD technique. It is found that partial dissolution of carbide particles takes place at the surface. The composition of fine grains at the surface vicinity, nitride compounds formed, and dissolution of Laves phase at the surface region enhances the hardness at the treated surface. In addition, laser treated surface is free from the micro-crack network and cavities.