大米中硒的FI-HG-AAS测定方法研究

研究了原子化器温度、载气流速、KBH4 浓度等条件对流动注射 氢化物发生 原子吸收光谱法 (FI-HG -AAS)测定硒时的影响。建立了FI-HG -AAS测定大米中硒的分析方法。在优化的工作条件下 ,测定硒的最低检测浓度为 0 3 3 μg·L- 1,线性范围为 0～ 5 0 μg·L- 1,相对标准偏差小于 4% ,加标回收率为 94%～ 1 0 2 %。本法克服了传统的间断氢化物发生 原子吸收光谱法分析速度慢、样品耗量大、操作繁琐且因手工进样在进样速度和进样体积上容易带来误差等缺点。方法操作简便、快速 ,灵敏度及自动化程度高 ,已广泛应用于大米及富硒大米中微量硒的测定     

粒径和流速对吸附速率的影响

本文主要考察了吸附剂的粒径大小及动态循环时流速大小对吸附速率的影响，根据膜扩散限制和孔隙扩散限制的理论模型对其影响作了定量描述。     

复杂电渗泵系统的输液特征

基于对电渗泵中压强产生原理的讨论, 对新兴的复杂串、并联电渗泵系统的流体输液特征加以研究. 在多级串联电渗泵系统中, 可以通过增加电渗泵的级数或操作电压来提高泵系统产生的压强, 但是单一流路的输液能力有限. 而在多级并联电渗泵系统中, 输液量也可以通过增加电渗泵的级数或操作电压得到提高. 在这一体系中, 尽管输液量的叠加有利于其在更为广泛的领域中应用, 但是因Joule热产生的电场强度与电渗流速度线性关系的偏离也使得其线性范围变小, 不利于操作条件的控制.     

增殖剂球床载气体流动特性

增殖剂球床是聚变堆或混合堆产氚包层可选结构之一,准确把握增殖剂球床中载带气体的流动特性有助于提高对球床载氚过程的认识并优化包层设计。采用离散元程序PFC3D模拟增殖剂小球的填充行为,在球床内不同位置随机截取不同尺寸的控制体,利用布尔运算中的差集得到孔隙范围,建立孔隙分布的三维几何模型,进一步划分网格并用计算流体力学（CFD）方法求解,得出控制体上单位长度的压降以及单元体内的速度分布特征,计算结果发现载带气体速度分布与分布很类似,且只要选取恰当的控制体,通过计算流体力学方法可以较好地分析整个球床孔隙内流体的流动,有利于进一步研究载氚及相关过程。     

带滩槽地形的连续弯道中纵向流速横向分布解析

本文基于沿水深积分的动量方程,假定二次流项和弯道附加应力项沿横断面呈线性分布,提出了预测弯道垂线平均纵向流速的解析计算方法,进一步提出了河槽区和河滩区垂线平均纵向流速沿断面分布的求解模式,并将其应用于带滩槽地形的反向连续弯道水槽中.根据实测数据率定计算参数,该模式可计算不同出口水深条件下断面垂线平均纵向流速分布,计算结...     

紫外光离子源-高场不对称波形离子迁移谱检测环境中挥发性有机物

本研究采用紫外光离子源-高场不对称波形离子迁移谱(UV-FAIMS)快速检测环境中挥发性有机物.选取苯和对二甲苯为研究对象,并分析了分离电压、流速等因素对其分离识别的影响.实验结果表明:当分离电压值为0～1200 V时,苯和对二甲苯信号强度逐渐降低,而特征补偿电压值却逐渐增加.实验选取分离电压值为900 V,当载气流速为0～240 L/h时,苯和对二甲苯的特征离子峰信号强度逐渐增加,当载气流速为0～120 L/h时,苯和对二甲苯团簇峰信号强度增加,当载气流速为120～240 L/h时,苯的团簇峰信号强度增加,而对二甲苯的团簇峰信号强度降低.此外,对样品浓度、信号强度与噪声的比值进行探讨,获得UV-FAIMS检测苯的检测限为0.011mg/m3.     

Velocity overshoot of start-up flow for a Maxwellfluid in a porous half-space

Stokes' first problem has been investigated for a Maxwell fluid in a porous half-space for gaining insight into the effect of viscoelasticity on the start-up flow in a porous medium. An exact solution was obtained by using the Fourier sine transform. It was found that at large values of the relaxation time the velocity overshoot occurs obviously and the system exhibits viscoelastic behaviours. On the other hand, for short relaxation time the velocity overshoot disappears and the system exhibits viscous behaviours. A critical value of the relaxation time was obtained for the emergence of the velocity overshoot. Furthermore, it was found that the velocity overshoot is caused by both the viscoelasticity of the Maxwell fluid and the Darcy resistance resulting from the structure of the micropore in the porous medium.     

Result of search for low velocity exotic particles

The L3＋C experiment, taking advantage of the L3 muon magnetic spectrometer, measured the spatial tracks of charged cosmic ray particles to obtain rigidity as well as velocity. One possible low velocity exotic particle is observed. The existing uncertainties are discussed, and the flux upper limit of the low velocity exotic particles from this observation is deduced based on the assumption of a null observation. The result is 6.2×10^-10 cm^-2·s^-1·sr^-1 at 90% confidence level in the velocity range from 0.04c to 0.5c.     

测定不同形状物体空气阻力系数的实验

设计空气流速连续可调的小型风洞,对圆形平板、圆柱体、流线体的空气阻力系数进行测量.利用U型管中水柱的高度差表达孔板法中空气的流速,通过悬臂梁力传感器测量测试物受到的空气阻力,根据空气阻力和U型管中水柱的高度差的关系测定空气阻力系数.     

Steady state speed distribution analysis for a combined cellular automaton traffic model

Cellular Automaton （CA） based traffic flow models have been extensively studied due to their effectiveness and simplicity in recent years. This paper develops a discrete time Markov chain （DTMC） analytical framework for a Nagel-Schreckenberg and Fukui Ishibashi combined CA model （W^2H traffic flow model） from microscopic point of view to capture the macroscopic steady state speed distributions. The inter-vehicle spacing Maxkov chain and the steady state speed Markov chain are proved to be irreducible and ergodic. The theoretical speed probability distributions depending on the traffic density and stochastic delay probability are in good accordance with numerical simulations. The derived fundamental diagram of the average speed from theoretical speed distributions is equivalent to the results in the previous work.