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921.
Vanadium Doped Sol-Gel TiO2 Coatings 总被引:1,自引:0,他引:1
Maria Crisan Maria Zaharescu D. Crisan Rodica Ion Mihaela Manolache 《Journal of Sol-Gel Science and Technology》1998,13(1-3):775-778
A study of the experimental conditions required to obtain vanadium doped sol-gel TiO2 coatings is presented. Tetraethyl orthotitanate was employed as the TiO2 source and VCl3, VOSO4 · H2O and VOSO4 dissolved H2SO4 where employed as vanadium sources.Dip coating has been used to produce coatings on silicon wafers, spectral carbon electrodes and titanium electrodes. Both supported and unsupported films have been studied by UV-Vis spectra, IR spectroscopy and X-ray diffraction (XRD). The measurements have been made on samples as prepared and treated thermally at temperatures between 100°C and 300°C. The thermal treatment temperatures have been established from DTA/TGA measurements.The vanadium doped sol-gel TiO2 coatings have been tested as sensors for redox potential measurements in electrochemical processes. The influence of both the thickness of films and the nature of substrate has been investigated. 相似文献
922.
用热聚法固定指示剂的光纤氧气传感器研究 总被引:5,自引:0,他引:5
采用热聚法将甲叉双丙烯酰胺(MBBA)聚合并共价交联在硅烷化的玻璃微珠上 ,同时将指示剂Ru(Ⅱ)-邻啡咯啉配合物物理包埋于聚合物中,研制了一种基于 荧光猝灭原理的光纤氧气传感器,采用NaHSO_3-O_2-MnSO_4体系引发MBBA水溶液热 聚合后应,通过确定NaHSO_3,MnSO_4,MBBA和Ru(phen)_3Cl_2的最佳反应浓度以及 玻璃微珠的尺寸,优化了聚合反应条件,改善了指示剂的固定效果,制备了性能较 好的传感器探头,该传感器的检测下限为5×10~(-6)(V/V),响应时间为10s该传感 器连续工作50min,重复性标准偏差为±1%。 相似文献
923.
利用X衍射(300, 270, 250 K)和中子衍射(300, 260, 250, 240 K)研究D-氨酸单晶在静态的和动力学的变温过程中的结构特征以及考证Salam预言的由D到L构型转变的可能性. 实验发现丙氨酸晶体的空间群P212121对称性没有改变. 实验结果否定了构型相变的可能,但是发现在~250 K有一个微小的、连续的对称性破缺发生. 晶体分子振动产生的环电流模型可以用来解释D-和L-丙氨酸单晶直流磁化率和天然旋光角相反的现象, 与之相关的中子衍射数据进一步揭示了变温过程中αC-H(2), N-H(1), N-H(4), N-H(6) 键长的不同变化. 中子衍射还显示了质子移动所导致的动力学无序,来源于分子内氨基和羧基形成的氢键和分子间αC-H和氨基形成的氢键,从而产生的晶格扭曲和NH3+的扭转. 实验结果表明Salam预言相变不是传统意义的结构相变,而是由于温度效应导致了在相变点附近分子的宇称破缺能差(PVED)增大,然后通过氨基酸分子的隧道效应扩大了宇称破缺能差的影响,这一研究为生命现象中快速的均一手性形成提供了非线性机理的合理解释. 相似文献
924.
聚酰胺修饰碳糊电极测定槲皮素的研究 总被引:10,自引:0,他引:10
用聚酰胺修饰碳糊电极在pH360的Briton-Robinson缓冲溶液中,将槲皮素开路富集一定时间后,从045V(vs.Ag/AgCl)向阴极化扫描至-055V获得I-E曲线。槲皮素的峰电位为018V。峰电流与槲皮素浓度在10~400μmol/L范围内呈良好的线性关系。所拟定方法用于芦丁水解产物测定,结果满意。 相似文献
925.
用X射线衍射分析、FT-IR、小角X光散射等方法研究了浸渍法制备的NiO/SiO_2和NiO/(La_2O_3+SiO_2)样品中组分之间的相互作用。La_2O_3在SiO_2上可形成近乎密置单层的分散。在负载了La_2O_3的SiO_2上,NiO的分散程度比在SiO_2上有明显提高,也更容易被还原,而且还原后所得金属镍粒子的平均粒度降低,小粒子所占百分比提高。这些结果表明,NiO/(La_2O_3+SiO_2)比NiO/SiO_2样品具有更高的加氢还原硝基普鲁卡因为胺基普鲁卡因的活性,与Ni/(La_2O_3+SiO_2)比Ni/SiO_2活性高的情形相一致。 相似文献
926.
Wen-Jia Zhou Shu-Juan Bao Yan-Yu Liang Ben-Lin He Hu-Lin Li 《Journal of Solid State Electrochemistry》2006,10(5):277-282
Pure-phase and well-crystallized spinel LiMn2O4 powders were successfully synthesized by a simple rheological phase method. The thermal behavior and structure properties
of the powders prepared by the rheological phase method compared with the solid-state reaction were investigated by thermogravimetry,
powder X-ray diffraction , scanning electron microscopy and transmission electron microscopy. According to the results of
the electrochemical tests, it is obvious that the sample resulting from the rheological phase method shows higher discharge
capacity and better cycling stability than one formed in the solid-state reaction. The cyclic voltammogram and columbic efficiency
curves also confirm that the product by the rheological phase method has a good cycling performance due to its fine cubic
spinel structure and morphology. 相似文献
927.
Single nucleotide polymorphism (SNP) arrays were used to detect chromosomal regions with DNA copy number alterations. Current statistical methods for microarray-based comparative genomic hybridization (array-CGH) analysis generally assume certain relationships among adjacent markers on the same chromosome, and these assumptions may be questionable. For an SNP-array-based CGH study, multiple normal reference SNP arrays were collected. In order to utilize these normal reference SNP arrays, we derived an empirical distribution of signal ratios for each SNP marker. With an assumed threshold value for the overall error rate control and the defined signal ratio ranges for chromosomal amplification and deletion, we proposed a procedure to identify chromosomal alteration regions based on several bootstrapped one-sample t-tests and the false discovery rate control. When we have multiple arrays for different individuals with the same disease, our method can also be used to detect SNP markers for chromosomal alteration regions that are common among these individuals. We applied our method to a published SNP array data set for breast carcinoma cell lines. For an individual with breast cancer, numerous chromosomal alteration regions were identified. Compared to results of previous studies, our method identified more chromosomal alteration regions, with some being implicated in the literature to harbor genes associated with breast cancer. For multiple cancer arrays, our results suggested the existence of common chromosomal alteration regions. However, a high proportion of false positives also indicated that genetic variations among different individuals with breast cancer can be present. 相似文献
928.
碳酸盐前驱物制备Y2O3超细粉及透明陶瓷 总被引:14,自引:1,他引:14
以Y(NO3)3和NH4HCO3为原料,通过向Y(NO3)3溶液中滴加NH4HCO3的方式制备了化学组成为Y2(CO3)3·2H2O的先驱沉淀物。研究了先驱沉淀物煅烧过程中的物相变化。先驱沉淀物1100℃煅烧4h后得到了平均粒径为60nm的无团聚Y2O3超细粉体。所得粉体不添加任何添加剂,在1700℃下真空烧结4h得到了透明Y2O3陶瓷。 相似文献
929.
A new catalytic kinetic spectrophotometric method has been developed for the determination of trace amount of manganese (II) in nonionic microemulsion medium. The method is based on the catalytic effect of manganese (II) on the oxidation of dahlia violet by potassium periodate with nitrilotriacetic acid as an activitor in the presence of nonionic microemulsion. Under the optimum conditions, the calibration graph is linear in the range of 0.0004-0.0056 μg ml−1 of manganese (II) at 580 nm. The detection limit achieved is 3.75×10−5 μg ml−1. Manganese (II) in foodstuff samples was determined with satisfactory results. 相似文献
930.
以99.995% Ce(NO3)3和强碱性阴离子交换树脂为原料,采用离子交换-双氧水氧化法合成制备出纳米CeO2晶体。并就离子交换反应中的Ce3+浓度、树脂加入速度和离子交换温度及H2O2加入速度等条件对CeO2粒径的影响进行了探讨,得出了离子交换-双氧水氧化法制备纳米CeO2晶体的最佳工艺条件。FTIR、TEM分析表明,离子交换法无需对合成的Ce(OH)3溶胶进行洗涤即可去除NO3-、CO32-等阴离子杂质,并用H2O2将该溶胶氧化,经真空干燥可制得粒径分布均匀,平均晶粒尺寸约3 nm,高纯度的CeO2粉体。 相似文献