Evaluation of 1.0 mm i.d. column performances on ultra high pressure liquid chromatography instrumentation

The present study focuses on the evaluation of 1.0 mm i.d. (internal diameter) columns on a commercial Ultra-High Pressure system. These systems have been developed specifically to operate columns with small volumes, typically 2.1 mm i.d., by reducing extra-column volume dispersion. The use of columns with smaller i.d. results in a reduced solvent consumption and required sample volume. The evaluation of the columns was carried out with samples containing neutral and pharmaceutical compounds. In isocratic mode, the extra-column volume produced additional band broadening leading to poor performances compared to equivalent 2.1 mm i.d. columns. By increasing the length of the column, the influence of the extra-column bandspreading could be reduced and 75,000 plates were obtained when four columns were coupled. In gradient mode, the effect of the extra-column contribution on efficiency was limited and about 80% of the performance of the 2.1 mm i.d. columns was obtained. Optimum conditions in gradient mode were further investigated by changing flow rate, gradient time and column length. A different approach of the calculation of peak capacity was also considered for the comparison of the influence of these different parameters.     

Convex hull: A new method to determine the separation space used and to optimize operating conditions for comprehensive two-dimensional gas chromatography

It is important to develop methods of optimizing the selection of column sets and operating conditions for comprehensive two-dimensional gas chromatography. A new method for the calculation of the percentage of separation space used was developed using Delaunay's triangulation algorithms (convex hull). This approach was compared with an existing method and showed better precision and accuracy. It was successfully applied to the selection of the most convenient column set and the geometrical parameters of second column for the analysis of 49 target compounds in wastewater.     

计算机辅助装调与传统基准传递技术相结合实现三镜消像散系统的装调

为满足复杂航天光学系统对精度的要求,克服传统基准传递技术与计算机辅助装调技术对多于3片反射镜的复杂光学系统进行装调时存在的局限性,提出了两种技术相结合的装调方法。采用提出的方法对三镜消像散(TMA)空间相机进行了装调,结果显示:三镜在Y向和Z向的失调量分别由18.651和9.879 mm降低到1.036和0.102 mm,系统波前差达到全视场平均值1/14λ(RMS)。结果证明:此方法能有效缩短装调时间并达到系统要求的精度指标,对于多镜复杂光学系统装调具有指导和参考价值。     

碳纤维复合材料在航天领域的应用

综述了碳纤维复合材料的应用现状和发展前景。首先,概述了碳纤维的分类和力学性能以及碳纤维复合材料的特性;重点介绍了碳纤维复合材料在国内外航天领域,特别是在卫星结构、运载火箭、精密支撑构件以及空间镜体等方面的应用情况。指出了目前碳纤维复合材料的主要问题是湿热效应。最后,结合我国国情,对碳纤维复合材料需要解决的问题提出了一些建设性的措施。     

基于铯原子光泵磁共振的磁场传感实验系统设计

给出了铯原子光泵磁共振测量磁场的原理.利用MEMS封装与制造技术,设计了一种芯片级的激光铯磁场传感系统,可实现对微弱磁场的检测.     

弱脉冲光时域平衡零拍测量的实验研究

设计了一套可以用来测量弱脉冲光时域噪声信息的平衡零拍探测系统,通过对本底光散粒噪声基准的测量分析了该系统的各项性能指标,并且对弱相干光脉冲进行了正交位相振幅分量的噪声测量。     

幂集上的线性空间

将线性空间的概念提升到线性空间的幂集上进行讨论,给出了线性空间的幂空间的定义,并研究了一种特殊幂空间的基本性质.     

LMI优化问题的择一性定理与对偶

考虑目标函数是线性函数约束条件为线性矩阵不等式的LMI优化问题,讨论了LMI优化问题中的四个择一性定理.每种类型的择一性定理包含两个线性不等式和(或)等式系统,一个原始系统和一个对偶系统.弱择一性定理说明两系统中至多只有其一有解;基于凸集分离理论得到的强择一性定理说明两系统有且仅有其一有解.并在此基础上推导了LMI优化...     

关于n维单形的两个轨迹定理

在n维欧氏空间En中,应用向量方法,给出了关于n维单形的两个优美的轨迹定理.     

Classification with Gaussians and convex loss Ⅱ:improving error bounds by noise conditions

We continue our study on classification learning algorithms generated by Tikhonov regularization schemes associated with Gaussian kernels and general convex loss functions. Our main purpose of this paper is to improve error bounds by presenting a new comparison theorem associated with general convex loss functions and Tsybakov noise conditions. Some concrete examples are provided to illustrate the improved learning rates which demonstrate the effect of various loss functions for learning algorithms. In our ...