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21.
In the present work, a three-dimensional (3D) elastic plate model capturing the small scale effects is developed for the free vibration of functionally graded (FG) nanoplates resting on elastic foundations. The theoretical model is formulated employing the nonlocal differential constitutive relations of Eringen in conjunction with the 3D equations of motion of elasticity.The material properties are assumed to vary continuously along the thickness of the nanoplate in accordance with the power law formulation. Through extending the generalized differential quadrature (GDQ) method to the three-dimensional case, the governing equations are simultaneously discretized in every three coordinate directions and are then recast to the standard form of an eigen value problem. Solving the acquired problem, the natural frequencies of the nanoplates with different boundary conditions are calculated. The convergence behavior of the numerical results is checked out and comparison studies are conducted to make sure of the accuracy and reliability of the present model. Finally, the dependence of the vibration behavior of the nanoplate on edge conditions, elastic coefficients of the foundation, scale coefficient, mode number, material and geometric parameters are discussed. 相似文献
22.
The free vibration analysis of a carbon nanotube (CNT) embedded in a volume element is performed using 3D finite element (FE) and analytical models. Three approaches consist of molecular and continuum mechanics FE methods and continuum analytical method are employed to simulate the CNT, interphase region and surrounding matrix. The bonding between CNT and polymer is treated as non-perfect bonding using van der Waals and triple phase material interaction in first and second approaches. In analytical approach a perfect bonding is assumed between nanotube and matrix. First, natural frequencies of CNT under different boundary conditions and aspect ratios are obtained by three approaches and the results are compared with published data. The results show the frequency response variations of CNT in GHz to THz range. Subsequently, vibration behaviors of CNT/polymer are evaluated and the results revealed the importance of interphase region role in the performance of nanocomposites. The results also showed the convergence of the natural frequencies for 1–2.5% of CNT volume in high aspect ratios using three methods, so that the interphase effects is negligible. In addition, it is observed that the molecular method due to interphase role has proper performance in vibration behavior investigation of volume elements. 相似文献
23.
The FT Raman spectra of the zero and first generations of phosphorus-containing dendrimers built from thiophosphoryl, cyclotriphosphazene and phthalocyanine core with terminal oxybenzaldehyde groups have been recorded and analyzed. The structural optimization and normal mode analysis were performed for dendrimers on the basis of the density functional theory (DFT). The calculated geometrical parameters, harmonic vibrational frequencies and Raman scattering activities are predicted in a good agreement with the experimental data. The experimental Raman spectra of dendrimers were interpreted by means of potential energy distribution. Relying on DFT calculations the lines of the cores, repeating units and terminal groups of dendrimers were assigned.The influence of the encirclement on the line frequencies and intensities was studied and due to the predictable, controlled and reproducible structure of dendrimers the information, usually inaccessible is obtained. The strong line at 1600 cm−1 show marked changes of intensity in dependence of aldehyde (CHO) or azomethyne (CHN) substituents in the aromatic ring. The polarizabilities and lipophilicity of dendrimers were estimated. 相似文献
24.
The aim of this work is to evaluate the dynamic properties of nonwoven flax, hemp, kenaf and glass fibre-reinforced polypropylene (PP) composites. Also, the influence of some parameters, such as the type of reinforcement, the fibre/matrix weight ratio, the fibre orientation and the porosity content, on the damping behaviour of these nonwoven composites is investigated. To this end, a free flexural vibrations analysis was conducted to experimentally identify their natural frequencies and their associated loss factors. The obtained results show that the nonwoven composites reinforced by natural fibres present higher loss factors compared with those of the glass-PP composite. These interesting damping properties make these nonwoven composites very attractive for automotive applications where the dissipation of vibrations is highly requested. 相似文献
25.
Yantao Pang Anoop Thomas Kalaivanan Nagarajan Robrecht M. A. Vergauwe Kripa Joseph Bianca Patrahau Kuidong Wang Cyriaque Genet Thomas W. Ebbesen 《Angewandte Chemie (International ed. in English)》2020,59(26):10436-10440
It is well known that symmetry plays a key role in chemical reactivity. Here we explore its role in vibrational strong coupling (VSC) for a charge‐transfer (CT) complexation reaction. By studying the trimethylated‐benzene–I2 CT complex, we find that VSC induces large changes in the equilibrium constant KDA of the CT complex, reflecting modifications in the ΔG° value of the reaction. Furthermore, by tuning the microfluidic cavity modes to the different IR vibrations of the trimethylated benzene, ΔG° either increases or decreases depending only on the symmetry of the normal mode that is coupled. This result reveals the critical role of symmetry in VSC and, in turn, provides an explanation for why the magnitude of chemical changes induced by VSC are much greater than the Rabi splitting, that is, the energy perturbation caused by VSC. These findings further confirm that VSC is powerful and versatile tool for the molecular sciences. 相似文献
26.
27.
The system of electrons on liquid helium is an interesting candidate to implement quantum computation, due to the long coherence times of the qubits encoded by the electronic spins. In order to implement the quantum logic operations between the spins, we propose here a configuration, similarly to the cooled ions in a trap, to couple the distant electrons via manipulating their center of mass (CM) vibrations. First, we show that the electrons could be confined in a common harmonic oscillator potential by using an electrostatic field. Then, with a single current pulse (applied on the micro-electrode below the liquid helium) the distant electronic spins can be coupled simultaneously to the CM mode. Finally, by adiabatically eliminating the CM mode, effective interaction between the distant spins is induced for implementing the desired quantum computing. 相似文献
28.
A passive vibration absorber, termed the nonlinear tuned vibration absorber (NLTVA), is designed for the suppression of chatter vibrations. Unlike most passive vibration absorbers proposed in the literature for suppressing machine tool vibrations, the NLTVA comprises both a linear and a nonlinear restoring force. Its linear characteristics are tuned in order to optimize the stability properties of the machining operation, while its nonlinear properties are chosen in order to control the bifurcation behavior of the system and guarantee robustness of stable operation. In this study, the NLTVA is applied to turning machining. 相似文献
29.
B. F. Kuntsevich 《Journal of Applied Spectroscopy》2002,69(3):388-394
The nonlinear dynamics of a CO2 laser having continuous electrical discharge pumping and loss modulation and generating in three vibrationalrotational lines of the same vibrational band is investigated theoretically. It is shown that it is possible to monitor the time and energy parameters of radiation in rather wide ranges by changing the depth and frequency of modulation and also the relationship between the constant components of losses. The character of the response of the threewave laser in loss modulation in one or two channels at certain parameters is similar to the response of a system with two degrees of freedom. In loss modulation simultaneously in three channels the response is equivalent to the response of a system with one degree of freedom. 相似文献
30.
P.?G.?ChufyrevEmail author N.?V.?Sidorov N.?N.?Mel'nik 《Journal of Applied Spectroscopy》2005,72(5):667-670
Using the Raman scattering spectra, we investigated the ordering of the structural units in the cation sublattice and the
photorefractive properties of lithium niobate single crystals of variable composition, i.e., nominally pure ones with different
Li/Nb ratios and those doped with the nonphotorefractive cations Mg2+, Gd3+, and Y3+. It is shown that at low concentrations of Mg2+, Gd3+, and Y3+ the magnitude of the photorefractive effect is substantially determined by the ordering of the structural units of the cation
sublattice. It has been found for the first time that the intensity of the line corresponding to the bridge valence vibrations
of oxygen atoms in the octahedrons of NbO6 is sensitive to the dipole ordering of the cation sublattice of the crystal.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 5, pp. 611–614, September–October, 2005. 相似文献