Mesoporous Titania Thin Film with Highly Ordered and Fully Accessible Vertical Pores and Crystalline Walls

We report the preparation of mesoporous titania thin films with the R m pore structure derived from the Im m self‐assembled ordering of the titania species and an EO₁₀₆PO₇₀EO₁₀₆ triblock copolymer. The films were spin‐cast and then aged at 18 °C at a relative humidity of 70 %, which led to the orientation of the Im m structure with the [111] direction perpendicular to the substrates. The [111] body‐diagonal channels became vertical channels upon calcination at 400 °C, thus leading to thin films with vertical channels. The pores are ordered over a large area of up to 1 μm². The titania films can be formed on various types of substrates. By using a titania film formed on a Pt‐coated Si wafer as a template, we produced by an electrochemical‐deposition technique arrays of gold nanowires, whose morphology suggests that most of the pores of the titania thin films are accessible. The pore structure of vertical channels is stable up to 600 °C, at which temperature the wall materials crystallize into anatase.     

The Magic Functions and Automorphisms of a Domain

We introduce the notion of magic functions of a general domain in and show that the set of magic functions of a given domain is an intrinsic complex-geometric object. We determine the set of magic functions of the symmetrised bidisc G and thereby find all automorphisms of G and a formula for the Carathéodory distance on G. Submitted: August 31, 2007. Accepted: November 11, 2007.     

Theoretical Study on the Spectroscopic Properties of CO3.−.nH2O Clusters: Extrapolation to Bulk

Vertical detachment energies (VDE) and UV/Vis absorption spectra of hydrated carbonate radical anion clusters, CO₃^.?.n H₂O (n=1–8), are determined by means of ab initio electronic structure theory. The VDE values of the hydrated clusters are calculated with second‐order Moller–Plesset perturbation (MP2) and coupled cluster theory using the 6‐311++G(d,p) set of basis functions. The bulk VDE value of an aqueous carbonate radical anion solution is predicted to be 10.6 eV from the calculated weighted average VDE values of the CO₃^.?.n H₂O clusters. UV/Vis absorption spectra of the hydrated clusters are calculated by means of time‐dependent density functional theory using the Becke three‐parameter nonlocal exchange and the Lee–Yang–Parr nonlocal correlation functional (B3LYP). The simulated UV/Vis spectrum of the CO₃^.?.8 H₂O cluster is in excellent agreement with the reported experimental spectrum for CO₃^.? (aq), obtained based on pulse radiolysis experiments.     

Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)6]·4H2O (Ln=lanthanide)

Along with crystallographic data of Ln[Fe(CN)₆]·4H₂O (Ln=lanthanide), the infrared spectra are reassigned to examine bond length trends across the series of Ln. The changes in mean Ln-O, Ln-N, CN and Fe-C distances are discussed and the bond natures of Ln-N and Ln-O are studied by bond length linear or quadratic fitting and comparisons with relevant ionic radii. The two different CN bond distances have been simulated by the covalo-electrostatic model.     

印制电路板缺陷图像边缘检测

为了提取含噪声印制电路板(PCB)光板缺陷图像边缘信息,提出了一种基于混合法的图像边缘检测方法.在分析类间最大距离法图像分割基本原理的基础上提出了一种改进的类间最大距离法(IMDBC);设计了结合中值滤波、IMDBC、改进的数学形态学边缘检测算子与LOG算子进行PCB光板缺陷图像边缘检测的混合方法.用CCD及显微镜成像系统获取4幅PCB光板缺陷图像,结果表明:用本文方法提取出的图像边缘信息清晰且较精确,噪声点较少,所得到的4幅图像优质系数是其它6种方法的1.0111~1.3586倍.     

一种基于相邻数据依赖性的混沌分析方法

混沌作为一种复杂的非线性行为,广泛存在于各个行业领域,对于混沌的研究具有重要的理论意义和应用价值.现在常用的混沌分析方法,如Lyapunov指数、关联维数、Poincaré图等,需要解决相空间重构、线性标度区选取等问题,且不能很好地兼顾定性与定量分析两方面.基于此,提出一种度量相邻数据依赖性的混沌分析方法,通过计算相邻数据间的距离变化,将复杂的一维原始数据列转换为新的相邻距离值序列进行分析,避免了相空间重构等问题,对于不同的典型混沌模型,如Logistic模型、Duffing振子、Lorenz模型等,均具有较好的分析效果,能够描述不同模型的混沌特性,直观与量化分析效果均较好,且具有一定的抗噪能力,由于不需要掌握真实的模型信息,更适用于模型未知的复杂实际问题.将相邻数据的距离值对于不同混沌状态的区分作用应用于机械转子振动信号分析,可以明显地识别出转子工作状态的变化,表明该方法具有良好的实际应用前景和潜力.     

二次偏振调制测距系统中调制频率与测距精度的关系

本文在基于二次偏振调制激光测距系统的基础上, 对调制频率与激光测距系统精度的关系做了深入的理论推导和实验验证. 最终得出结论: 相位法激光测距系统的测量精度会随着调制频率的增大而提高, 且精度的提高程度正比于调制频率的不确定度Δf与测程范围内半波长数N值的比值. 并通过选取合适的调制频率来提高系统的测距精度, 提高后的测距精度可达10^-7.     

1550nm-VCSELs在偏振保持光反馈和正交光注入下的偏振转换特性

基于自旋反转模型,研究了1550 nm垂直腔面发射激光器(1550 nm-VCSELs)在偏振保持光反馈和正交光注入下的偏振转换特性.结果表明:正交光注入下的从激光器会随着注入强度的增加产生偏振转换.在归一化注入电流较小时,改变反馈强度,会使从激光器发生偏振转换的注入强度出现规律不同的变化;改变频率失谐,会使从激光器发生偏振转换的注入强度出现规律相同的变化.     

1310nm垂直腔面发射激光器芯片制备技术的研究进展

垂直腔面发射激光器(VCSELs)在光纤通讯领域有着广泛的应用前景,国际上对VCSELs需求逐年增加,而国内目前VCSELs的产业化尚属空白。本文从两方面着手综述1 310 nm VCSELs制备方法。将可以制备出1 310 nm VCSELs的4种材料,从理论、制备、量产时需要考虑的因素等方面进行较为全面的汇总分析;同时对两种主流的制备方法从工艺步骤分析其在产业化方面的优势与不足。     

最大度为3的树的L(2,1)-标号数的一个刻画

图G的一个L(2,1)-标号是对G顶点集合的一个非负整数分配,使得其中相邻的点取得的整数差值至少为2并且距离为2的点取得不同的整数.L(2,1)-标号数就是所有这样的标号分配中最小的标号跨度值.Griggs和Yeh的[Labelling graphs with a condition at distance 2,SIAM J.Discrete Math.,1992,5:586-595]已经证明了,一棵树的L(2,1)-标号数不是△就是△+1.对于最大度为3的树的L(2,1)-标号数,本文给出了一个完全的刻画.