全文获取类型
收费全文 | 3233篇 |
免费 | 405篇 |
国内免费 | 266篇 |
专业分类
化学 | 603篇 |
晶体学 | 2篇 |
力学 | 290篇 |
综合类 | 132篇 |
数学 | 1802篇 |
物理学 | 1075篇 |
出版年
2024年 | 10篇 |
2023年 | 55篇 |
2022年 | 194篇 |
2021年 | 220篇 |
2020年 | 132篇 |
2019年 | 118篇 |
2018年 | 88篇 |
2017年 | 129篇 |
2016年 | 160篇 |
2015年 | 108篇 |
2014年 | 187篇 |
2013年 | 176篇 |
2012年 | 166篇 |
2011年 | 175篇 |
2010年 | 155篇 |
2009年 | 177篇 |
2008年 | 195篇 |
2007年 | 183篇 |
2006年 | 176篇 |
2005年 | 135篇 |
2004年 | 98篇 |
2003年 | 102篇 |
2002年 | 89篇 |
2001年 | 88篇 |
2000年 | 83篇 |
1999年 | 75篇 |
1998年 | 75篇 |
1997年 | 57篇 |
1996年 | 59篇 |
1995年 | 40篇 |
1994年 | 21篇 |
1993年 | 19篇 |
1992年 | 23篇 |
1991年 | 23篇 |
1990年 | 15篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1986年 | 6篇 |
1985年 | 13篇 |
1984年 | 10篇 |
1983年 | 9篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1959年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有3904条查询结果,搜索用时 31 毫秒
71.
针对三维调整机难以实现多台同步工作,设计了基于PLC的同步控制方案。在同步控制系统方案中,采用西门子PLC通过工业无线以太网进行同步控制,由各维度油缸的位移传感器来保证同步控制的精确性。经实验,证实了此系统的精度满足设计要求,实现了同步控制的效果。 相似文献
72.
73.
74.
Simple matching vs linear assignment in scheduling models with positional effects: A critical review
This paper addresses scheduling models in which a contribution of an individual job to the objective function is represented by the product of its processing time and a certain positional weight. We review most of the known results in the area and demonstrate that a linear assignment algorithm as part of previously known solution procedures can be replaced by a faster matching algorithm that minimizes a linear form over permutations. Our approach reduces the running time of the resulting algorithms by up to two orders, and carries over to a wider range of models, with more general positional effects. Besides, the same approach works for the models with no prior history of study, e.g., parallel machine scheduling with deterioration and maintenance to minimize total flow time. 相似文献
75.
When simulating free‐surface flows using the finite element method, there are many cases where the governing equations require information which must be derived from the available discretized geometry. Examples are curvature or normal vectors. The accurate computation of this information directly from the finite element mesh often requires a high degree of refinement—which is not necessarily required to obtain an accurate flow solution. As a remedy and an option to be able to use coarser meshes, the representation of the free surface using non‐uniform rational B‐splines (NURBS) curves or surfaces is investigated in this work. The advantages of a NURBS parameterization in comparison with the standard approach are discussed. In addition, it is explored how the pressure jump resulting from surface tension effects can be handled using doubled interface nodes. Numerical examples include the computation of surface tension in a two‐phase flow as well as the computation of normal vectors as a basis for mesh deformation methods. For these examples, the improvement of the numerical solution compared with the standard approaches on identical meshes is shown. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
76.
HUANG HouBing MA XingQiao YUE Tao XIAO ZhiHua SHI SanQiang & CHEN LongQing 《中国科学:物理学 力学 天文学(英文版)》2011,(7)
The current-induced magnetic switching is studied in Co/Cu/Co nanopillar with an in-plane magnetization traversed under the perpendicular-to-plane external field.Magnetization switching is found to take place when the current density exceeds a threshold.By analyzing precessional trajectories,evolutions of domain walls and magnetization switching times under the perpendicular magnetic field,there are two different magnetization switching modes:nucleation and domain wall motion reversal;uniform magnetization ... 相似文献
77.
《International journal of quantum chemistry》2018,118(2)
We investigate the success of the quantum chemical electron impact mass spectrum (QCEIMS) method in predicting the electron impact mass spectra of a diverse test set of 61 small molecules selected to be representative of common fragmentations and reactions in electron impact mass spectra. Comparison with experimental spectra is performed using the standard matching algorithms, and the relative ranking position of the actual molecule matching the spectra within the NIST‐11 library is examined. We find that the correct spectrum is ranked in the top two matches from structural isomers in more than 50% of the cases. QCEIMS, thus, reproduces the distribution of peaks sufficiently well to identify the compounds, with the RMSD and mean absolute difference between appropriately normalized predicted and experimental spectra being at most 9% and 3% respectively, even though the most intense peaks are often qualitatively poorly reproduced. We also compare the QCEIMS method to competitive fragmentation modeling for electron ionization, a training‐based mass spectrum prediction method, and remarkably we find the QCEIMS performs equivalently or better. We conclude that QCEIMS will be very useful for those who wish to identify new compounds which are not well represented in the mass spectral databases. 相似文献
78.
Soo Chung Christian M. Jennings Prof. Jeong-Yeol Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(57):13070-13077
In recent years, there has been high interest in paper-based microfluidic sensors or microfluidic paper-based analytical devices (μPADs) towards low-cost, portable, and easy-to-use sensing for chemical and biological targets. μPAD allows spontaneous liquid flow without any external or internal pumping, as well as an innate filtration capability. Although both optical (colorimetric and fluorescent) and electrochemical detection have been demonstrated on μPADs, several limitations still remain, such as the need for additional equipment, vulnerability to ambient lighting perturbation, and inferior sensitivity. Herein, alternative detection methods on μPADs are reviewed to resolve these issues, including relatively well studied distance-based measurements and the newer capillary flow dynamics-based method. Detection principles, assay performance, strengths, and weaknesses are explained for these methods, along with their potential future applications towards point-of-care medical diagnostics and other field-based applications. 相似文献
79.
In this paper, we propose a new methodology for numerically solving elliptic and parabolic equations with discontinuous coefficients and singular source terms. This new scheme is obtained by clubbing a recently developed higher‐order compact methodology with special interface treatment for the points just next to the points of discontinuity. The overall order of accuracy of the scheme is at least second. We first formulate the scheme for one‐dimensional (1D) problems, and then extend it directly to two‐dimensional (2D) problems in polar coordinates. In the process, we also perform convergence and related analysis for both the cases. Finally, we show a new direction of implementing the methodology to 2D problems in cartesian coordinates. We then conduct numerous numerical studies on a number of problems, both for 1D and 2D cases, including the flow past circular cylinder governed by the incompressible Navier–Stokes equations. We compare our results with existing numerical and experimental results. In all the cases, our formulation is found to produce better results on coarser grids. For the circular cylinder problem, the scheme used is seen to capture all the flow characteristics including the famous von Kármán vortex street. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
80.
《Journal of computational chemistry》2017,38(13):1005-1014
The fully polarizable, multipolar, and atomistic force field protein FFLUX is being built from machine learning (i.e., kriging) models, each of which predicts an atomic property. Each atom of a given protein geometry needs to be assigned such a kriging model. Such a knowledgeable atom needs to be informed about a sufficiently large environment around it. The resulting complexity can be tackled by collecting the 20 natural amino acids into a few groups. Using substituted deca‐alanines, we present the proof‐of‐concept that a given atom's charge can be modeled by a few kriging models only. © 2017 Wiley Periodicals, Inc. 相似文献