钯涂层石墨炉原子吸收热处理分离测定环境水样中的As~（3＋）／As~（5＋）

本文提出了一种较为简便的测定环境水体中Ａｓ３＋和Ａｓ５＋的方法。在研究了钯涂层石墨管性能的基础上，利用ＡｓＣｌ３的低沸点、高挥发性，在石墨炉升温过程中，使Ａｓ３＋在灰化阶段分离；改变灰化温度可以测定总Ａｓ含量。从而对Ａｓ３＋／Ａｓ５＋分别定量     

Comparison with experiment for TVD calculations of blast waves from a shock tube

Harten's second-order-accurate total-variation-diminishing (TVD) scheme is applied to calculation of flow from the open end of a shock tube. Comparison of numerical results with available experimental data for overpressure at selected points around the shock tube exit shows good agreement. Numerically indicated positions of the moving shock front and Mach stem also compare well with flow shadowgraph data. Where the problem geometry is sufficiently simple and rectangular gridding can be used, Harten's method affords a good choice for blast wave calculations.     

螺旋线行波管返波自激振荡的研究

 在2维小信号模型的基础上，分析了均匀和周期永久聚焦磁场对抑制返波自激振荡的影响。研究结果表明：改变聚焦磁场的幅值或周期来增加起振长度是可能的， 而且不会改变基波的互作用条件。与此同时，对起振长度、初始非同步速度参量随皮尔斯增益参量、空间电荷参量、损耗参量等的变化，以及在超宽带行波管中当存在两个或多个角向非对称空间谐波时,起振长度、初始非同步速度参量随周期永久聚焦磁场的变化进行了研究。优化设计聚焦磁场、电子注和螺旋线慢波系统的参量可以对螺旋线行波管的稳定性分析提供必要的依据。     

Undercooling and solidification of Ni77P23 alloy in a 52-m drop tube

This paper applies techniques of containerless processing, drop tube and glass fluxing, to undercool and solidify Ni77P23 alloys. Different diameter spheres were collected at the bottom of a 52-m long drop tube. Both crystalline and amorphous phase were formed in various size specimens due to the different cooling rate. The variation of partial undercooling with bulk undercooling is calculated for the Ni77P23 alloys. The deep undercooling and rapid solidification behaviour of Ni77P23 melts has been analysed with respect to microstructure formation and transition during fluxing and 52-m drop process of undercooled melts.     

不同压力下竖直管外Marangoni凝结换热特性研究

本文在不同压力状态下对水与酒精混合蒸汽在竖直管外Marangoni凝结换热特性进行了可视化实验研究,观测到不同过冷度下的凝结状态.实验结果表明,在相同流速和浓度条件下,酒精浓度较低时凝结换热系数随蒸汽压力的升高而升高.但在高酒精浓度下,凝结液表面张力梯度减小,扩散热阻的影响增大,蒸汽压力对于凝结换热系数的影响并不明显.     

气压对吸气式激光推进冲量耦合系数的影响

保持CO2激光的单脉冲能量为61.4~64.6 J，采用高精度冲击摆系统进行了不同气压下吸气模式激光推进冲量耦合系数的实验测试，分析了对应的高度特性。结果表明:气压为2.8×104～1×105 Pa，即距离地面0～10 km时，冲量耦合系数大约3.5×10-4 N·s·J-1，上下波动幅度低于5%；气压低于2.8×104 Pa，即高度大于10 km时，冲量耦合系数呈二次曲线显著下降；当气压降至1×103 Pa，即距离地面约31 km高度时，耦合系数仅为9.7×10-5 N·s·J-1。     

Methyl concentration time-histories during iso-octane and n-heptane oxidation and pyrolysis

Methyl radical concentration time-histories were measured during the oxidation and pyrolysis of iso-octane and n-heptane behind reflected shock waves. Initial reflected shock conditions covered temperatures of 1100-1560 K, pressures of 1.6-2.0 atm and initial fuel concentrations of 100-500 ppm. Methyl radicals were detected using cw UV laser absorption near 216 nm; three wavelengths were used to compensate for time- and wavelength-dependent interference absorption. Methyl time-histories were compared to the predictions of several current oxidation models. While some agreement was found between modeling and measurement in the early rise, peak and plateau values of methyl, and in the ignition time, none of the current mechanisms accurately recover all of these features. Sensitivity analysis of the ignition times for both iso-octane and n-heptane showed a strong dependence on the reaction C₃H₅ + H = C₃H₄ + H₂, and a recommended rate was found for this reaction. Sensitivity analysis of the initial rate of CH₃ production during pyrolysis indicated that for both iso-octane and n-heptane, reaction rates for the initial decomposition channels are well isolated, and overall values for these rates were obtained. The present concentration time-history data provide strong constraints on the reaction mechanisms of both iso-octane and n-heptane oxidation, and in conjunction with OH concentration time-histories and ignition delay times, recently measured in our laboratory, should provide a self-consistent set of kinetic targets for the validation and refinement of iso-octane and n-heptane reaction mechanisms.     

JP-10点火延时的激波管研究

在预加热激波管上测定了JP-10的点火延时时间．采用高精度真空仪直接测定注入激波管中JP-10蒸气压力，获得了JP-10气相浓度，解决了高碳数碳氢燃料点火延时激波管实验时管壁吸附影响燃料气相浓度确定的困难．采用压力传感器、单色仪和光电倍增管记录得到了完整的点火过程引起的压力变化和OH或CH自由基发射强度变化．自由基发射信号作为诊断点火发生的手段．当实验压力为151?556 kPa，温度为1000?2120 K，JP-10摩尔百分比为0.1%?0.55%，化学当量比为0.25、0.5、1.0、2.0时，获得了点火延时时间与实验温度、JP-10浓度、O2浓度的依赖关系，结果还表明，高温区和低温区呈现出不同的依赖关系．     

Linear theory of an electron cyclotron maser operating at the fundamental

The linear theory of an electron cyclotron maser (ECM) operating at the fundamental is developed. A set of analytic expressions, valid for all TE cavity modes, is derived for the starting current and frequency detuning using the Vlasov-Maxwell equations in the weakly relativistic limit. These results are applicable for an arbitrary electron velocity distribution as well as any longitudinal distribution of the RF field. It is shown that the starting current can be expressed in a simple form which contains the Fourier trans-form of the longitudinal field distribution. Analytic results are presented for specific longitudinal field variations, including uniform, sinusoidal, and Gaussian. It is found that the starting characteristics of an ECM are strongly influenced by the axial dependence of the RF field, but weakly affected by the velocity spread of the electron beam. The problem of multimode oscillation is treated in the linear theory by using a Slater expansion of the cavity field. The complete formulation for mode competition based on this expansion is presented and preliminary results are derived. This comprehensive analysis of ECM linear theory should be useful as a diagnostic of ECM performance and should facilitate comparison between theory and experiment.Work supported by U.S.D.O.E. Contract DE-AC-02-80ER52059Supported by U.S. Department of EnergySupported by National Science Foundation     

Laryngeal and pharyngeal behavior in countertenor and baritone singing—A videofiberscopic study

Changes in vocal tract configuration during singing were studied in four semiprofessional countertenors and one professional bass-baritone, by means of fiberoptic laryngoscopy. All of the countertenors showed a marked narrowing of the lower pharynx with increasing pitch when they used their countertenor voice (CT voice) but only a slight narrowing when using their baritone voice (B voice). The bass-baritone's pharynx remained unchanged with increasing pitch. Increasing loudness gave a widening of the pharynx in three of the four countertenors' CT voices, whereas no change was observed for the countertenors' B voices or for the bass-baritone voice. Vocal fold length seemed to decrease in one countertenor's B voice and in the bass-baritone with increasing loudness. Thus, the countertenors in this study exhibit several characteristic patterns of vocal tract gestures in countertenor voice that differ from both their own baritone voices and from the bass-baritone.