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51.
Optimal utilization of computational resources mandates spatio-temporal variation in resolution for computing complex engineering flows. Closure modeling in regions bridging between different resolutions is rendered difficult due to changing interactions between resolved and unresolved fields. We develop a closure model for the bridging region based on energy conservation principles. Then we proceed to provide a proof of concept in decaying isotropic turbulence with temporally varying resolution. The simplicity of the flow permits a thorough examination of various aspects of the proposed closure not feasible in more complex flows. The results demonstrate the potential promise of the approach, but more validation studies need to be performed.While the present development is in the context of partially averaged Navier–Stokes (PANS) method, the closure principle should apply for other variable-resolution (VR) approaches. 相似文献
52.
A general and efficient method for the synthesis of benzo-fused 7- and 8-membered ring lactams via the Beckmann rearrangement of cyclic oximes is presented. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file. 相似文献
53.
Rolf Appel Peter Schulte Falk Knoch 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):195-198
Abstract Two imino(bismethylene)phosphat-ions can be synthesized via reaction of phenylamino- and α-naphthylaminobismethylenephosphorane with n-butyllithium in tetrahydrofuran. Anions containing [sgrave]3λ6-bounded phosphorus are stabilized in the crystal with THF-solvated lithium-kations. Zwei Imino(bismethylen)phosphat-ionen werden durch Umsetzung des Phenylamino- und des α-Naphthylaminobismethylenphosphorans mit n-Butyllithium in Tetrahydrofuran erhalten. Die Anionen mit [sgrave]3λ6-gebundenem Phosphor werden im Kristall durch THF-solvatisierte Lithium-Kationen stabilisiert. 相似文献
54.
We study “large” nonnegative solutions for a class of quasilinear equations model of which is We give a sufficient condition on the exponents and for the removability of isolated singularities. 相似文献
55.
Synthesis of Schiff's bases in aqueous medium: a green alternative approach with effective mass yield and high reaction rates 总被引:1,自引:0,他引:1
《Green Chemistry Letters and Reviews》2013,6(3):217-223
Abstract Schiff's bases constitute a class of pharmaceutical and medicinally important molecules. The conventional methods for the synthesis of Schiff's bases require long reaction times and use of organic solvents. We report a novel and eco-friendly condensation reaction method permitting the “green synthesis” of various Schiff's bases by stirring 1,2-diaminobenzene with various aromatic aldehydes in water as solvent. This method is experimentally simple, clean, high yielding, green, and with reduced reaction times. The product is purified by simple filtration followed by washing with water and drying processes. 相似文献
56.
Katell Fiselier Florian Grundböck Karsten Schön Oliver Kappenstein Karla Pfaff Christoph Hutzler Andreas Luch Koni Grob 《Journal of chromatography. A》2013,1271(1):192-200
So far the majority of the measurements of mineral oil saturated hydrocarbons (MOSH) and mineral oil aromatic hydrocarbons (MOAH) were obtained from on-line high performance liquid chromatography–gas chromatography–flame ionization detection (on-line HPLC–GC–FID). Since this technique is not available in many laboratories, an alternative method with more easily available tools has been developed. Preseparation on a small conventional liquid chromatographic column was optimized to achieve robust separation between the MOSH and the MOAH, but also to keep out the wax esters from the MOAH fraction. This was achieved by mixing a small portion of silica gel with silver nitrate into highly activated silica gel and by adding toluene into the eluent for the MOAH. Toluene was also added to the MOSH fraction to facilitate reconcentration and to serve as a keeper preventing loss of volatiles during solvent evaporation. A 50 μl volume was injected on-column into GC–FID to achieve a detection limit for MOSH and MOAH below 1 mg/kg in most foods. 相似文献
57.
Aryl–heteroaryl and heteroaryl–heteroaryl compounds are obtained through the Suzuki–Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda–Heck reaction between several monoolefins with aryldiazonium salts. 相似文献
58.
An environmentally benign, three-component, one-pot integrated chemical process has been developed for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzoxanthene-11-one by nucleophilic addition reaction between aldehyde and β-naphthol followed by Michael addition of dimedone, catalyzed by thiamine hydrochloride in aqueous micellar medium with excellent yield. Simple reaction conditions, no requirement of chromatographic separation, short reaction time, ease of isolation, use of inexpensive, easily recoverable and reusable catalyst makes this protocol very interesting from an economic and environmental perspective. 相似文献
59.
The synthesis of 1H-indazoles from o-aminobenzoximes is achieved via N–N bond formation using triphenylphosphine, I2, and imidazole. Selective formation of oxime-phosphonium ion intermediate in the presence of the amino group is the driving force for this reaction. The nucleophilicity of the arylamino group and electrophilicity toward the N–O bond of oxime also control the reaction. The reaction proceeds at a faster rate with good to excellent yield under this mild reaction condition and is amenable to scale-up. 相似文献
60.
N-Sulfonyl imines have been synthesized in good to excellent yields from aldehydes and chloramine-T using proline as an organocatalyst in aqueous medium at ambient temperature. The protocol is applicable to a wide range of aldehydes, especially enals exhibit remarkable efficiency in the reaction. The reaction presumably occurs via iminium activation and opens new avenues for the synthesis of N-sulfonyl imines under environmentally benign and mild conditions. 相似文献