Electrochemical approaches to generation of phosphinidene complexes of tungsten pentacarbonyl

An alternative approach to synthesis of electrophilic terminal phosphinidene complexes of tungsten pentacarbonyl with various substituents at the phosphorus atom has been developed. The approach is based on the reaction of the electrochemically generated tungsten pentacarbonyl ion with trivalent phosphorus acyl chlorides. Electrochemical reduction of ethyldichlorophosphines in the presence of α-diimines is a one-step process that forms 1,3,2-diazaphospholenes containing an exocyclic P-C bond.     

手性(salen)Co配合物的合成及其在水解动力学拆分中的应用

综述了近几年来手性(salen) Co金属配合物的合成及其在水解动力学拆分末端环氧化合物中的应用。设计更合适的配体、发展可重复利用的催化剂、对催化剂及催化体系进行理论和模拟是当前乃至今后该领域研究工作的重点。     

典型卫星轨道辐射环境及在轨软错误率预计模型分析

使用最新版本的Space Radiation 7.0软件对典型卫星轨道（包括地球同步轨道、中地轨道和低地轨道）的空间辐射环境进行提取和计算,分析不同空间天气和屏蔽条件下的轨道离子通量-能量谱和通量-线性能量沉积（LET）谱特点。以一款SOI SRAM为例,结合地面加速器重离子试验获得的单粒子翻转截面-LET值关系曲线,预计该器件的在轨软错误率（SER）,并分析关键参数对预计结果的影响规律和内在机理。结果表明,使用Space Radiation软件的四种输入模式获得的预计结果可相差5倍左右;灵敏区厚度的增大导致在轨SER降低数个数量级,原因为灵敏区厚度的设置与灵敏区平均投影面积和符合条件的空间离子通量的大小直接相关;漏斗长度的大小对预计结果有一定的影响。最后,对SER预计模型的适用性和发展趋势进行了讨论。     

中子单粒子效应研究现状及进展

回顾了中子单粒子研究的国内外发展情况,介绍了近几年西北核技术研究所在西安脉冲堆开展的低能中子单粒子效应研究进展。比较了稳态与脉冲工况下中子单粒子效应的异同性;分析了含有SRAM结构器件随着特征尺寸的减小,中子单粒子效应敏感性加剧的物理机制。分析认为目前中子单粒子效应已成为小尺寸大规模互补金属氧化物半导体器件的主要中子效应表现;中子辐射效应研究中,除了位移损伤效应以外还必需重视由中子电离造成的中子单粒子效应。     

长期事件研究方法论——一个综述

本文对国外长期事件研究方法论文献进行了全面的梳理,并着重介绍和分析了期望收益模型(或收益基准)选择、异常收益度量,以及检验统计量的设定与检验力等。研究发现,在各期望收益模型、两种度量异常收益方法—AAR(或CAR)与BHAR的选择,以及各检验统计量是否存在错误设定等问题上,国外学界并未达成共识,争论仍在继续。     

概率论中一些易混淆的概念的教学探讨

从理论和实践相结合上对《概率论》课程中的一些概念教学进行了探究.     

静态单粒子翻转截面的获取及分类

为了评估静态随机访问存储器(SRAM)型现场可编程门阵列(FPGA)器件的单粒子效应,寻求单粒子翻转敏感部位,以XCV300PQ240为实验样品,利用重离子辐照装置详细测试了该器件的静态翻转截面,并根据配置存储单元用途的不同,对翻转数据进行了分类。结果表明：SRAM型FPGA的内部存储单元对单粒子翻转效应十分敏感;配置存储器翻转主要由查找表(LUT)及互连线资控制位造成,这两者的翻转占总翻转数的97.46%;配置存储器中各类资源的单粒子翻转(SEU)敏感性并不一致,输入输出端口(IOB)控制位和LUT的单粒子翻转的敏感性远高于其它几类资源,但LUT在配置存储器中占有很大比例,在加固时应予以重点考虑。     

An exclusive event generator for e~+ e~- scan experiments

An exclusive event generator is designed for e+e-scan experiments,including initial state radiation effects up to the second order correction.The generator is coded within the framework of BesEvtGen.There are seventy hadronic decay modes available,with effective center-of-mass energy coverage from the two pion mass threshold up to about 6 GeV.The accuracy achieved for the initial state radiation correction reaches the level achieved by the KKMC generator.The uncertainty associated with the calculation of the correction factor to the initial state radiation is dominated by the measurements of the energy-dependent Born cross section.     

A one‐pot method for synthesis of reduced graphene oxide‐supported Cu–Cu2O and catalytic application in tandem reaction of halides and sodium azide with terminal alkynes

Reduced graphene oxide (RGO)‐supported Cu–Cu₂O nanocomposite material (Cu‐Cu₂O@RGO) was prepared through a one‐pot reflux synthesis method. The morphology, crystal structure and composition of the prepared Cu‐Cu₂O@RGO were characterized using transmission electron microscopy, X‐ray diffraction, and X‐ray photoelectron, infrared and Raman spectroscopies. Cu‐Cu₂O@RGO as a heterogeneous catalyst was applied to tandem reactions of halides and sodium azide with terminal alkynes to synthesize effectively 1,4‐disubstituted 1,2,3‐triazoles. Moreover, the catalyst showed excellent recyclability performance with very little leaching of the metal. Compared with homogeneous catalysts, Cu‐Cu₂O@RGO as a green and efficient catalyst was recoverable, easy to separate and highly stable in the tandem method for the synthesis of 1,2,3‐triazole compounds.     

Synthesis and mesomorphic characterization of azoesters with a coumarin ring

We have synthesized a homologous series of azoesters consisting of a coumaryl moiety as the end group. Eleven derivatives of this series exhibit mesomorphism. The nematic mesophase is exhibited from ethyl homologue onward, while the smectic phase commences at the pentyl derivative and is exhibited along with the nematic phase up to the hexadecyl derivative. The N-I transition temperatures curves show the usual odd-even effect. All the compounds in this series are thermally stable and exhibit a wide mesomorphic range of nearly 120°C. Their thermal stabilities and other characteristics are discussed.