全文获取类型
收费全文 | 3061篇 |
免费 | 333篇 |
国内免费 | 274篇 |
专业分类
化学 | 844篇 |
晶体学 | 21篇 |
力学 | 293篇 |
综合类 | 37篇 |
数学 | 1317篇 |
物理学 | 1156篇 |
出版年
2024年 | 7篇 |
2023年 | 46篇 |
2022年 | 58篇 |
2021年 | 82篇 |
2020年 | 104篇 |
2019年 | 130篇 |
2018年 | 99篇 |
2017年 | 109篇 |
2016年 | 92篇 |
2015年 | 95篇 |
2014年 | 159篇 |
2013年 | 304篇 |
2012年 | 167篇 |
2011年 | 137篇 |
2010年 | 138篇 |
2009年 | 167篇 |
2008年 | 182篇 |
2007年 | 161篇 |
2006年 | 164篇 |
2005年 | 135篇 |
2004年 | 164篇 |
2003年 | 134篇 |
2002年 | 108篇 |
2001年 | 91篇 |
2000年 | 87篇 |
1999年 | 92篇 |
1998年 | 77篇 |
1997年 | 51篇 |
1996年 | 49篇 |
1995年 | 38篇 |
1994年 | 38篇 |
1993年 | 24篇 |
1992年 | 26篇 |
1991年 | 22篇 |
1990年 | 12篇 |
1989年 | 15篇 |
1988年 | 10篇 |
1987年 | 15篇 |
1986年 | 11篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 7篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1975年 | 5篇 |
1974年 | 4篇 |
排序方式: 共有3668条查询结果,搜索用时 15 毫秒
61.
In this paper, the nanosecond transient absorption spectra and the fluorescence spectraof Hypocrellin A(HA) are examined in solvents of varying polarity. There are three absorp-tion bands in dilute HA solutions: Ⅰa, Ⅱa are defined as the triplet-triplet absorption ofHA, the band Ⅲa is supposed to be the absorption of the solvent--sepatated ion pair (SSIP).In more concentrated solutions, only the absorption of SSIP was observed. The effects ofsolvent polarity on transient absorption spectra and fluorescence spectra of HA and the effectof oxygen on the intensities of the fluorescence of HA are discussed. Then a reasonablemechanism for the photolysis of HA is proposed. 相似文献
62.
原子发射光谱法间接测定黄连素片剂中盐酸小檗碱的研究 总被引:1,自引:0,他引:1
本文提出了离子对-原子发射光谱间接测定黄连素片剂中盐酸小檗碱的新方法。发现用1,2-二氯乙烷作萃取剂效果最佳。用此怯测定实际样品的结果与药典法一致,相对误差为0.61%,单一测定的相对标准偏差为0.67%。本法还可在盐酸普鲁卡因共存下单独测定盐酸小檗碱。方法可靠、适用,选择性较好。 相似文献
63.
The apparent molal volume and adiabatic compressibilities of some transition metal (Mn2+, Co2+ Ni2+, Cu2+, Zn2+, and Cd2+) sulfates have been determined at 25°C. Values of
to 11.4 cm3-mole–1 and
to 31.3 × 10–4cm3-mole–1-bar–1 at 1 atm were found for the formation of the transition metal sulfate ion pairs. These results are in good agreement with the values obtained from the high-pressure conductance measurements of Fisher et al., Shimizu et al., and Taniguchi et al. The volume and compressibility data indicate that 3.1±0.7 water molecules are lost when transition metals form ion pairs with SO
4
2–
. The fractions of inner-sphere ion pairs (20%) estimated in this study are in good agreement with the values obtained from ultrasonic measurements. 相似文献
64.
A multireference configurational interaction method based on the separated electron pair (SEP) wave functions, SEP‐CI approach, has been developed as an approximation to the traditional CASSCF method. It differs from the CASSCF method in that active orbitals are obtained from the SEP wave function without further optimization in the subsequent CI calculations, and the active space is automatically constructed according to the occupation coefficients of SEP natural orbitals. These features make the present SEP‐CI method computationally much less demanding than the CASSCF method. The applicability of the SEP‐CI method is illustrated with sample calculations on the insertion reaction of BeH2 and dissociation energies of LiH, BH, FH, H2O, and N2. © 2005 Wiley Periodicals, Inc. J Comput Chem 27: 39–47, 2006 相似文献
65.
66.
67.
V. R. Kartashov T. N. Sokolova O. A. Leksina A. B. Radbil N. V. Malisova Yu. K. Grishin 《Russian Chemical Bulletin》1995,44(3):527-531
The reaction of Hg(OAc)2 with bornylene in THF-H2O and CH3CN-H2O mixed solvents (75 25, v/v) was studied. The effects of the addition of NaOAc on the reaction rate and the composition of products were investigated. In the CH3CN-H2O mixture, the addition of NaOAc decreases the amount of the rearranged product, fundamentally changes the ratio between the regioisomeric solvoadducts, and promotes the formation of products of Hg(OAc)2 addition. The reaction proceedsvia an ion pair and free mercurinium ion; the cation of the ion pair and the free mercurinium ion have dissimilar structures.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 544–548, March, 1995. 相似文献
68.
J. A. Yan 《Applied Mathematics and Optimization》1995,31(2):137-153
Some sharp results about Weiner and Wick products of whitenoise functionals are obtained. Using the inequality of Wick products we show to what extent scaling transformations, translations, and Sobolev differentiations can be performed on white-noise functionals.This work was supported by the National Natural Science Foundation of China. This paper is an enlargement and revised version of the paper entitled Products and Transforms of White-Noise Functionals (preprint, 1990). 相似文献
69.
N. I. Golovina R. F. Trofimova L. O. Atovmyan A. G. Korepin P. V. Galkin G. V. Lagodzinskaya M. V. Loginova L. T. Eremenko 《Russian Chemical Bulletin》1994,43(3):398-401
The reaction of -fluorosubstituted polynitroalkylaldimines with HCl results in replacement of the fluorine atom by a chlorine atom. The hitherto unknown -chlorosubstituted polynitroalkylaldimines have been obtained, and their X-ray structural investigation has been performed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 440–443, March, 1994. 相似文献
70.
No modern theory of polymer excluded volume adequately describes the crossover from poor solvent to good solvent conditions; a fundamental difficulty is a singularity in the binary cluster integral. Mayer expansion techniques are applied to a model with a pair interaction between monomers to clarify the distinction between geometric and solvent contributions to excluded volume. Detailed calculations are undertaken for a hard-core potential and a mimic Lennard-Jones potential. The significance of the singularity in the binary cluster integral for calculations in the crossover regime is discussed. 相似文献