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991.
Musenga A Saracino MA Spinelli D Rizzato E Boncompagni G Kenndler E Raggi MA 《Analytica chimica acta》2008,612(2):204-211
Two methods, based on the use of capillary electrophoresis (CE) and high-performance liquid chromatography (HPLC), respectively, were developed for the analysis of the atypical antipsychotic aripiprazole in plasma of schizophrenic patients for therapeutic drug monitoring purposes. Good analytical performances were obtained with the CE method, using uncoated fused silica capillaries and a background electrolyte composed of 50 mM phosphate buffer at pH 2.5. With 20 kV voltage, aripiprazole was detectable at 214 nm within 5 min. The second analytical method, based on HPLC with diode array detection, employed a C8 reversed-phase column and a mixture of a 12.5 mM phosphate buffer, pH 3.5, containing triethylamine and acetonitrile as the mobile phase. Aripiprazole was detected at 254 nm and a complete chromatographic run lasted about 10 min. For both analytical methods loxapine was used as the internal standard and the same plasma sample pre-treatment by means of solid-phase extraction on cyano cartridges was carried out, with extraction yield values always higher than 91.3%. Linear responses for aripiprazole were obtained between 70 and 700 ng mL−1 and precision assays (expressed as relative standard deviation values) were lower than 7.0%. After validation, both methods were successfully applied to human plasma samples drawn from schizophrenic patients undergoing therapy with Abilify® tablets. Accuracy was satisfactory, with recovery value higher than 91.0%. 相似文献
992.
More and more attention is being focused on the analysis of post-translational modifications (PTMs) on proteins as researchers are continually learning how essential they are for proper cellular function. As there are hundreds of different types of known PTMs, traditional methods of modification analysis are incapable of comprehensively monitoring for post-translational modifications, a task which is a necessity for truly understanding a cell's biology. This review highlights recent developments in novel multiplexed methods of PTM analysis including: fluorescent stain and immuno-based methods, hardware-based mass spectrometric methods and computational-based mass spectrometric methods. Many of these techniques show great promise and will likely be a valuable resource for the biological community. 相似文献
993.
Laure F Raharivelomanana P Butaud JF Bianchini JP Gaydou EM 《Analytica chimica acta》2008,624(1):147-153
Various pyranocoumarins, calophyllolide, inophyllums B, C, G1, G2 and P, from Calophyllum inophyllum (Clusiaceae) leaves of French Polynesia (Austral, Marquesas, Society and Tuamotu archipelagos) have been determined in 136 leaf extracts using a high pressure liquid chromatography-UV-diode array detection (HPLC-UV-DAD) technique. Results show a wide range in chemical composition within trees growing on eighteen islands. The use of multivariate statistical analyses (PCA) shows geographical distribution of inophyllums and indicate those rich in HIV-1 active (+)-inophyllums. Inophyllum B and P contents (0.0-39.0 and 0.0-21.8 mg kg−1, respectively) confirm the chemodiversity of this species within the large area of French Polynesia. The study suggests the presence of interesting chemotypes which could be used as plant source for anti-HIV-1 drugs. 相似文献
994.
为了解决普通AM参量阵产生的解调信号质量差、效率低等问题,设计了一个动态载波AM算法。以此算法为基础设计了一个DSP处理平台,并在此平台上实现了参量阵系统。经过系统硬件和软件两方面的优化设计,保证了算法运行的实时性和稳定性。最后,使用500Hz、800Hz和1100Hz的合成波作为测试信号,测试了系统输出的波形和参量阵前方5米处的频谱。对比测得的波形和理论波形,验证了此系统能够可靠地运行。对比普通AM和动态载波AM参量阵输出信号的频谱图,验证了动态载波AM参量阵能输出更好信噪比和能量更高的解调信号。 相似文献
995.
《强激光与粒子束》2016,(5):71-77
Based on principle of power synthesis of sparse array, mathematical model of spatial power combining is established. Relation between cross angle of beams and synthesis efficiency on aimed point from two antenna nodes is derived. Furthermore, the setting principle of sampling interval is analyzed for simulation experiment. Energy distributions of the useful points under different cross angles were simulated. Simulation shows that if distance between the antenna nodes and aimed point are equal, and frequency, polarization and an- tenna type are the same, synthesis efficiency relies on the cross angles of beams, shape and density on the useful points accumulation area also rely on the cross angles of beams. 相似文献
996.
为了提高大靶面交汇测量系统的测量准确度,分析了交汇测量原理,推导出脱靶量坐标公式.根据脱靶量公式分析其各项参量,利用几何关系建立像元坐标与偏移角度之间的映射模型.根据映射模型,利用光栅尺设计了一种针对线阵相机的标定方法,该方法不考虑相机参量,将整个光学系统看作一个整体,基于整体参量直接对像元坐标和它所对应的偏移角进行标定.实验结果表明,标定后的交汇测量系统在1.4m处的平均测量误差为0.4mm,最大测量误差优于0.6mm.该方法简单高效,可提高系统标定的速度,且标定误差满足系统交汇测量准确度的要求. 相似文献
997.
Vortex identification techniques are used to analyse the wake of a 4 × 3 array of model wind turbines. The Q-criterion, Δ-criterion, and λ2-criterion are applied to particle image velocimetry data gathered fore and aft of the last row centerline turbine. The Q-criterion and λ2-criterion provide a clear indication of regions where vortical activity exists, while the Δ-criterion is not successful. Galilean decomposition, Reynolds decomposition, vorticity, and swirling strength are used to further understand the location and behaviour of the vortices. The techniques identify and display the high-magnitude vortices in high-shear zones resulting from the blade tips. Using Galilean and Reynolds decomposition, swirling motions are shown encapsuling vortex regions in agreement with the identification criteria. The Galilean decompositions selected are 20% and 50% of a convective velocity of 7 m/s. As the vortices convect downstream, the strength of the vortices decreases in magnitude, particularly in the far wake of the array, to approximately 25% of those present in the near wake. A high level of vortex activity is visualised as a result of the top tip of the wind turbine blade -- the location where the highest vertical entrainment is present. Analysing the full frame set, the Q-criterion, λ2-criterion, and swirling strength prove comparable, while the Δ-criterion under-performs in regions of high turbulence activity, namely in the back of the turbine. Entraining flow into the turbine canopy interacting with the turbine generates high-magnitude vortices concentrated at the blade tips. The count of vortices decreases when moving from the top tip down to the wall, as well as their strength for each Galilean technique when a non-zero threshold is applied. Vortex sizes in the near wake are found comparable to turbine blade, hub, and mast dimensions. In the far wake, the resulting size of the vortices is approximately 30% of those in the near wake. These vortices increase in velocity as they convect downstream, following the mean velocity behaviour. The lowest magnitude vortices reside at the hub height in the near-wake region, where they convect at nearly half the speed of those at the blade tips. 相似文献
998.
999.
针对水下低频声源的方位估计问题,基于基元紧密排列的二维矢量阵,建立了一种超指向性波束形成方法.根据矢量基元差分运算构建各阶多极子模型,获得了几乎与频率无关的模态函数,并经加权计算可在低频条件下实现超指向性波束,以解决阵列孔径对波束性能的限制.同时,结合输出信噪比最大准则所得波束,分析了超指向性波束形成算法的稳定性与波导的影响程度,探索模态阶数与阵列参数的选取原则.通过阵列性能的仿真计算与实际阵列的测量数据表明,该算法可在小尺寸阵列孔径下获得良好的阵列波束,兼具了水下线型超指向性阵和环形超指向性阵的优点,可有效实现水下低频声源的水平方位估计;且波束性能可通过调节模态阶数与基元间距以达到最佳,并受水下声波导多途与频散效应影响有限. 相似文献
1000.
通过有效控制合成液配比,合成出了形貌规则、结晶度高且具有不同长径比的LTL型分子筛晶粒。采用"瓶中造船法",在不同长径比的LTL型分子筛晶粒孔道中组装稀土有机配合物,制得LTL分子筛/Eu-TTA主-客体荧光材料。荧光光谱表征结果表明,在激发波长为350 nm时,长径比为0.2的LTL分子筛/Eu-TTA晶粒在617 nm处的5D0→7F2发光强度最大,而长径比为3的晶粒发光强度最小。最后,将长径比为0.2的LTL分子筛/Eu-TTA晶粒在PEI修饰的玻璃表面快速擦涂10 s后,就制得厘米尺寸的一维取向LTL型分子筛荧光阵列。SEM表征结果证实,该分子筛荧光阵列中几乎所有的LTL分子筛晶粒都沿着与底基表面垂直的c轴方向一维高密度、单层有序排列。在激发波长为365 nm时,该一维取向LTL分子筛荧光阵列发出鲜艳的红色荧光。 相似文献