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We have investigated the convergence of third order correlation energy within the hierarchies of correlation consistent basis sets for helium, neon, and water, and for three stationary points of hydrogen peroxide. This analysis confirms that singlet pair energies converge much slower than triplet pair energies. In addition, singlet pair energies with (aug)-cc-pVDZ and (aug)-cc-pVTZ basis sets do not follow a converging trend and energies with three basis sets larger than aug-cc-pVTZ are generally required for reliable extrapolations of third order correlation energies, making so the explicitly correlated R12 calculations preferable. 相似文献
945.
Igal Sason 《Entropy (Basel, Switzerland)》2021,23(3)
This paper studies the problem of upper bounding the number of independent sets in a graph, expressed in terms of its degree distribution. For bipartite regular graphs, Kahn (2001) established a tight upper bound using an information-theoretic approach, and he also conjectured an upper bound for general graphs. His conjectured bound was recently proved by Sah et al. (2019), using different techniques not involving information theory. The main contribution of this work is the extension of Kahn’s information-theoretic proof technique to handle irregular bipartite graphs. In particular, when the bipartite graph is regular on one side, but may be irregular on the other, the extended entropy-based proof technique yields the same bound as was conjectured by Kahn (2001) and proved by Sah et al. (2019). 相似文献
946.
Life is an epiphenomenon for which origins are of tremendous interest to explain. We provide a framework for doing so based on the thermodynamic concept of work cycles. These cycles can create their own closure events, and thereby provide a mechanism for engendering novelty. We note that three significant such events led to life as we know it on Earth: (1) the advent of collective autocatalytic sets (CASs) of small molecules; (2) the advent of CASs of reproducing informational polymers; and (3) the advent of CASs of polymerase replicases. Each step could occur only when the boundary conditions of the system fostered constraints that fundamentally changed the phase space. With the realization that these successive events are required for innovative forms of life, we may now be able to focus more clearly on the question of life’s abundance in the universe. 相似文献
947.
D. E. Ferreyra 《Numerical Functional Analysis & Optimization》2017,38(6):770-798
We study the behavior of the best simultaneous approximation to two functions from a convex set in Lp spaces, 2<p<∞, on a finite union of intervals when its measure tends to zero. In particular, we give su?cient conditions over the differentiability of two functions to assure existence of the best simultaneous local approximation from the class of algebraic polynomials of a fixed degree. These conditions are weaker than the ordinary differentiability given in previous works. More precisely, we consider differentiable functions in the sense Lp. 相似文献
948.
Observability from measurable sets for a parabolic equation involving the Grushin operator and applications
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In this work, we utilize the existing Carleman estimates and propagation estimates of smallness from measurable sets for real analytic functions, together with the telescoping series method, to establish an observability inequality from measurable subsets in time‐space variable for the parabolic equation with Grushin operator in some multidimension domains. We can apply this observability inequality to show the bang–bang property for both time optimal and norm optimal control problems for this kind of singular parabolic equation. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
949.
We show quantitative versions of classical results in discrete geometry, where the size of a convex set is determined by some non-negative function. We give versions of this kind for the selection theorem of Bárány, the existence of weak epsilon-nets for convex sets and the theorem of Alon and Kleitman. These methods can be applied to functions such as the volume, surface area or number of points of a discrete set. We also give general quantitative versions of the colorful Helly theorem for continuous functions. 相似文献
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