全文获取类型
收费全文 | 10961篇 |
免费 | 1158篇 |
国内免费 | 702篇 |
专业分类
化学 | 3559篇 |
晶体学 | 1166篇 |
力学 | 984篇 |
综合类 | 154篇 |
数学 | 4241篇 |
物理学 | 2717篇 |
出版年
2024年 | 20篇 |
2023年 | 122篇 |
2022年 | 217篇 |
2021年 | 258篇 |
2020年 | 308篇 |
2019年 | 273篇 |
2018年 | 236篇 |
2017年 | 298篇 |
2016年 | 410篇 |
2015年 | 331篇 |
2014年 | 518篇 |
2013年 | 903篇 |
2012年 | 575篇 |
2011年 | 699篇 |
2010年 | 612篇 |
2009年 | 703篇 |
2008年 | 750篇 |
2007年 | 749篇 |
2006年 | 672篇 |
2005年 | 557篇 |
2004年 | 525篇 |
2003年 | 406篇 |
2002年 | 319篇 |
2001年 | 270篇 |
2000年 | 300篇 |
1999年 | 239篇 |
1998年 | 222篇 |
1997年 | 227篇 |
1996年 | 147篇 |
1995年 | 116篇 |
1994年 | 121篇 |
1993年 | 82篇 |
1992年 | 91篇 |
1991年 | 76篇 |
1990年 | 63篇 |
1989年 | 56篇 |
1988年 | 42篇 |
1987年 | 40篇 |
1986年 | 36篇 |
1985年 | 28篇 |
1984年 | 33篇 |
1983年 | 22篇 |
1982年 | 18篇 |
1981年 | 24篇 |
1980年 | 20篇 |
1979年 | 21篇 |
1978年 | 17篇 |
1977年 | 13篇 |
1976年 | 14篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Mild and effective pretreatments are essential to deconstruct lignocellulosic biomass so as to reuse cellulose content for value-added products. In this study, sequential multimode-ultrasound and microwave with natural ternary deep eutectic solvent (NATDES) pretreatments were used to deconstruct corn straw and optimized factors such as NATDES, ultrasonic, and microwave parameters. Results indicated that the ultrasound-NATDES or microwave-NATDES pretreatment could remove 37.86% and 52.36% lignin, respectively. When using sequential multimode-ultrasound and microwave assisted NATDES pretreatment, the delignification efficiency increased to 61.50%, and the cellulose content increased from 34.70% to 76.08%. In addition, the delignification of sequential multimode-ultrasound and microwave assisted NATDES pretreatment (under the mild conditions of microwave heating at 60 °C and 60 min) increased to 57.39%, and the cellulose content increased to 59.98%, too. This highlighted the effect of the combined ultrasound and microwave technology. Finally, the microstructural changes of mercury intrusion porosimeters, scanning electron microscopy, thermogravimetric, X-ray diffraction and Fourier transform mid-infrared spectroscopy were conducted to confirm the effectiveness of this method to deconstruct corn straw. A mechanism of the deconstruction of corn straw biomass in NATDES with the assistance of the sequential multimode-ultrasound and microwave heating was proposed. This research could open a window for future use of biomass energy by deconstructing lignocellulosic biomasses using environmentally friendly pretreatment methods. 相似文献
82.
A mean-field type model with random growth and reset terms is considered. The stationary distributions resulting from the corresponding master equation are relatively easy to obtain; however, for practical applications one also needs to know the convergence to stationarity. The present work contributes to this direction, studying the transient dynamics in the discrete version of the model by two different approaches. The first method is based on mathematical induction by the recursive integration of the coupled differential equations for the discrete states. The second method transforms the coupled ordinary differential equation system into a partial differential equation for the generating function. We derive analytical results for some important, practically interesting cases and discuss the obtained results for the transient dynamics. 相似文献
83.
Jin-Zi Ding 《中国物理 B》2021,30(12):126201-126201
Flower-like tungsten disulfide (WS2) with a diameter of 5-10 μm is prepared by chemical vapor deposition (CVD). Scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), Raman spectroscopy, and ultraviolet-visible (UV-vis) spectroscopy are used to characterize its morphological and optical properties, and its growth mechanism is discussed. The key factors for the formation of flower-like WS2 are determined. Firstly, the cooling process causes the generation of nucleation dislocations, and then the "leaf" growth of flower-like WS2 is achieved by increasing the temperature. 相似文献
84.
合成了一系列以两个亚甲基为联接基的杂双子咪唑表面活性剂([Cm-2-Cnim]Br2, m, n=8, 10, 12, 14, 16; m≠n). 用氢谱和质谱对其结构进行了表征. 探索了物料比、反应温度和时间对反应产率的影响. 对合成的杂双子咪唑表面活性剂的表面活性进行了研究,讨论了分子结构的不对称程度对表面活性的影响. 相似文献
85.
低速生长条件下, 共晶“层片↔棒状”转变只由两相的体积分数控制. 高速情况下, 这种转变有时亦发生, 其转变机理不清楚. 本文应用竞争生长准则, 结合高速生长条件下层片共晶和棒状共晶生长模型研究了生长速度引起的“层片↔棒状”转变机理. 结果显示: 体积分数在临界值附近很小的范围内, 生长速度和溶质配分系数的增大可引起“棒状→ 层片”共晶转变; 而当体积分数远离临界值时, 转变不发生. 生长速度名义上引起“层片↔棒状”共晶转变实际上是由生长速度变化引起的体积分数的变化导致的.
关键词:
“层片↔棒状”共晶转变
竞争生长
生长速度
体积分数 相似文献
86.
Ken Taguchi Akihiko Toda Yoshihisa Miyamoto 《Journal of Macromolecular Science: Physics》2013,52(6):1149-1157
Crystallization of isotactic polystyrene (it‐PS) from dilute solution at high supercooling has been investigated by dynamic light scattering (DLS). We successfully obtained simultaneously, in situ in solutions, the time developments of both random coils of it‐PS molecules and the growing crystals. The size of coils remains constant during growth, while the crystals pass through two stages, that is, an induction period at the early stage with very slow growth rates and a subsequent linear growth stage. It is confirmed that the temperature dependence of the linear growth rates, determined by DLS, agree well with that determined by electron microscopy. The temperature dependences of the growth rate and the inverse of induction time are dependent on the viscosity of solvent, which indicates that all dynamics are dominated by the segmental motion of polymer chains in solution at high supercoolings (low temperatures). Two possibilities are proposed for the induction period. 相似文献
87.
J. Dyckmans H. Flessa Z. Shangguan F. Beese 《Isotopes in environmental and health studies》2013,49(1):63-78
Abstract A continuous dual 13CO2 and 15NH4 15NO3 labelling experimental set-up is presented that was used to investigate the C and N uptake and allocation within 3-year old beech (Fagus sylvatica L.) during one growing season. The C and N allocation pattern was determined after six, twelve and eighteen weeks of growth. The carbon uptake was distinctly different in the three phases examined: The first six weeks after budbreak were dedicated to leaf growth with a R/S (root to shoot) ratio of 0.14 for the new carbon. The second growth phase showed a balanced R/S ratio of C allocation and after week 13, the root compartment was the main carbon sink (R/S = 6.97). Nitrogen allocation was more basipetal as compared to carbon. In the second growth phase, R/S of Nnew was 5.57 but fell to 3.54 for the third growth phase probably due to formation of reserves in buds and stem. 相似文献
88.
H.-D. Knöfel 《Isotopes in environmental and health studies》2013,49(8):316-320
In vorliegender Arbeit wird eine kurze Darstellung der Grundlagen, Erfordernisse, Vor- und Nachteile des Radioimmunoassay für Pflanzenhormone gegeben. The purpose of this paper is to discuss briefly the basis, requirements, advantages, and disadvantages of radioimmunoassay with respect to plant hormones. 相似文献
89.
Crack propagation on the basal planes in zinc was examined by means of in situ fracture testing of pre-cracked single crystals, with specific attention paid to the fracture mechanism. During quasistatic loading, crack propagation occurred in short bursts of dynamic crack extension followed by periods of arrests, the latter accompanied by plastic deformation and blunting of the crack-tip. In situ observations confirmed nucleation and propagation of microcracks on parallel basal planes and plastic deformation and failure of the linking ligaments. Pre-existing twins in the crack path serve as potent crack arrestors. The crystallographic orientation of the crack growth direction on the basal plane was found to influence both the fracture load as well as the deformation at the crack-tip, producing fracture surfaces of noticeably different appearances. Finite element analysis incorporating crystal plasticity was used to identify dominant slip systems and the stress distribution around the crack-tip in plane stress and plane strain. The computational results are helpful in rationalizing the experimental observations including the mechanism of crack propagation, the orientation dependence of crack-tip plasticity and the fracture surface morphology. 相似文献
90.
With decreasing grain size, grain boundary junctions become increasingly important for microstructure evolution. We show that the effect of a limited mobility of triple junctions on the growth rate of polycrystals can be implemented in theories of three-dimensional (3D) grain growth. Respective analytical relations are derived on the basis of the average n-hedra approach introduced by Glicksman to describe the volume rate of change of 3D grains in a polycrystalline aggregate under the impact of a limited triple junction mobility. The theoretical predictions were compared to network-model computer simulations, and good agreement was obtained. 相似文献