全文获取类型
收费全文 | 6813篇 |
免费 | 650篇 |
国内免费 | 689篇 |
专业分类
化学 | 2693篇 |
晶体学 | 71篇 |
力学 | 252篇 |
综合类 | 42篇 |
数学 | 2334篇 |
物理学 | 2760篇 |
出版年
2024年 | 20篇 |
2023年 | 68篇 |
2022年 | 197篇 |
2021年 | 228篇 |
2020年 | 293篇 |
2019年 | 223篇 |
2018年 | 205篇 |
2017年 | 148篇 |
2016年 | 219篇 |
2015年 | 202篇 |
2014年 | 271篇 |
2013年 | 574篇 |
2012年 | 304篇 |
2011年 | 338篇 |
2010年 | 267篇 |
2009年 | 409篇 |
2008年 | 414篇 |
2007年 | 444篇 |
2006年 | 384篇 |
2005年 | 270篇 |
2004年 | 240篇 |
2003年 | 233篇 |
2002年 | 274篇 |
2001年 | 227篇 |
2000年 | 237篇 |
1999年 | 194篇 |
1998年 | 194篇 |
1997年 | 100篇 |
1996年 | 86篇 |
1995年 | 85篇 |
1994年 | 80篇 |
1993年 | 57篇 |
1992年 | 60篇 |
1991年 | 54篇 |
1990年 | 53篇 |
1989年 | 49篇 |
1988年 | 35篇 |
1987年 | 59篇 |
1986年 | 33篇 |
1985年 | 61篇 |
1984年 | 42篇 |
1983年 | 26篇 |
1982年 | 41篇 |
1981年 | 12篇 |
1980年 | 20篇 |
1979年 | 25篇 |
1978年 | 15篇 |
1977年 | 22篇 |
1976年 | 18篇 |
1974年 | 11篇 |
排序方式: 共有8152条查询结果,搜索用时 15 毫秒
101.
Mg-based hydrogen storage alloys Mg0.9Ti0.1-xZrxNi (x=0.02, 0.04, 0.06) were successfully prepared by means of mechanical alloying (MA). The effects of Zr addition on the discharge capacity and the cycle performance of the Mg-based electrodes were also studied. It was found that the discharge capacities were improved with addition of a small amount of Zr and the cycle performances of the alloy were stabilized with the addition of Ti. The effects of surface modification or coating on the properties of Mg0.9Ti0.06Zr0.04Ni were also studied. The results indicated that coating with graphite improved both the discharge capacity and cycle life of the amorphous Mg0.9Ti0.06Zr0.04Ni electrode. 相似文献
102.
Huifang Xu Wei Wei Chengliang Zhang Shujiang Ding Xiaozhong Qu Dr. Jiguang Liu Dr. Yunfeng Lu Prof. Zhenzhong Yang Prof. 《化学:亚洲杂志》2007,2(7):828-836
This report presents a facile approach for the low‐temperature synthesis of crystalline inorganic‐oxide composite hollow spheres by employing the bulk controlled synthesis of inorganic‐oxide nanocrystals with polymer spheres as templates. The sulfonated polystyrene gel layer can adsorb the target precursor and induce inorganic nanocrystals to grow on the template in situ. The crystalline phase and morphology of the composite shell is tunable. By simply adjusting the acidity of the titania sol, crystalline titania composite hollow spheres with tunable crystalline phases of anatase, rutile, or a mixture of both were achieved. The approach is general and has been extended to synthesize the representative perovskite oxide (barium and strontium titanate) composite hollow spheres. The traditional thermal treatment for crystallite transformation is not required, thus intact shells can be guaranteed. The combination of oxide properties such as high refractive index, high dielectric constant, and catalytic ability with the cavity of the hollow spheres is promising for applications such as opacifiers, photonic crystals, high‐κ‐gate dielectrics, and photocatalysis. 相似文献
103.
The main principles of solid-phase extraction techniques are reviewed in this paper. Various solid sorbents can be used as a suitable trap for direct accumulation of organic compounds from aqueous solutions. The trapped analytes can be desorbed by elution with suitably chosen liquid phases. These preconcentration procedures can be considered as low performance liquid chromatography and the efficiency of the procedure can thus be related to the retention characteristics of the preconcentration column. The main sorbents used for trace enrichment purposes are also reviewed. Besides, the concise methodology, sample storage, and automation are discussed. The advantages of solid phase extraction as compared to liquid-liquid extraction are given as well as some drawbacks of this method. 相似文献
104.
Traditionally, the application of supercritical fluid chromatography has been limited to compounds of relatively low polarity.
Thus, we report here that one secondary amine and two quaternary amine salts were successfully eluted from a Deltabond Cyano-bonded
silica column with the addition of sodium alkylsulfonate to the methanol-modified, carbon dioxide-based mobile phase. A possible
ion-pairing interaction between the positively charged analytes and the anionic part of the sulfonate additive has been proposed.
In another set of experiments, the three amine salts readily eluted from both Ethyl-pyridine-bonded silica and Amino-bonded
silica phases without the need of additive although the peak shapes were less than desirable. The addition of sulfonate salt
to the mobile phase again sharpened the peaks. In the presence of a mixture of methanol and CO2, we suggest that these stationary phases are positively charged. We describe here also for the first time the employment
of a strong silica-based anion exchange (SAX) column for supercritical fluid separation of cationic species. Two elution mechanisms
were proposed for the three amine salts depending upon whether the ionic additive was incorporated into the mobile phase.
Separation as the ion-pair was proposed with an ionic additive in the mobile phase; whereas separation of the intact amine
salt from the positively charged basic stationary phases was suggested to be operational without the ionic additive. 相似文献
105.
106.
Preparation and Characterization of Microencapsulated Hexadecane Used for Thermal Energy Storage 总被引:3,自引:0,他引:3
GuangLongZOU ZhiChengTAN XiaoZhengLAN LiXianSUN TaoZHANG 《中国化学快报》2004,15(6):729-732
Polyurea microcapsules about 2.5μm in diameter containing phase change material for thermal energy storage application were synthesized and characterized by interfacial polycondensation method with toluene-2,4-diisocyanate and ethylenediamine as monomers in an emulsion system. Hexadecane was used as a phase change material and OP, which is nonionic surfactant, and used as an emulsifier. The chemical structure and thermal behavior of the microcapsules were investigated by FTIR and thermal analysis respectively. The results show encapsulated hexadecane has a good potential as a solar energy storage material. 相似文献
107.
The adsorption equilibrium of water on microporous adsorbents (zeolites of NaA-, NaY- and NaX-type as well as their ion exchanged
forms) and on mesoporous adsorbents (different silica gels and composite material i.e. silica gel + salt hydrate) has been
studied experimentally and theoretically. Using the Dubinin theory of pore filling the characteristic curves of the adsorption
systems and other relevant dependences such as isotherms, isobars, isosteres and the curve of the differential heat of adsorption
were calculated. For all systems investigated the adsorption were calculated. Aads and the desorption potential Ades of the closed heat storage system were estimated. These values define the working range of the adsorption/desorption cycle
and allow to calculate the specific heat storage density Δ hsp. On the basis of Δ hsp the different adsorbents were compared in order to select the optimal porous storage material for a given application.
The presented experimental and theoretical investigations show that the adsorption systems water-zeolite and water-composites
are promising working pairs for thermochemical heat storage processes for hot tap water supply and space heating of single
family dwellings. The advantage of the water-composite system is the low desorption temperature (solar energy) the main shortcoming
the low temperature lift. The advantage of the water zeolite system is the high temperature lift, the shortcoming are the
relative high desorption temperatures. 相似文献
108.
The detection of oxygen in magneto-optical layers is of fundamental importance for the characterization of the stability of RE-TM material. The magnetic properties are directly influenced by oxide formation. Oxygen depth profiles are carried out by using the SIMS technique. A comparison with magnetic measurements showed a clear conformity. We were able to study the oxidation behaviour of various layers at room temperature and at higher values up to 250° C for several hours. It could be shown that aluminum is a successful material for the protection of RE-films against oxidation. The difficulties of translating SIMS counting rates into concentration values were overcome by using EPMA. Specially prepared reference samples were measured by this technique and could then be used as standard samples for SIMS. 相似文献
109.
Yu. A. Titov N. S. Slobodyanik Ya. A. Kraevskaya N. N. Belyavina V. Ya. Markiv 《Theoretical and Experimental Chemistry》2007,43(6):380-384
The synthesis of three-layered titanates BaLn2Ti3O10 (Ln = La, Nd, Sm) in systems with coprecipitated hydroxocarbonates was studied. It was established that they are formed through
an intermediate phase with a defective perovskite structure followed by its transformation into the three-layered structure
by the ordering of vacancies and rare-earth element and barium atoms and subdivision into three-layered blocks.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 6, pp. 349–353, November–December, 2007. 相似文献
110.
The deformation processes in impact-modified PMMA, which deforms homogeneously, were determined by means of the stress/strain experiment (, ) with simultaneous lateral strain measurement (lat) in a wide range of strain rates () up to 105%/min (impact stress). The elastic, plastic cavitation and plastic shear processes were determined as a function of strain. Therefore we calculated the elastic strain (
el), the elastic volume expansion (
vol el), the cavitation strain (
cav), which is identical with the plastic volume expansion (
vol pl), the shear strain (
sh) and the energy densities (Wel, Wcav, Wsh) related to these three processes.For strains of 3 % onward it was found that plastic shear processes and plastic cavitation processes are responsible for a partial loss of elastically stored energy. Both plastic processes turn out to be mostly anelastic deformations, their amount depending strongly on the strain rate. The contributions of the processes to the total deformation of the unmodified PMMA in its strain range are similar to those of the impact-modified PMMA, and the high impact strength is caused by a shift of the catastrophic rupture to very high strains. 相似文献