全文获取类型
收费全文 | 1747篇 |
免费 | 113篇 |
国内免费 | 180篇 |
专业分类
化学 | 1049篇 |
晶体学 | 1篇 |
力学 | 55篇 |
综合类 | 55篇 |
数学 | 395篇 |
物理学 | 485篇 |
出版年
2024年 | 2篇 |
2023年 | 14篇 |
2022年 | 45篇 |
2021年 | 31篇 |
2020年 | 31篇 |
2019年 | 38篇 |
2018年 | 40篇 |
2017年 | 57篇 |
2016年 | 64篇 |
2015年 | 57篇 |
2014年 | 71篇 |
2013年 | 113篇 |
2012年 | 96篇 |
2011年 | 102篇 |
2010年 | 85篇 |
2009年 | 96篇 |
2008年 | 91篇 |
2007年 | 110篇 |
2006年 | 101篇 |
2005年 | 75篇 |
2004年 | 97篇 |
2003年 | 71篇 |
2002年 | 77篇 |
2001年 | 67篇 |
2000年 | 61篇 |
1999年 | 49篇 |
1998年 | 46篇 |
1997年 | 44篇 |
1996年 | 38篇 |
1995年 | 34篇 |
1994年 | 19篇 |
1993年 | 15篇 |
1992年 | 10篇 |
1991年 | 13篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 9篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 13篇 |
1978年 | 6篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2040条查询结果,搜索用时 15 毫秒
171.
Marcin Wieczorek Anna Tobiasz Danuta Dudek-Adamska Stanisław Walas Paweł Kościelniak 《Analytical letters》2017,50(14):2279-2291
Selenium was determined in serum, hair, and tobacco by inductively coupled plasma-mass spectrometry using 77Se, 78Se, and 82Se. The set of standards method (SSM) and the standard addition method (SAM) were applied to calibration with and without the use of internal standards (72Ge and 103Rh). In addition, the usefulness of the dynamic reaction cell (DRC) with methane as the reaction gas was characterized. The results obtained in different conditions were evaluated in terms of precision and accuracy. It was demonstrated theoretically and experimentally that an internal standard is a potential source of systematic errors as it can be influenced multiplicatively and additively by its own interferents (independently of selenium). Furthermore, it was shown that—against common opinion—an internal standard can fail in elimination of chemical interference effects influencing selenium and in increasing of precision of selenium determinations. The DRC was shown to be effective in the elimination of additive effects, although the results obtained by both SSM and SAM with DRC were systematically positively erroneous. Finally, selenium was determined accurately in each examined sample when SAM was applied to calibration, and signals were measured either for 82Se without the use of the DRC, or for 77Se or 78Se with the use of the DRC. In addition, it has also been shown that samples should be diluted prior to analysis to the greatest acceptable extent. 相似文献
172.
173.
174.
A sensitive adsorptive cathodic stripping voltammetry with H‐point standard addition method for simultaneous determination of uranium and cadmium has been developed. The trace amounts of these metal ions can be simultaneously determined using the Levodpa as complexing agent. Optimal conditions were: accumulation time 50 s, accumulation potential 0.0 mV, scan rate 40 mV s?1, supporting electrolyte 0.1 M ammonium buffer pH 9.6, and 1×10?5 M of Levodopa. The results revealed that the cadmium and uranium could be simultaneously determined by H‐point standard addition method with different concentration ratios of uranium to cadmium. The method was successfully applied in a several of real samples. 相似文献
175.
Diabetes, a multifunctional disease and a major cause of morbidity and mortality in the industrialized countries, strongly associates with the development and progression of atherosclerosis. One of the consequences of high level of glucose in the blood circulation is glycation of long-lived proteins, such as collagen I, the most abundant component of the extracellular matrix (ECM) in the arterial wall. Glycation is a long-lasting process that involves the reaction between a carbonyl group of the sugar and an amino group of the protein, usually a lysine residue. This reaction generates an Amadori product that may evolve in advanced glycation end products (AGEs). AGEs, as reactive molecules, can provoke cross-linking of collagen I fibrils. Since binding of low-density lipoproteins (LDLs) to the ECM of the inner layer of the arterial wall, the intima, has been implicated to be involved in the onset of the development of an atherosclerotic plaque, collagen modifications, which can affect the affinity of native and oxidized LDL for collagen I, can promote the entrapment of LDLs in the intima and accelerate the progression of atherosclerosis.In this study, open tubular capillary electrochromatography is proposed as a new microreactor to study in situ glycation of collagen I. The kinetics of glycation was first investigated in a fused silica collagen I-coated capillary. Dimethyl sulphoxide, injected as an electroosmotic flow marker, gave information about the charge of coating. Native and oxidized LDL, and selected peptide fragments from apolipoprotein B-100, the protein covering LDL particles, were injected as marker compounds to clarify the interactions between LDLs and the glycated collagen I coating. The method proposed is simple and inexpensive, since only small amounts of collagen and LDL are required. Atomic force microscopy images complemented our studies, highlighting the difference between unmodified and glycated collagen I surfaces. 相似文献
176.
T. A. Dang H.‐J. Lunk S. Roychowdhury T. A. Frisk T. J. Bard 《Surface and interface analysis : SIA》2010,42(1):45-51
Solid standards prepared by freeze‐drying consistently showed a high degree of homogeneity. The freezing process, completed in fractions of a second, preserves the original homogeneous distribution of the dopants, and the subsequent sublimation step would minimize any disturbance. Compared to those prepared by conventional methods such as blending and spiking, freeze‐dried standards exhibited superior lateral distribution and better uniform depth distribution. There is, however, a concentration constraint for achieving homogeneity. At 5% doping, segregation was observed in both lateral and depth distribution. Many tungsten standards doped with 10–28 elements ranging from 10 to 200 ppm were successfully prepared and used as controls for a number of analytical techniques including glow discharge mass spectrometry (GDMS) and d.c.‐arc optical emission spectroscopy (OES). Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
177.
Zheng Han Xuesong Liu Yiping Ren Lianjun Luan Yongjiang Wu 《Journal of separation science》2010,33(13):1923-1932
A speedy and selective ultra‐HPLC‐MS/MS method for simultaneous determination of deoxynivalenol (DON), 3‐acetyldeoxynivalenol (3‐ADON), 15‐ADON, nivalenol and fusarenon X in traditional Chinese medicines (TCMs) was developed. The method was based on one‐step sample cleanup using reliable homemade cleanup cartridges. A linear gradient mobile‐phase system, consisting of water containing 0.2% aqueous ammonia and acetonitrile/methanol (90:10, v/v) at a flow rate of 0.4 mL/min, and an Acquity UPLC HSS T3 column (100 mm×2.1 mm, 1.8 μm) were employed to obtain the best resolution of the target analytes. [13C15]–DON was used as the internal standard to accomplish as accurate as possible quantitation. The established method was further validated by determining the linearity (R2≥0.9990), sensitivity (LOQ, 0.29–0.99 μg/kg), recovery (88.5–119.5%) and precision (RSD≤15.8%). It was shown to be a suitable method for simultaneous determination of DON, 3‐ADON, 15‐ADON, nivalenol and fusarenon X in various TCM matrices. The utility and practical impact of the method was demonstrated using different TCM samples. 相似文献
178.
Zheng Han Yunliang Zheng Lianjun Luan Yiping Ren Yongjiang Wu 《Journal of chromatography. A》2010,1217(26):4365-4374
The paper reported a reliable analytical method for simultaneous determination of ochratoxin A (OTA) and ochratoxin B (OTB) in traditional Chinese medicines (TCMs) by ultra-high-performance liquid chromatography–tandem mass spectrometry (UHPLC–MS/MS). The development of the method and investigations on the matrix influence were described in particular. The matrix effects were thereby minimized by using a reliable internal standard and a simple sample pretreatment. The established method was further validated by determining the linearity (R2 ≥ 0.9990), average recovery (86.3–114.2%), sensitivity (limit of quantitation 0.03–0.19 ng mL−1) and precision (relative standard deviation ≤ 13.1%). It was shown to be a suitable method for simultaneous determination of OTA and OTB in various TCMs. Finally, a total of 51 TCMs widely used in China were screened for OTA and OTB with the proposed method. The results showed that only 4 samples were contaminated with ochratoxins at low levels, indicating that it was low risk of ochratoxins to consumers who occasionally used TCMs. 相似文献
179.
180.
A wide class of Higgs sectors is investigated in supersymmetric standard models. When the lightest Higgs boson (h ) looks the standard model one, the mass (mh) and the triple Higgs boson coupling (the hhh coupling) are evaluated at the one-loop level in each model. While mh is at most 120–130 GeV in the minimal supersymmetric standard model (MSSM), that in models with an additional neutral singlet or triplet fields can be much larger. The hhh coupling can also be sensitive to the models: while in the MSSM the deviation from the standard model prediction is not significant, that can be 30–60% in some models such as the MSSM with the additional singlet or with extra doublets and charged singlets. These models are motivated by specific physics problems like the μ-problem, the neutrino mass, the scalar dark matter and so on. Therefore, when h is found at the CERN Large Hadron Collider, we can classify supersymmetric models by measuring mh and the hhh coupling accurately at future collider experiments. 相似文献