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911.
R. B. King 《Russian Chemical Bulletin》1993,42(11):1772-1781
Reactions of disodium tetracarbonylferrate, Na2Fe(CO)4, with sterically hindered dialkylaminodichlorophosphines, R2NPCl2 (R2N=diisopropylamino, dicyclohexylamino, and 2,2, 6, 6-tetramethylpiperidino) in diethyl ether lead to the air-stable phosphorus-bridging carbonyl derivatives (R2NP)2COFe2(CO)6 as the major products. The phosphorus-bridging carbonyl group in (i-Pr2NP)2COFe2(CO)6 has been found to undergo the following types of reactions: 1)Reduction, 2)Acylation, 3)Extrusion of the carbonyl group. The mechanisms of the reactions have been considered.This work was presented at the Workshop «The Modern Problems of Heteroorganic Chemistry» held on the ship «Nikolai Bauman» during the period May 8–13, 1993.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1858–1867, November, 1993. 相似文献
912.
913.
Bang-yen Chen 《Annals of Global Analysis and Geometry》1993,11(4):345-359
In this article we obtain the best possible estimates of the type number of tensor product immersions and investigate tensor product immersions with lowest possible type. Several classification theorems in this respect are then proved. 相似文献
914.
We revealed the changes in the γ-luminescence spectra under the influence of a thermal radiation field on high-purity alkali-silicate
glasses (I) and those with addition of Fe3+ ions (II). We explain the obtained results within the framework of the L-model of edge absorption and electron-hole recombination
processes.
Samarkand State University, 15, Universitetskii Bul., Samarkand, 703004, Republic of Uzbekistan. Translated from Zhurnal Prikladnoi
Spektroskopii, Vol. 65, No. 3, pp. 453–455, May–June, 1998. 相似文献
915.
本文应用多重尺度法构造出非线性微分方程组的解的渐近展开式。并用微分不等式的技巧,证明原问题的解的存在性,且给出解的一致有效渐近估计. 相似文献
916.
Summary Measurements on sea surface films were conducted during five separate experimental periods in the following marine areas:
the Sicilian Channel, the Gulf of Maine (spring and fall periods), Bermuda, and the Pacific Ocean West of Southern California.
The measurements consisted in surface elevation sampling using an interferential microwave probe with frequency spectra evaluation.
Wave spectra were performed for both clean and film-covered sea surface conditions to determine the wave attenuation ratio
within the 2–20 Hz spectral range. The method is able to detect, chart and characterize sea surface films. Theoretical analyses
of the results yield several viscoelastic film parameters: the modulus of elasticity, the relaxation frequency and the maximum
of the damping ratio as a function of wave frequency. The analysed data are interpreted to infer film weathering effects,
surface concentration of film-forming constituents, and compactness of the organic sea surface film. 相似文献
917.
918.
在添加了15%Li_2O的NdMO_3(M=Cr、Mn、Fe、Co、Ni)上进行了甲烷氧化偶联(OCM)反应研究.通过改变反应气中CH_4:O_2浓度比,在氧化态和“脱氧态”催化剂上的CH_4脉冲反应,探讨了表面吸附氧和晶格氧在OCM反应中的作用以及NdMO_3中不同金属离子(M)对OCM反应活性的影响等. 相似文献
919.
In a general measure-theoretic context, it is proved that the action of a stochastic map on a pair of probability distributions can be characterized by the criterion of decreasing mixing distance. 相似文献
920.
We study notions of nondegeneracy and several levels of increasing degeneracy from the perspective of the local behavior of a local solution of a nonlinear program when problem parameters are slightly perturbed. Ideal nondegeneracy at a local minimizer is taken to mean satisfaction of second order sufficient conditions, linear independence and strict complimentary slackness. Following a brief exploration of the relationship of these conditions with the classical definition of nondegeneracy in linear programming, we recall a number of optimality and regularity conditions used to attempt to resolve degeneracy and survey results of Fiacco, McCormick, Robinson, Kojima, Gauvin and Janin, Shapiro, Kyparisis and Liu. This overview may be viewed as a structured survey of sensitivity and stability results: the focus is on progressive levels of degeneracy. We note connections of nondegeneracy with the convergence of algorithms and observe the striking parallel between the effects of nondegeneracy and degeneracy on optimality conditions, stability analysis and algorithmic convergence behavior. Although our orientation here is primarily interpretive and noncritical, we conclude that more effort is needed to unify optimality, stability and convergence theory and more results are needed in all three areas for radically degenerate problems.Research supported by National Science Foundation Grant ECS 90-00560 and Grant N00014-89-J-1537 Office of Naval Research 相似文献