首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   28160篇
  免费   950篇
  国内免费   924篇
化学   7205篇
晶体学   966篇
力学   834篇
综合类   134篇
数学   15168篇
物理学   5727篇
  2023年   119篇
  2022年   286篇
  2021年   267篇
  2020年   277篇
  2019年   556篇
  2018年   527篇
  2017年   422篇
  2016年   479篇
  2015年   451篇
  2014年   851篇
  2013年   1711篇
  2012年   806篇
  2011年   2004篇
  2010年   1806篇
  2009年   1841篇
  2008年   1847篇
  2007年   1789篇
  2006年   1455篇
  2005年   1174篇
  2004年   980篇
  2003年   829篇
  2002年   840篇
  2001年   568篇
  2000年   585篇
  1999年   533篇
  1998年   538篇
  1997年   409篇
  1996年   438篇
  1995年   393篇
  1994年   382篇
  1993年   292篇
  1992年   297篇
  1991年   218篇
  1990年   209篇
  1989年   200篇
  1988年   128篇
  1987年   151篇
  1985年   578篇
  1984年   392篇
  1983年   298篇
  1982年   306篇
  1981年   274篇
  1980年   226篇
  1979年   191篇
  1978年   184篇
  1977年   176篇
  1976年   173篇
  1975年   123篇
  1974年   154篇
  1973年   157篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
141.
In this paper, we establish some new nonlinear integral inequalities of the Gronwall–Bellman–Ou-Iang-type in two variables. These on the one hand generalizes and on the other hand furnish a handy tool for the study of qualitative as well as quantitative properties of solutions of differential equations. We illustrate this by applying our new results to certain boundary value problem.  相似文献   
142.
Cr-doped mullites were prepared from single-phase precursors containing up to 9.60 wt% Cr2O3 using a sol-gel technique followed by thermal treatment. Particle induced X-ray emission spectroscopy and X-ray powder diffraction were used to characterize the samples. Mullites were orthorhombic, space group Pbam. Cr doping caused the increase of unit-cell parameters. Strongest expansion was noticed along c-axis followed by a and bc/c=0.089, Δa/a=0.061, Δb/b=0.045% per mole Cr2O3). A second phase, namely θ-(Al,Cr)2O3, was revealed by XRD in the sample containing 9.60 wt% Cr2O3. The structure of mullites was refined by the Rietveld method, location of Cr3+ was performed by the EPR spectroscopy. At low chromium doping level (Cr2O3 content less than ∼5 wt%) Cr3+ ions were substituted for Al3+ in the AlO6 octahedra of the mullite structure (M1 site). For higher doping level, Cr3+ ions were additionally substituted for Al3+ in the AlO6 octahedra of the second phase [θ-(Al,Cr)2O3 at 1400 °C, or α-(Al,Cr)2O3 at 1600 °C] which segregated in the system. Substitution of Cr3+ for Al3+ on M1 site in the mullite structure resulted in increase of average distances in (M1)O6 octahedron and decrease of average distances in T*O4 tetrahedron, while average distances in TO4 tetrahedron stayed almost constant.  相似文献   
143.
144.
本文介绍非线性方程转化直线性方程和多元线性回归法来分析近代物理实验中塞曼效应分裂干涉圆环多处选点测量的处理过程。  相似文献   
145.
A simple microscopic model of charge ordering in the NaxCoO2 system is presented. The model takes into account the interplane interactions between the ordered Na ions and d electrons from the CoO2 layers as well as the nearest-neighbor intraplane Coulomb interactions between d electrons. It is shown that a driving force of charge ordering in the CoO2 layers is the interplane interaction that alone is able to describe various types of inhomogeneous charge ordering (e.g., the striped phases) as well as to predict correctly the conducting properties of the system.  相似文献   
146.
The first total synthesis of (R)-convolutamydine A has been achieved by the organocatalytic addition of acetone to 4,6-dibromoisatin. The absolute configuration was determined by single crystal X-ray diffraction. DFT studies were used to model the transition states for the aldol reaction and equilibrium geometries of the post-aldol reaction intermediates. The DFT study revealed that the aldol bond forming reaction was considerably endothermic.  相似文献   
147.
Common fixed-point results are established for a new class of noncommuting selfmaps. We apply them to obtain several invariant approximation results which unify, extend, and complement well-known results.  相似文献   
148.
An approximation theorem for families of weakly coercive convex functions by means of countably many smooth families of convex functions is proved. As a consequence, the classical “three-fold” lower semicontinuity theorem for integral functionals of the Calculus of Variations by James Serrin is unified in one single statement.  相似文献   
149.
由于混凝土材料理化特性的差异,高强混凝土的弯压极限应变明显地小于普通混凝土,依据试验结果分析了高强混凝土的弯压极限应变变化规律,并给出了它的计算公式.  相似文献   
150.
橙皮素A的NMR研究   总被引:5,自引:3,他引:2  
原忠  周碧野  李铣 《波谱学杂志》2002,19(3):309-313
橙皮素A是从中药北沙参(Glehnia littoralis Fr. Schmidt ex Miquel)的正丁醇萃 取物中分离得到的一种8-O-4′-型异木脂素苷类化合物. 通过化学方法和波谱分析鉴 定了该 化合物的结构. 采用2D NMR技术对其NMR信号进行了全归属. DMSO-d6代替CD3OD作为溶剂,并利用重水交换,能准确读出偶合常数J7,8值.   相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号