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21.
薛世翔  吴攀  赵亮  南艳丽  雷琬莹 《化学进展》2022,34(12):2686-2699
析氧反应(OER)是电催化裂解水、二次金属-空气电池和可再生燃料电池等绿色可持续能源储存和转化技术中的关键步骤,但其较高的势垒和迟滞的动力学过程限制了反应的效率。因此,设计开发高效、稳定的非贵金属催化剂是新能源领域面临的挑战之一。钴铁水滑石(CoFe LDH)材料具有独特的二维层状结构、丰富多变的化学组成、高分散的金属阳离子、优异的稳定性和成本低廉等优点,在OER反应中有广泛的应用前景。但不良的导电性和有限的活性位点阻碍了CoFe LDH的工业化应用。本文首先介绍了CoFe LDH的结构并阐述了其OER反应机理,接着总结了CoFe LDH的制备工艺,并详细综述了近年来提升其OER性能的改性策略:插层剥离、空位制造、材料复合、离子取代和衍生物等。最后讨论了水滑石材料现阶段存在的问题和未来在能源转化和利用领域的发展方向。  相似文献   
22.
This research aims to compare the performance of ARIMA as a linear model with that of the combination of ARIMA and GARCH family models to forecast S&P500 log returns in order to construct algorithmic investment strategies on this index. We used the data collected from Yahoo Finance with daily frequency for the period from 1 January 2000 to 31 December 2019. By using a rolling window approach, we compared ARIMA with the hybrid models to examine whether hybrid ARIMA-SGARCH and ARIMA-EGARCH can really reflect the specific time-series characteristics and have better predictive power than the simple ARIMA model. In order to assess the precision and quality of these models in forecasting, we compared their equity lines, their forecasting error metrics (MAE, MAPE, RMSE, MAPE), and their performance metrics (annualized return compounded, annualized standard deviation, maximum drawdown, information ratio, and adjusted information ratio). The main contribution of this research is to show that the hybrid models outperform ARIMA and the benchmark (Buy&Hold strategy on S&P500 index) over the long term. These results are not sensitive to varying window sizes, the type of distribution, and the type of the GARCH model.  相似文献   
23.
在需求不确定下,由风险规避的供应商和占主导地位的零售商组成的二级供应链中,构建了在现货市场影响下基于实物期权的双源柔性采购协调模型,给出了实现供应链协调的最优期权参数的求解算法,探讨了现货市场价格不确定性和供应商风险规避特性对零售商采购策略和双方利润的影响。研究结果表明,在考虑现货市场影响和供应商风险规避的条件下,实物期权契约可以实现供应链协调。  相似文献   
24.
Algebraic modelling languages allow models to be implemented in such a way that they can easily be understood and modified. They are therefore a working environment commonly used by practitioners in Operations Research. Having once developed models, they need to be integrated inside the company information system. This step often involves embedding a model into a programming language environment: many existing algebraic modelling languages make possible to run parameterised models and subsequently retrieve their results, but without any facility for interacting with the model during the model generation or solution process.In this paper we show how to use the Mosel environment to implement complex algorithms directly in the modelling language.The Office cleaning problem is solved by a branch-and-cut algorithm, implemented entirely in the modelling language (including the definition of the callback function for the solver). Secondly, a cutting stock problem is solved by column generation, also implemented in the modelling language.AMS classification: 90Cxx, 65K05, 68N15  相似文献   
25.
Trading by Quantum Rules: Quantum Anthropic Principle   总被引:1,自引:0,他引:1  
This is a short review of the background and recent development in quantum game theory and its possible application in economics and finance. The intersection of science and society is discussed and Quantum Anthropic Principle is put forward. The review is addressed to nonspecialists.  相似文献   
26.
In 1999 Amodio and Mazzia presented a new backward error analysis for LU factorization and introduced a new growth factor n . Their very interesting approach allowed them to obtain sharp error bounds. In particular, they derive nice results assuming that partial pivoting is used. However, the forward error bound for the solution of a linear system whose coefficient matrix A is an M-atrix given in Theorem 4.1 of that paper is not correct. They first obtain a bound for the condition number (U) assuming that one has the LU factorization of an M-matrix and then they apply the bounds obtained when partial pivoting is used. But if P is the permutation associated with partial pivoting then PA = LU can fail to be an M-atrix and the bound for (U) can be false, as shown in our Example 1.1. We also prove that, for a pivoting strategy presented in the paper, the growth factor of an M-matrix A is n(A) = 1 and (U) (A), where U is the upper triangular matrix obtained after applying such a pivoting strategy.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献   
27.
Digital image correlation (DIC) has received a widespread research and application in experimental mechanics. In DIC, the performance of subpixel registration algorithm (e.g., Newton-Raphson method, quasi-Newton method) relies heavily on the initial guess of deformation. In the case of small inter-frame deformation, the initial guess could be found by simple search scheme, the coarse-fine search for instance. While for large inter-frame deformation, it is difficult for simple search scheme to robustly estimate displacement parameters and deformation parameters simultaneously with low computational cost. In this paper, we proposed three improving strategies, i.e. Q-stage evolutionary strategy (T), parameter control strategy (C) and space expanding strategy (E), and then combined them into three population-based intelligent algorithms (PIAs), i.e. genetic algorithm (GA), differential evolution (DE) and particle swarm optimization (PSO), and finally derived eighteen different algorithms to calculate the initial guess for qN. The eighteen algorithms were compared in three sets of experiments including large rigid body translation, finite uniaxial strain and large rigid body rotation, and the results showed the effectiveness of proposed improving strategies. Among all compared algorithms, DE-TCE is the best which is robust, convenient and efficient for large inter-frame deformation measurement.  相似文献   
28.
Multi-period guarantees are often embedded in life insurance contracts. In this paper we consider the problem of hedging these multi-period guarantees in the presence of transaction costs. We derive the hedging strategies for the cheapest hedge portfolio for a multi-period guarantee that with certainty makes the insurance company able to meet the obligations from the insurance policies it has issued. We find that by imposing transaction costs, the insurance company reduces the rebalancing of the hedge portfolio. The cost of establishing the hedge portfolio also increases as the transaction cost increases. For the multi-period guarantee there is a rather large rebalancing of the hedge portfolio as we go from one period to the next. By introducing transaction costs we find the size of this rebalancing to be reduced. Transaction costs may therefore be one possible explanation for why we do not see the insurance companies performing a large rebalancing of their investment portfolio at the end of each year.  相似文献   
29.
研究电子商务网站竞争模型,分析其平衡点的稳定性,给出数值模拟图,建立一系列电子商务网站获胜的新策略.  相似文献   
30.
For the analysis presented in this paper we use experiments to study human behavior in a simulation environment based on a simple Lotka–Volterra predator–prey ecology. The aim is to study the influence of different harvesting strategies and of certain personality traits derived from the Hamburg Personality Inventory (HPI) [Andresen, B., 2002. HPI – Hamburger Persönlichkeitsinventar. Hogrefe, Göttingen] on the outcome in terms of sustainability and economic performance.  相似文献   
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