A novel electron scattering apparatus combining a laser photoelectron source and a triply differentially pumped supersonic beam target: characterization and results for the resonance

A novel electron scattering apparatus for high resolution studies of angle-differential elastic and inelastic electron scattering from atoms and molecules in the gas phase is described and its performance characterized. It combines a laser photoelectron source, a triply differentially pumped collimated supersonic beam target (half angle 0.015 rad, background to beam density ratio < 0.01), and several electron multipliers for simultaneous detection of elastically scattered electrons and metastable atoms (or molecules) due to inelastic scattering. In detailed test measurements of the yield for the production of metastable He^*(2³S₁) atoms around its threshold, the dependence of the overall energy width on various experimental parameters has been investigated. So far a resolution down to 7 meV (FWHM) has been obtained. Under such conditions we have investigated the profile of the He^- (1 s 2 s ^{2 2} S _1/2 ) resonance at the scattering angles 22 ^° , 45 ^° , and 90 ^° . From a consistent fit of the measured profiles by resonant scattering theory we determine a new value for the resonance energy ( E _r = 19.365(1) eV) and an accurate resonance width ( Γ = 11.2(5) meV). These results are consistent with the previously recommended values. Received 23 July 2002 Published online 29 October 2002 RID="a" ID="a"e-mail: hotop@physik.uni-kl.de RID="b" ID="b"Permanent address: Department of Physics and Astronomy, Drake University, Des Moines, IA 50311, USA.     

(Im-)possible ISOL beams

Refractory elements, i.e. elements with very high melting point and low vapor pressure, cannot be released in atomic form from an ISOL target. Therefore most of these elements are presently not available as ISOL beams. However, when reactive gases are introduced into the target, they may form volatile compounds with the refractory elements, allowing for an easier transport to the ion source. Particularly useful are high-temperature stable fluorides and oxides. By these chemical evaporation methods so far ISOL beams of the refractory elements C, Zr, Hf and Ta have been produced. We discuss how ISOL beams of B, Ti, Nb, Mo, Tc, Ru, W, Re, Os and Ir could be produced in a similar way.     

CERN的ISOLDE装置上的ECR离子剥离器Phoenix的最新进展

At ISOLDE (CERN),an on-line test bench is dedicated to charge breeding experiments with a 14GHz Phoenix ion source,for the investigation of the 1 →n scenario at next generation ISOL-type facilities.This year,various technical developments have been undertaken for intensifying the tests of the on- line performances of the booster with a high diversity of stable and radioactive ion beams.This contribution will present an overview of the latest developments,the current challenges,and some perspectives for the future use of the Phoenix booster for physics experiments at ISOLDE.     

高频ECR离子源的最新进展

As they are first optimized for their ion losses,ECRISs are always under a fundamental compromise: having high losses and strong confinement at the same time.To help ECR ion source developers in the design or improvement of existing machines,general comments are presented in a review article being soon published. In this 160 pages contribution,fundamental aspects of ECRISs are presented,with a discussion of electron temperature and confinement and ion confinement.Then,as microwaves play a key role in these machines, a chapter presents major guidelines for microwave launching and coupling to ECR plasma.Moreover,once ECR plasma is created,understanding this plasma is important in ion sourcery;and a section is dedicated to plasma diagnostics with an emphasis on the determination of electron and ion density and temperature by vacuum ultraviolet(VUV)spectroscopy.Another chapter deals with the role of magnetic confinement and presents updated scaling laws.Next chapter presents different types of ECRISs designed according to the main parameters previously described.Finally,some industrial applications of ECRISs and ECR plasmas in general are presented like ion implantation and photon lithography.Some hints taken from this review article are presented in the following article.     

Novel long chain unsaturated diisocyanate from fatty acid: Synthesis,characterization, and application in bio‐based polyurethane

A novel long chain linear unsaturated terminal diisocyanate, 1,16‐diisocyanatohexadec‐8‐ene (HDEDI) was synthesized from oleic acid via Curtius rearrangement. Its chemical structure was identified by FTIR, ¹H NMR, ¹³C NMR, and HRMS. This diisocyanate was used as a starting material for the preparation of entirely bio‐based polyurethanes (PUs) by reacting it with canola diol and canola polyol, respectively. The physical properties and crystalline structure of the PUs prepared from this diisocyanate were compared to their counterparts prepared from similar fatty acid‐derived diisocyanate, 1,7‐heptamethylene diisocyanate (HPMDI). The HDEDI based PUs demonstrated various different properties compared to those of HPMDI based PUs. For example, HDEDI based PUs exhibited a triclinic crystal form; whereas HPMDI based PUs exhibited a hexagonal crystal lattice. In addition, canola polyol‐HDEDI PU demonstrated a higher tensile strength at break than that of canola polyol‐HPMDI, attributed to the higher degree of hydrogen bonding associated with the former sample. Nevertheless, lower Young's modulus and higher elongation in canola polyol‐HDEDI PU were obtained because of the flexibility of the long chain introduced by the HDEDI diisocyanate. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3302–3310, 2010     

An analysis of the morphological and spectral behaviour of the gamma-ray bursts

Summary We investigate by a statistical analysis possible correlations among the observational parameters of the γ-ray bursts: the rise time, the decay time and spectral hardness. We discuss the physical constraints implied by the results. To speed up publication, the proofs were not sent to the authors and were supervised by the Scientific Committee.     

多源单汇网络资源调度路径优化探讨

在考虑队列长度的前提下 ,论文在分析多源单汇资源传输问题的基础上 ,以两源单汇网络为例 ,在资源到达终点所需时间最短约束下 ,研究、计算了最短传输时间的上下界 ,并提出了相应的算法 .论文的研究内容为进一步研究多源多汇问题建立了基础 ,提供了思路 .     

On the pfaffianized-KP equation with self-consistent sources

A new procedure called ‘source generation’ is applied to the pfaffianized KP equation. As a result, the pfaffianized-KP equation with self-consistent sources (ESCS) is obtained. This coupled system cannot only be reduced to the pfaffianized KP equation, but also reduced to the KP equation with self-consistent sources (KPESCS). So the pfaffianized-KP ESCS can be viewed as a pfaffian version of the KPESCS, which indicates the commutativity of the ‘source generation’ procedure and pfaffianization.     

Physical and electrochemical properties of LiFe<Subscript>0.5</Subscript>Mn<Subscript>1.5</Subscript>O<Subscript>4</Subscript> spinel synthesized by different methods

The study deals with the synthesis and comparison of physicochemical properties of LiFe_0.5Mn_1.5O₄ based cathode materials synthesized by the standard ceramic and the auto-ignition method.