平面研磨中影响工件起动力矩的因素

本文针对平面研磨过程中工件运动的随机性，从理论上求出了在机床起动瞬间磨具作用于工件上的合力矩；探讨了影响这个力矩的主要因素，偏心距和工件几何尺寸的作用规律；为选择研磨参数提供一理论依据。     

电位滴定法测定模拟高放废液中的游离酸

本文研究了用电位滴定法测定模拟高放废液中游离酸的方法。用草酸钾做络合剂以消除Ｆｅ＾３＋、Ａｌ＾３＋、Ｎｄ＾３＋等多种水解离子的影响，用标准碱直接进行电位滴定，即可快速准确地测定模拟高放废液中游离酸的含量。方法的相对标准偏差为１．８％，标准加入回收率为１００－１０１％，能为放射性废物固化试验提供可靠的分析数据。     

Electrostatic calculation of the substituent effect: an efficient test on isolated molecules

The energy of a disubstituted molecule has often been approximated by simple electrostatic formulas that represent the substituents as poles or dipoles. Herein, we test this approach on a new model system that is more direct and more efficient than testing on acid-base properties. The energies of 27 1,4-derivatives of bicyclo[2.2.2]octane were calculated within the framework of the density functional theory at the B3LYP/6-311+G(d,p) level; interaction of the two substituents was evaluated in terms of isodesmic homodesmotic reactions. This interaction energy, checked previously on some experimental gas-phase acidities, was considered to be accurate and served as reference to test the electrostatic approximation. This approximation works well in the qualitative sense as far as the sign and the order of magnitude are concerned: beginning with the strongest interaction between two poles, a weaker interaction between pole and dipole, and the weakest between two dipoles. However, all the electrostatic calculations yield energies that are too small, particularly for weak interaction, and this fundamental defect is not remedied by some possible improvements. In particular, variation of the effective permittivity would require a physically impossible value less than unity. The explanation must lie in a more complex distribution of electron density than anticipated in the electrostatic model. It also follows that possible conclusions about the transmission of substituent effects "through space" have little validity.     

蒿甲醚在模拟体内酸碱环境中的代谢动力学研究

 利用高效液相法对蒿甲醚进行了模拟体内酸碱环境的代谢动力学研究 ,测定了蒿甲醚及其代谢产物双氢青蒿素、蒿甲醚呋喃酯的代谢曲线。结果表明 ,蒿甲醚在模拟体内肠道和血液的弱碱性环境条件下半衰期为2 87 2min(计算值 ) ;在模拟体内胃液的酸性环境条件下半衰期为 74 6min ;在两种条件下的主要代谢产物均为双氢青蒿素和蒿甲醚呋喃酯。该方法克服了以往文献所报道方法的一些缺点 ,不仅简化了样品制备方法 ,也提高了检测结果的准确性。     

The high resolution infrared spectrum and laser Stark spectroscopy of thev8 band of propyne

The perpendicularv ₈ band lying in the 1000–1100 cm^–1 region has been studied from infrared and laser Stark, spectra. We were interested in the part of spectrum corresponding to the spectral range of the 9 m CO₂ laser lines. Assignments of rovibrational lines with J'<40 and K'<6 have been made. About 100 Stark resonances have been assigned to 12 rovibrational transitions. Effective molecular constants and dipole moment have been determined with high accuracy. A list of close resonances with CO₂ laser lines is given and may be used for optical pumping experiments.     

稀土锰氧化物La0.7Ca0.3Mn1-xCuxO3低场磁电阻及电传输特性研究

采用溶胶-凝胶法制备了系列多晶CMR材料La0.7Ca0.3Mn1-xCuxO3（x=0%,1%,5%,10%,15%,20%）。在77-350 K温度范围内测量了样品的电阻率及磁电阻大小。实验结果发现：系列样品TC随掺杂量增加而递减;系列样品的电阻率峰及磁电阻峰在整个测温范围内随掺杂量的增加均依次被展宽直至消失,当掺杂量为x≥10%时,电阻率随温度的变化在整个测温范围内呈现绝缘相行为;同时还发现,掺杂量为x≥10%时,样品的磁电阻在整个测温区内基本表现为隧穿磁电阻。基于我们采用蒙特卡罗模拟方法提出的逾渗模型及隧穿磁电阻模型,对样品的磁电阻行为进行了很好的解释。对系列样品的ρ-T曲线进行lnρ-T^-（1/4）系拟合,发现掺杂量为x=10%样品在整个温区内的lnρ-T^-（1/4）系基本呈线性。     

Electric parameters of photosystem II particles — electric light scattering study

Electric light scattering and microelectrophoresis were applied to investigate the electric moments (permanent dipole moment and electric polarizability and electrophoretic mobility of envelope-free chloroplasts and photosystem II (PS II particles. The effect of the removal of the extrinsic polypeptides (18, 24 and 33 kDa) on the electric moments was also studied. A significant difference was observed between the orientation behaviour of chloroplasts and PS II preparations. The data indicate that the permanent and induced dipole moments contribute to the orientation of the PS II particles, whereas chloroplasts possess induced dipole moment only.

NaCl and Tris treatments of PS II preparations influence both the transverse permanent dipole moment and the electric polarizability of PS II particles. The increase in the electrophoretic mobility of PS II particles on removal of the extrinsic proteins corresponds to an increase in the electric polarizability value, demonstrating its interfacial nature.     

Liquid chromatography of benzene derivatives on a porous methacrylate copolymer containing epoxy groups

Summary The retention of benzene derivatives with nonpolar and polar substituents on a porous methacrylate copolymer containing epoxy groups using both nonpolar and polar eluents was investigated. When n-hexane is used as the eluent, the retention of n-alkylbenzenes and polymethylbenzenes is weaker than that of benzene. In the case of benzene derivatives containing polar functional groups their capacity ratios (k) on this porous polymer increases approximately linearly with the increase of the adsorbate molecules dipole moment. The retention characteristics of the methacrylate copolymer were compared with that of a styrene-divinylbenzene copolymer and silica gels with a hydroxylated surface and with a surface modified by chemically bonded alkylsilyl groups.     

Nanostructural Approach to Proton Ordering in Gas Hydrate Cages

A nanostructural approach to analysis of proton ordering in gas hydrate cages has been worked out within the framework of the topological model of strong and weak H-bonds. The approach involves rejection of the periodic boundary conditions, decomposition of the H-bond net into spherical layers, and two-dimensional drawing of the structure of spherical (spheroidal) fragments in the form of conjugate Schlegel diagrams. To analyze proton ordering in the spherical fragments composed of gas hydrate voids, we used the simulated annealing procedure and the correlation extension method proposed earlier.     

Dipole moments and structure of poly(epoxypropylcarbazole)

The mean-square molecular dipole moments 〈μ²〉 of carbazole, N-ethylcarbazole and of the sequence of poly(epoxypropylcarbazole) (PEPCa) oligomers of various molecular weights have been evaluated in solutions of these organic compounds in dioxan. For PEPCa the values of 〈μ²〉 have also been determined in the solid state. On the basis of the experimental results and of molecular mechanics calculations it has been shown that the orientation of the lateral group of PEPCa favors noninteracting racemic dyads. The temperature-dependence of the effective dipole moment of solid PEPCa follows the Onsager theory above 295 K.